File name: Pandora185s1_EastProvidenceRI_20230812_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20230813T045830.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20230812_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20230812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230812T111845.4Z 8624.471359 203 1 49.22 2 74.90 83.26 34.35 101.78 0.00 1 0.00 1 0 17 2.098e-01 1.055e-02 1.512e-01 6.128e-03 4.911526e-01 3.249215e-03 6.294722e-03 -6.000000e+00 1.236880e-01 231.99 -2.00 3.53 -2.00 320.54 0.00e+00 3.315878e-03 1.283207e-03 3.895656e-03 -6.000000e+00 5.545516e-03 289.54 -2.00 20.00 -2.00 319.80 0.00e+00 3.764 0.001 302.00 328.00 3 3.9180e+00 1.0294e-02 4.9167e-02 -6.0000e+00 3.0961e-01 6.5963e-02 1.2948e-02 3.5231e-02 -6.0000e+00 3.3478e-01 -7.2455e-02 1.1061e-02 1.5782e-02 -6.0000e+00 1.9953e-01 1.9383e-02 5.5182e-03 3.6059e-03 -6.0000e+00 8.4179e-02 1.3824e-04 -5.1513e-04 1.8747e-04 7.4264e-05 -6.0000e+00 5.9686e-03 3.7650e-03 0.0000e+00 12 8 8 10 0 0 99.43 22.90 0.18 0.00377 -0.00011 21 5 1 5 0 2343.440 26.73 20.01 22.90 26.49 19.8 982.32 -80187 -104365 601 -55402 -30823 -43211 -70960 -65128 -105956 -32427 -96581 12039 -16075 -33960 -23591 -31912 10326 8550 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-1494 -466 -1927 -75 758 773 1901 1062 -1395 -187 -1434 -181 -1031 -629 -200 190 192 -1158 -1402 -2706 -1103 -439 -1447 -1947 -788 -709 481 2375 1730 2183 2224 1738 -1059 152 -451 -24 908 85 1334 -91 428 372 498 374 -2012 127 -219 512 -208 -1324 -2010 -532 -1212 449 1940 1694 -674 477 -472 -425 -399 SS 20230812T113203.5Z 8624.480596 210 1 48.84 2 72.44 85.41 32.00 104.78 0.00 1 0.00 1 0 17 7.880e-02 6.850e-03 4.095e-02 2.339e-03 4.230426e-01 1.230800e-03 4.932978e-03 -6.000000e+00 4.646167e-02 231.99 -2.00 3.53 -2.00 319.91 0.00e+00 2.488318e-03 3.912782e-04 7.051380e-04 -6.000000e+00 2.082736e-03 289.54 -2.00 20.00 -2.00 319.10 0.00e+00 3.266 0.001 302.00 328.00 3 3.0000e+00 3.6631e-03 3.9754e-02 -6.0000e+00 1.1630e-01 6.0418e-03 4.4085e-03 2.2623e-02 -6.0000e+00 1.2575e-01 7.2630e-03 3.4963e-03 1.1472e-02 -6.0000e+00 7.4944e-02 -1.5110e-02 1.7943e-03 3.9375e-03 -6.0000e+00 3.1626e-02 6.1185e-04 2.0897e-04 7.2264e-05 4.5714e-05 -6.0000e+00 2.2416e-03 2.4000e-03 0.0000e+00 11 8 0 10 0 0 98.03 22.96 0.39 0.00240 0.00397 57 12 1 5 0 856.680 26.83 19.98 22.96 27.14 20.0 987.58 -30189 -8549 -36321 -11150 -16307 -14979 -46183 -15805 -19979 -27000 -22715 -19592 -18595 -6891 -9679 -2595 2230 2679 -5873 -4807 -3168 -6413 -2244 -3073 -7343 -14 -8517 -2559 -6026 1429 1866 612 -6535 -17 -10154 -1540 -2197 -1871 -1970 -1885 -857 -734 301 -941 2072 1459 439 -774 820 11 876 1091 1341 743 1631 440 351 344 -276 1012 1379 2604 1752 2216 672 920 291 700 -51 749 1694 822 194 -206 -914 -887 -1330 -221 -1209 -807 -1772 -2052 -2200 -1153 -772 400 858 1025 1065 1358 1125 1141 633 326 -812 321 590 -105 -354 -835 -1408 -760 45 -1493 -1501 -1194 -734 -81 1032 325 26 29 -182 -209 341 321 139 425 32 -99 234 599 151 440 -224 165 1105 322 -138 -341 10 -91 426 -37 -36 301 675 -275 -59 -474 -320 -334 -488 -133 -753 -166 -240 -224 -1044 -298 -431 -649 -546 -524 -598 -239 -405 -113 100 128 -324 -273 -179 -380 -135 -200 -527 -1 -623 -169 -412 109 161 60 -748 -2 -1146 -169 -281 -287 -363 -394 -191 -171 72 -230 497 355 108 -195 208 3 260 350 460 270 608 171 137 132 -105 391 571 1179 878 1151 342 443 139 354 -29 477 1129 556 127 -127 -511 -452 -657 -114 -718 -548 -1368 -1731 -1967 -1090 -708 383 847 1017 1025 1338 1025 970 533 294 -832 335 690 -134 -451 -1009 -1569 -863 51 -1686 -1800 -1502 -972 -114 1557 531 45 48 -288 -308 475 445 201 655 52 -165 380 939 229 634 -311 219 1487 475 -223 -591 18 -170 833 -77 -79 621 1416 -583 -122 -1018 -658 -673 SS 20230812T114106.3Z 8624.486878 216 1 4.95 2 70.76 86.88 30.41 106.98 0.00 1 0.00 1 0 17 7.583e-02 1.065e-02 5.368e-02 6.798e-03 3.871251e-01 3.520838e-03 4.526993e-03 -6.000000e+00 4.471793e-02 231.99 -2.00 3.53 -2.00 318.86 0.00e+00 3.155542e-03 8.111265e-04 6.209372e-04 -6.000000e+00 2.004206e-03 289.54 -2.00 20.00 -2.00 318.01 0.00e+00 2.998 0.000 302.00 328.00 3 3.5217e+00 9.7814e-03 3.6338e-02 -6.0000e+00 1.1194e-01 2.9575e-02 1.1256e-02 2.0407e-02 -6.0000e+00 1.2102e-01 -3.0598e-02 7.7457e-03 1.0237e-02 -6.0000e+00 7.2128e-02 6.6760e-03 4.0425e-03 3.7091e-03 -6.0000e+00 3.0443e-02 4.8869e-04 -1.3196e-04 2.0274e-04 3.8070e-05 -6.0000e+00 2.1570e-03 1.1172e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.97 0.13 0.00112 0.00013 2 7 1 5 0 1589.490 26.83 19.99 22.97 27.64 19.9 990.26 -19527 -33153 15292 -39814 -33211 -27157 -25958 3242 -17706 -17438 -13214 14647 -10241 -9472 5028 -3101 863 1334 -4561 -6552 2325 3841 128 -7798 3726 -8486 253 -6153 4949 -857 1756 -3295 -2890 -6496 -10263 -5416 -562 -425 3288 -1603 1806 -270 922 1308 63 2595 215 2874 -1984 2230 4013 2653 963 -668 2866 1630 101 479 -1610 1716 1389 887 3114 734 2136 -1325 445 1117 981 1603 551 236 2761 2620 -1626 -1646 -3872 -2658 -1527 -1859 -2043 -1800 -2166 -1525 -225 945 96 912 1858 1135 197 -1593 -1339 -1327 -1100 373 756 -988 -281 -73 -1055 -855 281 -380 -1533 -941 -600 -142 1244 642 -19 210 -81 -792 -93 686 -154 524 653 634 1456 -132 322 458 510 -585 916 163 970 -427 -84 -71 569 -755 246 121 977 -85 -25 -821 -969 -708 -718 -1518 476 -1799 -1431 -1116 -1153 120 -880 -890 -666 631 -679 -747 400 -296 85 139 -529 -803 262 430 16 -1091 487 -1282 34 -844 604 -119 268 -590 -556 -1270 -2000 -1059 -120 -108 963 -507 592 -94 328 469 23 932 79 1027 -758 865 1664 1200 473 -350 1492 879 55 258 -877 925 806 571 1961 491 1353 -819 290 695 689 1244 457 198 2183 1936 -1134 -1139 -2622 -1861 -1099 -1535 -1895 -1671 -2133 -1592 -248 1013 108 1022 2005 1240 200 -1529 -1251 -1316 -1215 425 964 -1289 -365 -96 -1285 -970 318 -465 -2019 -1295 -812 -203 1901 991 -30 329 -120 -1176 -129 944 -223 803 991 979 2339 -210 489 662 704 -840 1314 238 1525 -681 -140 -122 1012 -1360 460 234 1908 -168 -49 -1523 -1727 -1232 SS 20230812T114610.6Z 8624.490401 219 1 49.42 2 69.81 87.71 29.53 108.29 0.00 1 0.00 1 0 17 4.878e-02 6.758e-03 2.355e-02 2.083e-03 3.763444e-01 1.083393e-03 4.469411e-03 -6.000000e+00 2.875964e-02 231.99 -2.00 3.53 -2.00 319.40 0.00e+00 1.624534e-03 2.912847e-04 9.165495e-04 -6.000000e+00 1.289345e-03 289.54 -2.00 20.00 -2.00 318.56 0.00e+00 2.867 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