File name: Pandora185s1_EastProvidenceRI_20230824_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20230825T134758.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20230824_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20230824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230824T113538.0Z 8636.483079 83 1 48.27 2 73.77 89.52 157.71 40.73 0.00 1 0.00 1 0 17 1.768e-01 9.643e-03 1.415e-01 5.559e-03 4.523582e-01 2.946135e-03 5.287734e-03 -6.000000e+00 1.046636e-01 231.13 -2.00 3.53 -2.00 320.26 0.00e+00 1.848958e-03 1.067730e-03 1.308852e-03 -6.000000e+00 4.747413e-03 288.95 -2.00 20.00 -2.00 319.51 0.00e+00 3.518 0.001 302.00 328.00 3 4.0757e+00 8.9900e-03 4.2886e-02 -6.0000e+00 2.6129e-01 1.1595e-02 1.1161e-02 2.4970e-02 -6.0000e+00 2.8293e-01 2.9807e-03 9.5024e-03 1.2496e-02 -6.0000e+00 1.6813e-01 -1.3857e-02 4.8076e-03 3.5911e-03 -6.0000e+00 7.1248e-02 1.5858e-04 -1.5802e-04 1.7158e-04 4.7697e-05 -6.0000e+00 5.0736e-03 3.2044e-03 0.0000e+00 12 8 8 10 0 0 97.61 23.12 0.25 0.00320 0.00202 21 5 1 5 0 2297.880 26.94 20.01 23.12 25.38 20.2 974.17 900000 -35578 -44003 55454 -104191 900000 -75426 -17325 -85404 41189 -14517 -14337 -56946 12904 -19015 30270 2105 34151 -5419 -1219 -22198 -5931 549 -18595 -8422 -27003 4903 -14036 3989 -8557 25622 -1140 6773 -5801 -2305 -6632 9068 -1101 1279 6949 822 2563 -3476 1794 -2757 -557 -565 -2571 2893 55 -163 3098 2604 356 2429 -168 3866 -3464 4679 -628 2839 187 5361 1973 1753 749 -398 56 -854 2989 -533 2540 -1260 1725 -2839 -568 -4586 1685 -2261 -953 -1706 -2125 -2020 -620 252 -137 615 -223 2384 1732 987 63 398 78 280 -458 800 -123 -1025 -529 -1490 19 -1750 -648 -1942 -325 -1213 629 430 401 279 473 -238 -150 489 128 -409 149 393 199 767 285 1157 -288 -786 -861 1563 136 287 148 -539 188 -382 -137 -63 823 2 202 -282 261 -733 -468 900000 -466 -636 300 -2399 900000 -1498 -219 -2352 365 -236 -268 -1991 273 -656 716 72 908 -227 -51 -1159 -269 25 -1099 -477 -1902 246 -816 194 -518 1262 -83 497 -477 -177 -565 764 -124 169 993 135 434 -710 352 -574 -114 -117 -549 603 13 -41 826 750 111 770 -56 1253 -1188 1460 -211 992 74 2234 889 768 316 -169 25 -438 1642 -321 1495 -742 918 -1429 -255 -2075 759 -1212 -580 -1181 -1614 -1625 -525 227 -131 604 -222 2246 1534 814 49 305 64 259 -486 945 -159 -1335 -648 -1689 19 -1863 -733 -2362 -409 -1633 891 664 670 441 735 -389 -229 704 185 -619 238 660 339 1273 461 1786 -430 -1130 -1194 2163 208 480 268 -1026 335 -719 -274 -132 1763 4 444 -604 530 -1441 -898 SS 20230824T122057.4Z 8636.514553 109 1 49.16 2 65.36 97.29 151.63 59.10 0.00 1 0.00 1 0 17 2.137e-02 6.657e-03 6.864e-03 1.105e-03 3.107446e-01 5.670429e-04 3.670816e-03 -6.000000e+00 1.256062e-02 231.13 -2.00 3.53 -2.00 318.54 0.00e+00 9.274035e-04 1.167717e-04 5.299779e-04 -6.000000e+00 5.634379e-04 288.95 -2.00 20.00 -2.00 317.68 0.00e+00 2.382 0.000 302.00 328.00 3 2.8765e+00 1.5532e-03 2.8943e-02 -6.0000e+00 3.1380e-02 8.0740e-03 1.7784e-03 1.6433e-02 -6.0000e+00 3.3956e-02 8.4808e-03 1.1724e-03 8.0022e-03 -6.0000e+00 2.0245e-02 -1.2186e-02 6.0461e-04 2.2242e-03 -6.0000e+00 8.5534e-03 1.8940e-03 1.0718e-04 3.3654e-05 2.4669e-05 -6.0000e+00 6.0779e-04 2.5780e-03 0.0000e+00 11 8 0 10 0 0 99.16 23.09 0.28 0.00258 0.00338 102 22 1 5 0 481.890 26.94 20.01 23.09 27.50 20.2 987.89 -6348 -1569 -8050 -6715 -10682 -4881 -5743 -1952 -6242 -6338 -6769 -4507 -3658 217 -1269 -375 -623 344 -613 -825 1066 125 1454 -985 29 -1487 -1519 -2780 -953 -256 625 993 -532 -3230 -3641 -3081 -2517 -1393 -566 -496 -732 -259 -413 361 288 -130 -129 -820 117 318 622 654 1330 812 1323 1107 550 272 123 1306 1615 2338 2346 1043 158 -94 -566 837 798 745 748 631 607 321 -642 -1408 -1883 -1077 -1446 -1426 -1476 -2212 -1685 -859 -514 84 603 759 790 488 150 -526 -219 -190 -407 355 832 147 -592 -905 -1251 -644 -296 -1000 -1232 -955 -646 134 900 891 538 559 129 -101 51 148 106 215 70 -88 277 505 526 455 -18 137 822 327 78 -82 -345 -307 177 -89 -85 313 363 37 -91 -210 -562 -562 -318 -80 -434 -326 -499 -219 -286 -106 -383 -399 -478 -342 -320 21 -144 -46 -80 46 -87 -121 154 18 222 -164 5 -266 -263 -457 -150 -42 111 193 -112 -678 -736 -653 -608 -398 -191 -188 -296 -109 -177 154 124 -55 -54 -343 49 139 291 327 702 450 749 642 322 157 70 755 993 1558 1688 778 113 -63 -368 561 601 565 600 511 477 261 -477 -952 -1211 -710 -1071 -1196 -1254 -2046 -1633 -881 -564 96 717 907 917 529 150 -487 -195 -177 -422 408 1059 201 -814 -1180 -1509 -726 -338 -1240 -1626 -1318 -934 186 1328 1395 864 872 190 -151 72 205 153 332 106 -136 420 744 812 668 -25 184 1106 473 121 -124 -543 -496 296 -158 -159 601 710 72 -174 -389 -1007 -989 SS 20230824T122739.5Z 8636.519207 114 1 49.77 2 64.12 98.49 150.61 61.26 0.00 1 0.00 1 0 17 1.572e-02 6.801e-03 1.259e-03 2.492e-04 2.991322e-01 1.280838e-04 3.544767e-03 -6.000000e+00 9.240057e-03 231.13 -2.00 3.53 -2.00 318.23 0.00e+00 9.885300e-04 2.401746e-05 4.645837e-04 -6.000000e+00 4.144587e-04 288.95 -2.00 20.00 -2.00 317.36 0.00e+00 2.277 0.000 302.00 328.00 3 1.9067e-01 3.4739e-04 2.7704e-02 -6.0000e+00 2.3084e-02 1.1613e-02 3.9501e-04 1.5716e-02 -6.0000e+00 2.4978e-02 2.9492e-03 2.5194e-04 7.6505e-03 -6.0000e+00 1.4892e-02 -9.9104e-03 1.2859e-04 2.1486e-03 -6.0000e+00 6.2925e-03 3.1278e-02 2.1623e-04 7.5721e-06 2.3118e-05 -6.0000e+00 4.4708e-04 2.0987e-03 0.0000e+00 11 8 0 10 0 0 0.94 23.08 0.26 0.00210 0.00372 1483 323 1 5 0 32.970 26.94 20.00 23.08 27.81 20.3 990.50 -2137 -3181 -3587 -6446 -4877 -4444 -3321 -2937 -4090 -4976 -4867 -2612 -2688 -585 -863 -121 -202 694 506 776 -21 1027 538 105 21 -822 -1490 -1872 -718 113 974 720 -646 -3656 -3248 -3489 -2222 -1008 -465 -844 -562 -263 -204 220 216 101 -374 -603 -394 684 621 1013 1154 960 1234 1064 432 236 385 1086 1757 2270 2396 947 255 -199 -409 630 1023 693 964 636 782 95 -614 -1250 -1875 -1251 -1474 -1392 -1642 -2129 -1764 -809 -546 198 442 873 668 607 225 -353 -77 -180 -201 312 910 -6 -477 -904 -1276 -939 -236 -1191 -1202 -857 -533 215 813 896 605 525 69 1 3 210 174 383 -8 -69 343 500 435 438 -98 -4 847 230 92 -224 -258 -307 183 30 -87 277 372 -6 -173 -214 -569 -454 -128 -205 -229 -386 -265 -269 -218 -216 -331 -415 -410 -236 -281 -70 -117 -18 -31 110 84 133 -4 177 98 20 4 -171 -302 -357 -131 21 200 162 -157 -888 -752 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