File name: Pandora185s1_EastProvidenceRI_20230914_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20230916T185108.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20230914_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20230914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230914T123555.5Z 8657.524948 112 1 27.14 2 66.64 107.48 60.68 106.41 0.00 1 0.00 1 0 17 1.994e-02 8.834e-03 9.414e-03 1.705e-03 3.091905e-01 8.661109e-04 3.734826e-03 -6.000000e+00 1.164129e-02 229.31 -2.00 3.53 -2.00 318.36 0.00e+00 1.111440e-03 1.699221e-04 8.111180e-04 -6.000000e+00 5.220963e-04 287.30 -2.00 20.00 -2.00 317.53 0.00e+00 2.502 0.000 302.00 328.00 3 3.2346e+00 2.3486e-03 2.9804e-02 -6.0000e+00 2.8971e-02 1.1269e-02 2.6823e-03 1.6398e-02 -6.0000e+00 3.1402e-02 1.3470e-03 1.7418e-03 7.9934e-03 -6.0000e+00 1.8732e-02 -8.8308e-03 8.9828e-04 2.2109e-03 -6.0000e+00 7.9310e-03 1.1899e-03 1.8785e-04 5.1639e-05 2.4794e-05 -6.0000e+00 5.6686e-04 3.1558e-03 0.0000e+00 12 9 1 12 1 1 99.62 23.11 0.28 0.00316 0.00457 32 13 1 5 0 822.000 26.94 20.00 23.11 27.31 20.8 980.33 -1199 -5134 -1436 -9661 1190 -7126 93 -2971 -3778 -5746 -8419 2563 -2951 855 -2633 -865 -228 1177 200 -389 -188 1523 655 628 -735 -359 -1280 -2479 -958 -1800 -185 -284 -2119 -5130 -3108 -5630 -1583 -1326 -556 -973 -71 341 -433 449 -93 144 -496 -714 -259 1155 494 1533 1501 1292 1378 1364 627 2 32 1174 2362 2655 2905 1311 259 -562 -892 485 949 865 1265 1121 1021 588 -1022 -2092 -3113 -1823 -2646 -1745 -1852 -1990 -1599 -250 -89 808 831 1084 505 10 -1061 -2108 -1598 -1223 -609 229 975 292 -199 -638 -1271 -946 -634 -1159 -1099 -530 -203 593 1259 1581 1190 1065 277 116 -312 -302 -285 228 37 -65 493 735 433 395 -220 -507 716 81 -70 -295 -460 -767 -107 -327 -387 481 799 340 102 -29 -619 -467 -64 -303 -81 -537 60 -399 5 -198 -275 -436 -666 200 -284 92 -335 -117 -32 173 31 -62 -30 243 111 113 -140 -69 -242 -445 -165 -328 -36 -61 -495 -1202 -684 -1339 -414 -414 -205 -405 -31 155 -202 209 -43 67 -229 -326 -118 546 253 831 784 707 773 781 363 1 18 674 1429 1749 2061 967 183 -373 -578 324 708 716 1101 985 870 471 -753 -1411 -2009 -1201 -1969 -1459 -1725 -2005 -1550 -255 -97 926 987 1294 588 11 -1071 -2162 -1577 -1263 -634 265 1244 401 -273 -831 -1538 -1073 -730 -1444 -1455 -732 -294 830 1875 2489 1921 1675 412 173 -440 -423 -417 327 57 -102 756 1095 622 584 -312 -690 973 119 -102 -456 -737 -1263 -182 -593 -686 870 1471 630 186 -51 -1129 -835 SS 20230914T124051.7Z 8657.528376 115 1 23.44 2 65.76 108.43 59.83 107.38 0.00 1 0.00 1 0 17 2.119e-02 7.334e-03 1.114e-02 2.256e-03 2.960891e-01 1.147258e-03 3.516440e-03 -6.000000e+00 1.236836e-02 229.31 -2.00 3.53 -2.00 318.19 0.00e+00 1.426344e-03 2.142886e-04 3.344851e-04 -6.000000e+00 5.547567e-04 287.30 -2.00 20.00 -2.00 317.36 0.00e+00 2.419 0.000 302.00 328.00 3 3.7253e+00 3.0979e-03 2.8652e-02 -6.0000e+00 3.0780e-02 1.7171e-02 3.5304e-03 1.5438e-02 -6.0000e+00 3.3365e-02 2.6522e-03 2.2458e-03 7.5908e-03 -6.0000e+00 1.9903e-02 -1.0773e-02 1.1465e-03 2.3165e-03 -6.0000e+00 8.4255e-03 8.0263e-04 2.1210e-04 6.8301e-05 2.5296e-05 -6.0000e+00 6.0233e-04 3.9174e-03 0.0000e+00 12 9 1 12 1 1 99.56 23.14 0.41 0.00392 0.00551 18 9 1 5 0 1232.970 26.94 20.00 23.14 27.25 20.8 980.60 -2777 -10828 -11773 -50 -1296 5494 -10079 -1346 -3546 1158 -5930 -2122 -1894 -828 -478 -2469 -152 -579 1400 1684 1627 -1409 2367 155 -115 60 338 -2277 339 2187 -126 2285 -288 -2828 -3242 -3757 -2473 187 -1988 -259 -561 -539 310 557 217 92 635 -1042 33 1019 687 52 726 581 556 694 -477 -343 464 889 1642 2229 2284 843 42 410 -382 752 625 857 950 1006 665 84 -1344 -1334 -1893 -778 -1068 -1709 -1554 -2429 -1685 -1243 -238 7 376 740 1333 1306 755 -120 531 201 -387 23 331 91 -445 -833 -1385 -1091 -299 -1135 -1310 -1007 -710 563 1001 698 535 534 132 -211 166 111 204 406 67 -157 352 132 340 303 -333 0 864 642 -356 4 -172 -92 386 187 55 201 547 -177 -233 -409 -679 -275 -172 -773 -838 -3 -77 308 -725 -99 -290 92 -513 -194 -201 -101 -66 -376 -24 -95 235 291 282 -254 430 30 -24 13 68 -443 62 415 -27 517 -71 -693 -764 -939 -698 61 -790 -114 -262 -238 139 249 107 45 306 -504 16 506 369 27 399 334 327 416 -290 -206 273 533 1042 1534 1692 647 31 278 -253 515 480 727 851 908 583 69 -1019 -915 -1235 -518 -799 -1454 -1468 -2497 -1660 -1301 -264 9 455 899 1562 1424 759 -122 518 206 -405 27 427 125 -615 -1091 -1682 -1244 -344 -1422 -1746 -1403 -957 791 1497 1108 867 841 196 -314 232 153 294 577 102 -243 539 198 486 446 -471 -1 1165 927 -516 6 -272 -149 646 332 96 358 995 -326 -418 -709 -1224 -485 SS 20230914T130445.0Z 8657.544966 127 1 50.46 2 61.61 113.21 55.79 112.28 0.00 1 0.00 1 0 17 1.269e-02 6.866e-03 7.196e-04 1.984e-04 2.601042e-01 1.010922e-04 3.102680e-03 -6.000000e+00 7.408503e-03 229.31 -2.00 3.53 -2.00 317.71 0.00e+00 8.959889e-04 1.644443e-05 3.135412e-04 -6.000000e+00 3.322812e-04 287.30 -2.00 20.00 -2.00 316.88 0.00e+00 2.093 0.000 302.00 328.00 3 4.1757e-02 2.6955e-04 2.4885e-02 -6.0000e+00 1.8437e-02 9.8379e-03 3.0488e-04 1.3507e-02 -6.0000e+00 1.9985e-02 2.2676e-03 1.8581e-04 6.5940e-03 -6.0000e+00 1.1921e-02 -8.9750e-03 9.2515e-05 1.8739e-03 -6.0000e+00 5.0470e-03 4.6550e-02 2.5370e-04 6.0027e-06 2.1247e-05 -6.0000e+00 3.6077e-04 3.6334e-03 0.0000e+00 11 8 0 10 0 0 8.35 23.17 0.28 0.00363 0.00554 1952 426 1 5 0 25.200 27.05 20.00 23.17 29.40 21.0 996.26 -1788 -1506 -3697 -4615 -3748 -3148 -1940 -1324 -2278 -4143 -3328 -2086 -1284 -1 71 -182 609 714 956 895 426 1287 922 462 161 -371 -1127 -1237 -522 576 1000 1286 -634 -3173 -3041 -3036 -2013 -950 -491 -817 -563 -389 -232 63 186 -131 -241 -713 -316 586 678 904 1045 922 1118 1075 305 223 219 1034 1605 2238 2199 832 111 -247 -533 598 900 490 833 575 703 101 -479 -1213 -1727 -1208 -1371 -1479 -1604 -2192 -1776 -798 -539 187 440 873 624 589 111 -311 -129 -147 -298 348 837 -2 -484 -880 -1270 -880 -261 -1190 -1143 -799 -516 152 817 810 580 485 115 -21 16 160 222 443 2 -77 339 536 412 509 -41 95 850 330 146 -169 -254 -248 223 66 -72 285 373 -8 -161 -288 -620 -567 -159 -141 -347 -436 -322 -272 -182 -138 -259 -487 -389 -261 -183 0 13 -35 122 149 207 199 96 288 216 115 42 -99 -290 -297 -120 136 253 352 -187 -926 -847 -889 -667 -371 -226 -383 -279 -199 -121 33 97 -67 -122 -389 -171 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