File name: Pandora185s1_EastProvidenceRI_20230915_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20230918T165021.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20230915_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20230915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230915T123635.9Z 8658.525415 105 1 17.99 2 66.72 107.98 71.42 103.63 0.00 1 0.00 1 0 17 1.999e-02 7.479e-03 1.968e-02 3.645e-03 3.069229e-01 1.855191e-03 3.632641e-03 -6.000000e+00 1.166784e-02 229.22 -2.00 3.53 -2.00 318.31 0.00e+00 1.418708e-03 3.600449e-04 3.635921e-04 -6.000000e+00 5.233013e-04 287.22 -2.00 20.00 -2.00 317.49 0.00e+00 2.511 0.000 302.00 328.00 3 4.2348e+00 5.0211e-03 2.9722e-02 -6.0000e+00 2.9032e-02 2.2060e-02 5.7266e-03 1.5987e-02 -6.0000e+00 3.1471e-02 2.6196e-03 3.7092e-03 7.8657e-03 -6.0000e+00 1.8774e-02 -9.8327e-03 1.9097e-03 2.3832e-03 -6.0000e+00 7.9489e-03 4.3249e-04 8.4349e-05 1.1061e-04 2.5834e-05 -6.0000e+00 5.6835e-04 3.4761e-03 0.0000e+00 12 9 1 12 1 1 99.91 23.13 0.46 0.00348 0.00411 7 5 1 5 0 2247.910 26.94 19.99 23.13 22.70 20.7 951.89 483 -2570 -5179 -4363 -6910 1022 -1548 2049 -10471 -1859 -9573 153 2049 -1095 -218 3158 -1748 -3185 3996 -2761 1365 938 3745 363 3950 1258 58 -455 1817 -2213 -718 2895 61 -1216 -3369 -1996 -4151 -1704 -1737 -544 -2124 -1201 -1300 -354 -344 106 -226 -1605 -260 -143 2231 298 1076 135 1233 407 931 -611 1097 689 1971 2592 1645 850 403 764 -708 817 872 891 936 802 815 880 416 -1152 -1968 -1810 -1197 -1394 -1099 -2276 -1888 -861 31 196 740 635 845 340 -171 -232 263 -177 -943 623 645 110 -618 -725 -1334 -15 -391 -870 -1518 -976 -507 -105 922 643 595 42 -46 -385 388 265 98 85 45 -34 382 322 800 538 -310 -42 1083 627 70 8 -681 85 171 -91 -253 672 770 6 -267 -597 -700 -353 26 -153 -313 -238 -393 54 -93 133 -837 -139 -786 13 192 -124 -28 422 -258 -501 611 -466 222 154 628 67 733 245 11 -82 311 -415 -145 618 14 -280 -759 -467 -1137 -544 -659 -229 -968 -512 -567 -169 -165 50 -106 -753 -121 -69 1142 151 574 76 702 239 545 -358 624 403 1214 1733 1198 639 288 507 -463 550 658 745 826 715 704 710 305 -777 -1268 -1203 -885 -1171 -1024 -2318 -1849 -891 34 227 885 766 988 372 -172 -235 256 -182 -989 719 828 152 -856 -950 -1620 -17 -450 -1084 -2024 -1357 -737 -148 1380 1023 967 66 -69 -532 543 369 142 122 69 -53 586 482 1143 794 -440 -58 1463 911 102 13 -1090 139 290 -164 -447 1207 1411 11 -484 -1045 -1272 -628 SS 20230915T124442.2Z 8658.531044 111 1 12.79 2 65.30 109.55 70.01 105.10 0.00 1 0.00 1 0 17 2.470e-02 8.172e-03 1.713e-02 3.951e-03 2.946336e-01 2.017403e-03 3.511177e-03 -6.000000e+00 1.441471e-02 229.22 -2.00 3.53 -2.00 317.97 0.00e+00 1.935341e-03 3.554501e-04 2.156021e-04 -6.000000e+00 6.465385e-04 287.22 -2.00 20.00 -2.00 317.15 0.00e+00 2.376 0.000 302.00 328.00 3 4.2491e+00 5.4201e-03 2.8276e-02 -6.0000e+00 3.5866e-02 3.3213e-02 6.1491e-03 1.5426e-02 -6.0000e+00 3.8881e-02 -5.5166e-03 3.8318e-03 7.5609e-03 -6.0000e+00 2.3194e-02 -7.3880e-03 1.9343e-03 2.5204e-03 -6.0000e+00 9.8197e-03 4.9200e-04 2.5114e-05 1.1817e-04 2.6290e-05 -6.0000e+00 7.0220e-04 3.9975e-03 0.0000e+00 12 9 1 12 1 1 99.59 23.13 0.16 0.00400 0.00419 5 5 1 5 0 2130.920 26.94 19.99 23.13 22.94 20.7 953.35 930 -5809 -2815 -1808 -14792 2665 -11274 3685 -3655 -6420 -5440 9849 -4291 3571 -2332 1780 1157 2264 -435 394 2482 -132 1635 -2600 -977 -2535 1821 -1608 -2451 -2851 692 -983 1895 -2702 -5176 -112 -3522 -307 -1813 314 -288 1049 -553 160 882 864 -28 -224 469 581 -1228 -373 3042 200 2062 -50 1127 -811 1182 -54 1790 1683 1505 360 1472 16 -503 1258 -110 897 121 1713 529 0 -604 -1301 -2147 -477 -1449 -1446 -1429 -2620 -1740 -1659 -507 -204 964 800 842 465 1087 131 452 -340 -302 -14 1241 292 -894 -758 -1422 -612 -290 -622 -1512 -680 -436 419 915 776 568 726 -208 -590 204 352 411 50 -63 -382 549 106 298 704 -206 -740 682 420 305 180 -11 77 16 133 -407 531 975 -415 -170 -324 -758 -391 69 -490 -228 -132 -1128 172 -916 288 -332 -611 -518 884 -516 462 -364 288 198 401 -82 76 471 -26 329 -575 -222 -595 396 -340 -508 -622 159 -251 499 -723 -1358 -29 -1092 -110 -779 135 -132 493 -270 78 428 416 -13 -106 220 285 -659 -212 1763 124 1286 -32 725 -524 741 -35 1217 1250 1206 298 1140 12 -357 916 -91 745 107 1503 455 0 -485 -952 -1499 -338 -1158 -1307 -1316 -2634 -1825 -1854 -600 -236 1138 954 973 543 1156 129 430 -342 -334 -17 1551 394 -1214 -970 -1690 -735 -353 -757 -1971 -922 -619 624 1343 1208 903 1119 -303 -857 276 473 576 75 -94 -582 820 155 449 1004 -282 -977 894 589 460 267 -16 121 26 230 -696 926 1729 -750 -299 -589 -1333 -672 SS 20230915T130450.6Z 8658.545031 123 1 50.10 2 61.81 113.60 66.55 108.88 0.00 1 0.00 1 0 17 1.285e-02 6.838e-03 8.258e-04 2.261e-04 2.630334e-01 1.151173e-04 3.143405e-03 -6.000000e+00 7.497411e-03 229.22 -2.00 3.53 -2.00 317.71 0.00e+00 8.740933e-04 1.875710e-05 3.328055e-04 -6.000000e+00 3.362922e-04 287.22 -2.00 20.00 -2.00 316.89 0.00e+00 2.106 0.000 302.00 328.00 3 2.8494e-01 3.0683e-04 2.5086e-02 -6.0000e+00 1.8655e-02 1.6950e-02 3.4714e-04 1.3667e-02 -6.0000e+00 2.0223e-02 2.2886e-03 2.1176e-04 6.6722e-03 -6.0000e+00 1.2064e-02 -8.8611e-03 1.0549e-04 1.8850e-03 -6.0000e+00 5.1072e-03 3.5712e-02 2.1054e-04 6.8211e-06 2.1372e-05 -6.0000e+00 3.6525e-04 4.3339e-03 0.0000e+00 11 8 0 10 0 0 85.16 23.04 0.27 0.00433 0.00592 1478 322 1 5 0 33.300 26.83 20.00 23.04 24.02 20.7 960.68 -1804 -1944 -3300 -5212 -3625 -3491 -1512 -1871 -2046 -4226 -3240 -2324 -1528 -111 16 -160 485 720 941 910 242 1399 692 620 15 -295 -1267 -1170 -452 476 964 1245 -567 -3168 -2892 -3186 -1818 -992 -408 -787 -571 -379 -181 112 158 -65 -309 -689 -365 619 574 892 992 930 1042 1103 297 267 222 1087 1644 2275 2274 801 185 -291 -508 583 979 500 871 537 739 54 -414 -1179 -1706 -1154 -1334 -1409 -1624 -2178 -1780 -829 -588 101 357 816 536 566 74 -356 -118 -177 -273 327 841 11 -449 -901 -1237 -854 -215 -1162 -1104 -819 -482 178 787 827 568 505 69 28 25 221 204 477 -16 -26 347 517 413 521 -56 109 862 294 130 -191 -242 -289 254 30 -82 261 402 -16 -143 -263 -603 -579 -158 -181 -305 -489 -308 -300 -139 -194 -230 -493 -375 -289 -216 -18 3 -31 97 150 203 202 54 311 162 153 4 -78 -326 -280 -104 112 244 340 -167 -924 -803 -934 -601 -388 -187 -369 -283 -194 -94 58 82 -34 -156 -376 -198 346 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