File name: Pandora185s1_EastProvidenceRI_20230926_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20230927T204147.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20230926_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20230926 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230926T125656.7Z 8669.539545 187 1 18.39 2 65.63 115.99 151.90 319.94 0.00 1 0.00 1 0 17 6.328e-02 1.740e-02 5.455e-02 1.097e-02 2.785634e-01 5.578246e-03 3.350545e-03 -6.000000e+00 3.677364e-02 227.97 -2.00 3.53 -2.00 318.21 0.00e+00 1.542336e-03 1.048108e-03 6.668187e-04 -6.000000e+00 1.646655e-03 285.88 -2.00 20.00 -2.00 317.41 0.00e+00 2.407 0.000 302.00 328.00 3 5.8079e+00 1.5069e-02 2.8005e-02 -6.0000e+00 9.1272e-02 8.5112e-02 1.7165e-02 1.4523e-02 -6.0000e+00 9.9035e-02 -5.9152e-03 1.1004e-02 7.2445e-03 -6.0000e+00 5.9090e-02 -1.2205e-02 5.6350e-03 2.2267e-03 -6.0000e+00 2.5069e-02 1.0145e-04 1.1581e-03 3.3285e-04 2.3489e-05 -6.0000e+00 1.7977e-03 -7.5201e-04 0.0000e+00 12 9 9 12 1 1 99.99 23.15 0.50 -0.00075 0.00795 4 3 1 5 0 3677.210 26.94 19.98 23.15 23.93 20.8 968.87 13028 -1512 9318 -4990 -26670 -16320 28516 3702 -19264 -1376 -8727 18336 -4227 15986 -9844 15245 -7879 13557 -8760 10026 -14916 -4374 6155 -12619 9126 -5162 -1526 -7703 10179 2559 10297 -5455 14074 6700 -2528 849 -894 103 -1652 1018 937 466 -2524 760 -3945 -1678 2144 2719 -4951 1741 -4358 151 -770 3454 3883 2772 -788 -951 1213 985 2399 1173 3362 -1852 2191 374 551 -566 2590 -2113 2589 3256 2965 1755 -438 673 -6693 -985 -3202 -2186 -4123 -175 -3019 -910 601 1374 396 1799 1062 786 -1312 -4223 -570 -2934 733 -1116 2599 151 930 -537 -1282 -2090 568 -3927 -1243 -16 84 869 269 2958 152 819 -1115 25 -714 -685 -1362 1298 -415 377 2216 410 1167 94 1267 -2222 1983 -169 817 -784 1091 -1186 728 9 -284 -320 1221 -13 76 -966 -2163 812 785 -112 607 -340 -2074 -1158 1414 263 -1854 -112 -772 1354 -452 1616 -1454 1882 -1279 1858 -1558 1520 -2900 -770 1017 -2649 1606 -1064 -292 -1467 1573 490 1982 -1336 2995 1483 -587 201 -246 33 -643 431 421 218 -1239 362 -1970 -811 976 1209 -2377 815 -2325 82 -445 1987 2271 1669 -492 -585 723 601 1539 829 2494 -1472 1574 253 361 -390 1938 -1830 2253 2834 2505 1404 -324 444 -4487 -643 -2383 -1816 -3870 -170 -3170 -997 695 1515 456 2054 1301 898 -1398 -4254 -534 -2943 780 -1350 3357 193 1173 -712 -1580 -2450 661 -5156 -1685 -22 112 1214 403 4551 245 1265 -1642 37 -998 -950 -1983 1969 -619 570 3253 596 1777 137 1744 -3026 2609 -243 1243 -1278 1799 -1860 1166 15 -511 -592 2274 -25 141 -1732 -3787 1356 SS 20230926T132219.1Z 8669.557165 207 1 49.92 2 61.49 121.36 154.35 331.38 0.00 1 0.00 1 0 17 4.942e-02 1.410e-02 3.780e-02 8.745e-03 2.505590e-01 4.443815e-03 3.005662e-03 -6.000000e+00 2.869168e-02 227.97 -2.00 3.53 -2.00 318.23 0.00e+00 3.429977e-03 8.193273e-04 3.003287e-04 -6.000000e+00 1.286109e-03 285.88 -2.00 20.00 -2.00 317.42 0.00e+00 2.085 0.000 302.00 328.00 3 5.9420e+00 1.1952e-02 2.4506e-02 -6.0000e+00 7.1210e-02 9.7283e-02 1.3602e-02 1.3209e-02 -6.0000e+00 7.7298e-02 -8.6072e-04 8.5277e-03 6.6689e-03 -6.0000e+00 4.6120e-02 -1.3060e-02 4.3336e-03 3.2355e-03 -6.0000e+00 1.9541e-02 1.2466e-04 3.4823e-04 2.6813e-04 2.9797e-05 -6.0000e+00 1.4043e-03 7.3388e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.89 0.91 0.00734 0.00996 35 8 1 5 0 1426.030 26.73 20.00 22.89 24.03 20.8 969.03 -1933 24071 707 9658 -20092 -7725 -9741 4368 -15342 11274 -15397 16924 -3872 4403 -6112 2467 1525 -4907 10589 -4118 5902 -3597 16551 -2724 -4334 -4573 2128 -3531 8798 -2498 67 -1671 839 418 -8408 -3753 -7700 1 3074 -1622 -4245 2695 -1044 2128 -2112 3575 2126 -1080 1666 479 1321 -1862 2934 -1196 2910 358 2329 -1345 1680 -135 4428 3444 2094 1334 -1032 86 -3146 1497 -1964 1531 -659 2058 1257 2578 -2388 1384 -3356 -4327 -1167 -3331 -3048 -2525 -1103 -18 1579 -237 1373 891 2841 -405 -82 -2059 -805 -1475 -792 935 954 780 -1138 72 -3074 -767 159 -969 -1980 -757 -675 1455 637 1233 1666 259 851 -1320 997 -1356 454 769 -151 -1273 508 1045 947 -1189 -691 -738 648 540 548 279 -446 -112 -963 395 -339 978 414 236 342 512 -646 -1622 -163 1659 60 679 -1742 -593 -824 354 -1613 913 -1630 1419 -462 560 -973 386 250 -896 1715 -793 1023 -685 2658 -552 -921 -1074 450 -742 1589 -527 15 -409 211 102 -2125 -951 -2310 0 1149 -705 -2000 1226 -504 998 -1036 1640 967 -496 741 224 653 -1006 1588 -697 1654 211 1347 -794 955 -80 2681 2287 1508 979 -727 55 -2009 948 -1438 1193 -551 1686 1004 1902 -1841 926 -2218 -2966 -863 -2829 -2851 -2519 -1137 -20 1810 -292 1566 1129 3415 -467 -85 -2012 -745 -1435 -841 1085 1224 1064 -1567 93 -3751 -863 182 -1206 -2637 -1043 -972 2155 1011 2044 2781 423 1286 -1872 1298 -1795 615 1111 -234 -2046 794 1582 1375 -1671 -919 -937 816 724 784 420 -696 -178 -1600 686 -621 1818 790 453 639 922 -1136 -2833 SS 20230926T132740.3Z 8669.560883 210 1 8.71 2 60.64 122.55 154.76 334.01 0.00 1 0.00 1 0 25 2.439e-02 9.005e-03 1.582e-02 5.178e-03 2.380581e-01 2.637916e-03 2.891697e-03 -6.000000e+00 1.415843e-02 227.97 -2.00 3.53 -2.00 317.34 0.00e+00 8.698341e-04 3.887628e-04 2.665744e-04 -6.000000e+00 6.346183e-04 285.88 -2.00 20.00 -2.00 316.54 0.00e+00 2.031 0.000 302.00 328.00 3 3.6171e+00 6.9686e-03 2.3702e-02 -6.0000e+00 3.5140e-02 2.3761e-02 7.8614e-03 1.2366e-02 -6.0000e+00 3.8143e-02 8.0836e-03 4.6896e-03 6.0517e-03 -6.0000e+00 2.2758e-02 -1.3100e-02 2.2917e-03 1.7259e-03 -6.0000e+00 9.6435e-03 1.4328e-03 -1.9189e-05 1.5639e-04 2.0342e-05 -6.0000e+00 6.9296e-04 6.9295e-03 0.0000e+00 12 9 1 12 1 1 99.60 22.85 0.37 0.00693 0.00679 4 6 2 5 0 1740.680 26.62 19.99 22.85 24.10 20.8 969.66 2437 1302 -3328 -10349 3426 -13790 -2203 -7958 2563 -3969 4284 5209 -3712 3478 -3068 5461 627 1190 -787 3160 -1947 1413 1544 1200 2088 -1994 952 -3104 1105 -4926 385 1715 1121 -5444 -3737 -5827 -5530 22 619 -2834 1564 736 601 1413 1298 772 371 -1485 -577 1509 395 3034 372 1559 178 1274 -736 -362 311 564 828 2173 2250 506 85 197 -197 -451 750 142 117 -415 501 239 -451 -2178 -2370 -411 -535 -1790 -1044 -1706 -1715 -626 -623 782 510 1212 1348 272 -132 -1191 -234 -1302 -242 214 1421 330 -578 -674 -1293 -1129 -757 -1131 -1216 -590 -816 262 1158 688 543 1056 -73 493 -277 85 -90 743 20 -500 315 813 601 272 -26 -240 674 29 424 338 -182 -21 292 -635 172 -335 535 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