File name: Pandora185s1_EastProvidenceRI_20231013_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20240123T204113.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231013_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231013 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231013T114532.1Z 8686.489955 87 1 49.67 2 81.77 108.25 68.90 112.20 0.00 1 0.00 1 0 17 5.537e-01 1.556e-02 3.443e-01 8.087e-03 7.273500e-01 4.695859e-03 8.424126e-03 -6.000000e+00 3.264970e-01 226.05 -2.00 3.53 -2.00 321.95 0.00e+00 4.689718e-03 2.834766e-03 5.276863e-03 -6.000000e+00 1.609697e-02 283.81 -2.00 20.00 -2.00 321.44 0.00e+00 6.549 0.005 302.00 328.00 3 1.2298e+00 1.8666e-02 7.9741e-02 -6.0000e+00 8.1005e-01 2.8230e-01 2.7949e-02 5.0499e-02 -6.0000e+00 8.8435e-01 -3.8873e-01 2.8965e-02 2.8099e-02 -6.0000e+00 5.2291e-01 1.5068e-01 1.3019e-02 9.0265e-03 -6.0000e+00 2.2120e-01 1.1629e-04 -4.0742e-04 2.5020e-04 1.7156e-04 -6.0000e+00 1.6423e-02 3.1360e-03 0.0000e+00 12 8 8 10 0 0 99.84 23.25 0.50 0.00314 0.00007 57 12 1 5 0 871.270 27.15 20.00 23.25 16.35 20.5 928.71 -111152 900000 -232385 900000 -222497 900000 -252257 900000 -111147 -215698 -83574 900000 -89424 -144719 67924 2484 900000 -5666 900000 -103907 900000 -77016 900000 -116467 92622 -74928 900000 -42321 36874 -20439 -45011 66341 -45959 110663 -12111 79107 -25540 82083 -13930 48521 -14721 57841 -15203 58174 27463 43422 19468 39491 50193 18259 20111 -9779 17351 -9579 35170 -683 15776 3386 19840 12424 3460 13032 11050 10029 -4424 18108 -2195 15273 -1005 9201 3892 12372 -2618 9828 -1971 -34 -3822 -2577 375 -1983 1145 -3650 47 -3815 1519 -1556 4242 -442 3697 -1434 1688 -203 -3712 -397 -2613 941 -650 706 -2403 1335 -2712 -125 -1117 -1533 -4131 -1924 -1150 -102 73 1663 -95 -1516 -115 -892 528 -239 546 117 1279 -475 2214 1315 1428 247 -252 634 563 703 -452 -18 -760 217 -130 -42 -468 581 778 544 -248 -821 -531 -440 -875 900000 -3505 900000 -2627 900000 -4467 900000 -875 -3395 -658 900000 -704 -2563 535 20 900000 -45 900000 -2385 900000 -1364 900000 -3833 729 -1769 900000 -696 290 -336 -1159 664 -1578 871 -286 792 -841 1116 -598 1284 -800 1614 -914 1706 1120 1553 919 1610 1975 1097 1338 -972 1440 -1117 2743 -79 1546 366 1952 1340 444 1733 1713 1705 -874 2836 -435 2777 -247 2281 1075 3135 -732 2220 -450 -7 -833 -619 104 -670 433 -1614 22 -1933 779 -867 2304 -252 1967 -754 808 -96 -1879 -218 -1715 698 -567 669 -2386 1210 -2320 -95 -846 -1242 -3651 -1764 -1130 -109 88 2224 -139 -2283 -166 -1246 701 -322 765 174 1952 -731 3194 1844 1935 326 -324 791 740 1047 -775 -33 -1559 468 -300 -103 -1221 1537 2085 1453 -641 -2000 -1213 -978 SS 20231013T123515.1Z 8686.524480 111 1 38.36 2 73.24 117.36 61.00 122.44 0.00 1 0.00 1 0 17 6.052e-02 6.447e-03 1.623e-02 1.103e-03 4.179936e-01 5.610815e-04 4.912617e-03 -6.000000e+00 3.489436e-02 226.05 -2.00 3.53 -2.00 319.64 0.00e+00 1.938461e-03 1.652429e-04 1.032894e-03 -6.000000e+00 1.561189e-03 283.80 -2.00 20.00 -2.00 318.92 0.00e+00 3.414 0.001 302.00 328.00 3 1.5015e+00 1.6001e-03 4.0314e-02 -6.0000e+00 8.6279e-02 3.2598e-02 1.9059e-03 2.1921e-02 -6.0000e+00 9.3806e-02 -8.4713e-03 1.5283e-03 1.1289e-02 -6.0000e+00 5.5986e-02 -8.8472e-03 7.9613e-04 3.5940e-03 -6.0000e+00 2.3782e-02 2.4125e-03 8.4217e-05 3.3490e-05 4.2385e-05 -6.0000e+00 1.7187e-03 4.3726e-03 0.0000e+00 12 9 1 12 1 1 99.66 23.01 0.30 0.00437 0.00501 168 47 1 5 0 226.870 26.83 20.00 23.01 17.16 20.8 935.58 -27134 -10683 -16066 -18221 -23462 -27773 -17508 -19932 -12472 -16540 -15765 -16867 -6936 -11446 -243 -5497 -2726 -1440 -194 -1078 -2117 -2989 -3060 -1496 -4302 -3710 -5448 -2930 -5437 540 -2196 1333 -2179 -3697 -4188 -5209 -3353 -2222 -1042 -1528 -533 -857 222 -56 953 -313 330 -1113 389 765 736 1171 1482 1366 1171 1108 -102 -79 -81 1325 1988 2795 2567 1527 339 210 -377 498 1244 915 1298 850 903 -49 -494 -1624 -2053 -1732 -1342 -1408 -1558 -1947 -1628 -694 -398 342 477 1024 833 904 178 -279 -440 -350 -588 308 845 173 -349 -896 -1251 -970 -340 -1132 -1159 -919 -563 102 929 698 551 454 14 -220 42 170 80 336 -164 -50 452 711 475 420 -367 -64 732 251 -156 -269 -222 -384 106 -52 -105 281 550 66 11 -212 -475 -331 -565 -206 -328 -351 -445 -565 -356 -470 -299 -429 -422 -523 -235 -490 -11 -289 -165 -92 -13 -75 -150 -217 -236 -122 -380 -335 -489 -245 -465 47 -224 147 -270 -457 -502 -668 -487 -384 -213 -357 -132 -224 59 -15 257 -86 90 -310 109 229 241 413 558 543 481 467 -44 -33 -34 556 890 1374 1387 867 187 111 -197 273 766 629 938 620 634 -32 -296 -897 -1098 -976 -858 -1033 -1287 -1599 -1410 -635 -389 350 505 1085 857 867 158 -256 -399 -308 -582 343 1049 232 -472 -1150 -1477 -1064 -375 -1350 -1468 -1221 -789 151 1365 1105 902 732 21 -315 62 250 123 502 -260 -80 705 1075 755 638 -538 -90 1044 391 -244 -451 -390 -698 201 -106 -205 564 1120 134 22 -438 -942 -642 SS 20231013T123951.5Z 8686.527679 114 1 49.54 2 72.49 118.26 60.31 123.46 0.00 1 0.00 1 0 17 4.549e-02 6.309e-03 5.298e-03 4.001e-04 4.016722e-01 2.023293e-04 4.716086e-03 -6.000000e+00 2.622881e-02 226.05 -2.00 3.53 -2.00 319.49 0.00e+00 1.909778e-03 5.702764e-05 9.224858e-04 -6.000000e+00 1.173365e-03 283.80 -2.00 20.00 -2.00 318.77 0.00e+00 3.275 0.001 302.00 328.00 3 -1.1802e-01 5.7339e-04 3.8659e-02 -6.0000e+00 6.4853e-02 3.0800e-02 6.7816e-04 2.0947e-02 -6.0000e+00 7.0508e-02 -4.5742e-03 5.3047e-04 1.0762e-02 -6.0000e+00 4.2081e-02 -1.0357e-02 2.7762e-04 3.4549e-03 -6.0000e+00 1.7878e-02 1.4194e-02 1.3852e-04 1.2129e-05 4.0694e-05 -6.0000e+00 1.2917e-03 3.4974e-03 0.0000e+00 10 0 0 10 0 0 -12.61 22.99 0.26 0.00350 0.00454 1167 254 1 5 0 42.190 26.83 20.00 22.99 17.55 20.8 938.66 -18191 -9316 -14985 -14761 -20251 -13050 -16861 -10827 -12872 -14157 -11886 -11292 -7248 -5617 -2731 -2797 -1011 -1577 74 -1561 -218 -1006 -127 -1816 -1740 -2640 -3891 -3580 -3439 -1223 -1167 473 -2084 -3840 -5283 -3904 -3513 -1616 -1171 -1122 -985 -630 -333 54 417 -73 12 -662 -118 472 913 1042 1323 1015 1281 937 203 -197 -68 1013 1753 2711 2573 1339 442 140 -451 858 992 920 1058 834 848 147 -604 -1450 -1954 -1615 -1341 -1379 -1347 -2086 -1628 -835 -425 261 591 1052 897 753 210 -392 -296 -296 -423 388 901 112 -422 -798 -1270 -798 -264 -1222 -1257 -969 -541 133 849 739 546 414 -2 -141 -61 116 185 343 -76 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