File name: Pandora185s1_EastProvidenceRI_20231113_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20231114T043816.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231113_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231113T123529.8Z 8717.524651 70 1 48.66 2 80.57 124.65 84.19 125.77 0.00 1 0.00 1 0 17 5.488e-01 1.919e-02 3.512e-01 1.061e-02 7.235597e-01 6.031552e-03 8.412434e-03 -6.000000e+00 3.196142e-01 223.22 -2.00 3.53 -2.00 321.88 0.00e+00 8.116860e-03 3.442390e-03 3.783051e-03 -6.000000e+00 1.524195e-02 279.97 -2.00 20.00 -2.00 321.39 0.00e+00 5.810 0.004 302.00 328.00 3 2.3469e+00 2.2687e-02 7.0587e-02 -6.0000e+00 7.9025e-01 3.6646e-01 3.2210e-02 4.1784e-02 -6.0000e+00 8.6579e-01 -5.8173e-01 3.2456e-02 2.4897e-02 -6.0000e+00 5.1332e-01 2.4040e-01 1.4893e-02 1.0388e-02 -6.0000e+00 2.1588e-01 7.5796e-05 -5.6648e-04 3.2394e-04 1.8297e-04 -6.0000e+00 1.6003e-02 4.8929e-03 0.0000e+00 12 8 8 10 0 0 98.60 23.14 0.34 0.00489 0.00064 39 9 1 5 0 1247.460 26.94 20.00 23.14 5.40 19.9 883.04 -231533 64361 -188024 900000 -105120 900000 -225556 -94839 -178844 900000 -185700 -69547 900000 -112233 -48633 -97141 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4244 -125 3661 447 2131 1698 3593 1199 3121 -218 1468 -273 -7 426 -969 448 83 1761 -3964 934 -1576 394 -681 1396 -682 848 -84 -383 157 -3134 -1388 -2655 -896 17 945 -2068 -543 -1911 -1043 -3184 -1665 -1634 -940 -1470 -1114 446 637 1117 -430 844 -2149 1305 -1040 882 -2111 509 133 3251 1383 1914 3506 23 783 -66 1862 -1360 4641 -1382 837 -2106 1751 -1113 1383 489 -424 33 -195 -3089 -1125 SS 20231113T124531.3Z 8717.531612 76 1 48.72 2 79.05 126.52 82.77 127.54 0.00 1 0.00 1 0 17 5.696e-01 1.236e-02 3.879e-01 9.520e-03 6.686235e-01 5.262388e-03 7.688170e-03 -6.000000e+00 3.288973e-01 223.22 -2.00 3.53 -2.00 321.58 0.00e+00 1.427813e-03 2.782207e-03 3.901493e-03 -6.000000e+00 1.580045e-02 279.96 -2.00 20.00 -2.00 321.06 0.00e+00 5.075 0.002 302.00 328.00 3 3.0984e+00 1.8838e-02 6.4402e-02 -6.0000e+00 8.1550e-01 8.0629e-02 2.7091e-02 4.3703e-02 -6.0000e+00 8.9218e-01 -1.5421e-01 2.8811e-02 2.2395e-02 -6.0000e+00 5.2630e-01 5.8339e-02 1.3440e-02 6.3715e-03 -6.0000e+00 2.2259e-01 7.8672e-05 -6.3652e-04 2.9048e-04 1.1442e-04 -6.0000e+00 1.6387e-02 4.5220e-03 0.0000e+00 12 8 8 10 0 0 99.96 23.14 0.64 0.00452 -0.00026 26 6 1 5 0 1873.630 26.94 20.00 23.14 5.85 20.0 885.94 -208143 -127118 -137657 -200048 -241106 62716 -120131 900000 900000 -88287 900000 -121324 -148613 -71494 -64797 -49468 -85228 900000 18306 58036 -29787 61847 -68331 113331 102296 2202 -24638 -27383 -3341 699 -33519 -4640 52098 346843 -27244 -30364 12792 -15137 20514 1393 12084 -9962 -408 17065 -14012 -11566 20428 3994 -5919 1319 1004 -1738 6703 5852 8863 1563 9564 -2247 1171 -1402 445 2284 5716 2431 1237 4696 2928 7392 3050 5227 3961 3049 2298 181 502 -3643 -3288 -6864 -5126 -4028 1345 -112 -1099 -241 1702 2136 -18 316 -291 3871 421 -1506 -6380 -2726 -333 -887 709 159 -237 -56 -836 -2507 -352 -816 -2617 -2332 -734 229 716 1762 1834 -28 -1043 535 -995 -989 4 361 422 561 57 872 1438 34 202 -800 1106 217 491 -1298 267 -302 128 -303 -291 277 986 -228 139 -573 -212 -233 -2252 -1179 -1277 -2165 -3727 582 -1114 900000 900000 -819 900000 -1219 -2527 -718 -751 -574 -1581 900000 170 538 -427 574 -1613 1051 949 32 -457 -508 -51 12 -961 -117 835 3217 -942 -1152 367 -702 813 78 662 -722 -28 993 -1134 -936 1240 300 -524 120 103 -204 791 750 1274 251 1428 -369 181 -226 76 436 1198 568 293 1059 690 1810 894 1677 1363 1061 768 57 141 -987 -887 -2114 -1831 -1678 611 -57 -608 -141 1044 1373 -12 214 -193 2302 242 -851 -3876 -1772 -245 -761 688 169 -257 -57 -783 -2179 -297 -735 -2551 -2397 -798 270 943 2549 2825 -44 -1621 778 -1407 -1402 6 556 676 890 88 1284 2032 47 268 -1045 1481 329 837 -2481 537 -646 289 -734 -740 718 2576 -599 350 -1364 -474 -507 SS 20231113T125112.0Z 8717.535556 79 1 48.69 2 78.21 127.60 81.97 128.56 0.00 1 0.00 1 0 25 3.752e-01 1.021e-02 2.167e-01 5.206e-03 6.157793e-01 2.787420e-03 7.255417e-03 -6.000000e+00 2.140149e-01 223.22 -2.00 3.53 -2.00 321.21 0.00e+00 2.526912e-03 1.353005e-03 3.571109e-03 -6.000000e+00 9.749406e-03 279.96 -2.00 20.00 -2.00 320.69 0.00e+00 4.741 0.002 302.00 328.00 3 2.6322e+00 9.4061e-03 5.9366e-02 -6.0000e+00 5.2646e-01 4.3494e-02 1.3038e-02 3.9255e-02 -6.0000e+00 5.7404e-01 -9.7913e-02 1.3515e-02 2.0193e-02 -6.0000e+00 3.4299e-01 3.2050e-02 6.4440e-03 5.7436e-03 -6.0000e+00 1.4816e-01 1.8229e-04 -3.4355e-04 1.5555e-04 1.0530e-04 -6.0000e+00 1.0679e-02 4.6103e-03 0.0000e+00 12 8 8 10 0 0 98.52 23.14 0.22 0.00461 0.00203 37 8 1 5 0 1315.790 26.94 20.00 23.14 5.95 19.9 887.06 900000 900000 99781 -31984 -151980 -102921 -180468 -154776 -137341 -111378 -129557 -34190 -88905 -64917 -41188 -29710 -78051 -49135 -40493 -44866 -7378 -32771 -5466 -24991 24301 5834 -13430 -68410 -29497 -25644 -12366 4816 6547 -7929 9499 3142 -3142 2759 -6577 3672 -2344 -3138 -3145 -7524 2161 4483 6252 8827 5454 -1452 -3487 2580 5443 3290 9275 3709 1260 -889 849 -3172 6171 6151 5889 3587 2859 3178 1999 179 605 3205 1405 624 1389 38 676 -620 -4113 -5056 -1750 590 271 -2450 -1815 -132 -520 924 853 1382 518 1315 -1451 -656 79 -1321 -387 -980 191 842 -566 -1391 -1375 661 -1423 -3363 -2609 -1792 -846 435 1372 1680 1201 1102 88 -383 -47 -527 -132 -514 -347 93 529 916 261 680 -304 -114 1136 377 85 -413 -503 -231 -137 -71 -254 447 452 183 -41 -248 -547 -142 900000 900000 506 -162 -1414 -609 -2594 -1963 -1626 -1083 -1643 -202 -1271 -928 -570 -425 -2016 -1043 -841 -1014 -116 -680 -93 -565 359 108 -297 -2556 -776 -745 -376 144 214 -300 294 110 -136 137 -437 254 -188 -269 -280 -711 208 432 609 873 592 -186 -510 391 875 579 1609 704 247 -174 160 -636 1221 1376 1491 996 793 861 559 55 212 1223 578 259 546 14 222 -191 -1302 -1767 -694 268 142 -1455 -1142 -87 -368 680 649 1050 385 908 -962 -413 50 -938 -314 -922 203 971 -669 -1564 -1405 607 -1327 -3414 -2791 -2009 -1006 558 1941 2616 1989 1833 143 -590 -69 -780 -203 -840 -590 157 861 1435 398 988 -430 -156 1605 599 152 -812 -958 -460 -289 -161 -603 1079 1109 447 -97 -553 -1160 -293 SS 20231113T125605.6Z 8717.538954 82 1 23.66 2 77.49 128.53 81.30 129.45 0.00 1 0.00 1 0 17 3.692e-01 1.367e-02 1.834e-01 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