File name: Pandora185s1_EastProvidenceRI_20231118_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20231119T043703.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231118_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231118T184404.1Z 8722.780603 286 1 0.53 2 68.48 213.91 76.94 142.11 0.00 1 0.00 1 0 17 2.409e-02 8.373e-03 1.483e-02 3.620e-03 3.352918e-01 1.815824e-03 4.053039e-03 -6.000000e+00 1.371537e-02 223.00 -2.00 3.53 -2.00 317.67 0.00e+00 1.093676e-03 2.961661e-04 2.712836e-04 -6.000000e+00 6.099754e-04 279.36 -2.00 20.00 -2.00 317.00 0.00e+00 2.701 0.000 302.00 328.00 3 8.9575e-01 4.7865e-03 3.1726e-02 -6.0000e+00 3.3731e-02 1.7516e-02 5.4233e-03 1.7000e-02 -6.0000e+00 3.6794e-02 -4.3854e-03 3.4054e-03 8.4810e-03 -6.0000e+00 2.1952e-02 -5.2047e-03 1.7340e-03 2.4956e-03 -6.0000e+00 9.3366e-03 9.8827e-03 -1.0792e-03 1.0675e-04 2.8529e-05 -6.0000e+00 6.8343e-04 1.1083e-02 0.0000e+00 12 9 1 12 1 1 27.26 23.11 0.30 0.01108 0.00297 4 102 1 5 0 104.690 26.94 20.00 23.11 18.06 21.1 977.00 -6379 -2387 -2656 -6462 -2836 -9883 4994 -13010 1515 -7443 -170 -9973 -5152 -2562 3121 1045 -535 1689 434 1829 -126 3307 -916 1961 406 1043 -3833 224 -2984 592 -606 1594 -1013 -3297 -1628 -4940 -2533 -448 349 -994 -681 -758 78 -1426 1351 360 -197 118 -522 1296 403 1820 1673 2194 605 1274 628 1241 -59 1666 1457 2235 2718 637 -222 -732 406 810 873 492 652 -70 795 -776 -1107 -1142 -1102 -1795 -1259 -1890 -1629 -2658 -2140 -540 -235 -52 252 1336 662 479 163 -395 -718 -221 -79 178 885 29 -321 -1332 -1055 -653 -108 -941 -346 -1302 -773 8 869 1105 541 632 -5 363 -90 174 107 605 -272 109 19 1077 327 657 -96 274 1049 216 -199 -171 185 -495 582 -374 198 26 369 -142 -56 -225 -279 -1063 -511 -197 -218 -504 -197 -750 360 -1263 139 -765 -17 -1190 -687 -392 517 175 -96 313 85 365 -26 659 -201 444 98 256 -957 51 -680 138 -157 446 -311 -1010 -470 -1553 -891 -169 156 -468 -341 -396 41 -770 713 191 -104 62 -277 710 241 1067 1044 1426 410 878 438 844 -40 1137 1065 1657 2175 535 -179 -556 297 619 749 440 616 -67 730 -676 -934 -874 -859 -1365 -1072 -1725 -1558 -2781 -2219 -587 -273 -61 302 1596 772 551 173 -412 -729 -236 -89 211 1101 39 -432 -1710 -1307 -755 -126 -1192 -439 -1752 -1037 12 1248 1686 815 970 -7 509 -126 240 147 880 -404 164 28 1616 475 906 -134 364 1401 298 -298 -259 290 -767 931 -614 339 46 636 -248 -98 -381 -474 -1786 SS 20231118T184814.0Z 8722.783496 289 1 50.45 2 68.91 214.86 76.47 142.93 0.00 1 0.00 1 0 17 2.374e-02 6.509e-03 2.142e-03 2.794e-04 3.414861e-01 1.408615e-04 4.117997e-03 -6.000000e+00 1.353351e-02 223.00 -2.00 3.53 -2.00 318.76 0.00e+00 1.455146e-03 3.098446e-05 5.093389e-04 -6.000000e+00 6.010772e-04 279.36 -2.00 20.00 -2.00 318.10 0.00e+00 2.753 0.000 302.00 328.00 3 -1.0765e-01 3.8282e-04 3.2411e-02 -6.0000e+00 3.3286e-02 1.4864e-02 4.3987e-04 1.7482e-02 -6.0000e+00 3.6290e-02 2.0308e-03 3.0992e-04 8.9074e-03 -6.0000e+00 2.1651e-02 -9.1633e-03 1.6347e-04 2.8476e-03 -6.0000e+00 9.2232e-03 2.5380e-02 1.4906e-04 8.4768e-06 3.2228e-05 -6.0000e+00 6.7345e-04 1.3240e-03 0.0000e+00 11 8 0 10 0 0 30.51 23.14 0.28 0.00132 0.00244 1586 346 1 5 0 31.050 26.94 20.00 23.14 18.38 21.4 980.92 -5867 -4813 -5740 -9240 -7985 -9787 -5954 -6865 -5294 -8979 -6589 -6114 -2809 -1741 -517 -1095 87 177 224 656 -583 884 -155 -30 -1328 -1070 -2740 -2186 -2264 -119 92 1292 -811 -3632 -3486 -3905 -2381 -1478 -675 -1214 -609 -719 -165 -13 500 44 21 -521 -292 636 598 1014 1163 1141 1000 1089 168 86 -44 1025 1548 2469 2436 1145 414 -48 -325 701 1099 690 1033 596 829 81 -386 -1362 -1770 -1429 -1292 -1390 -1500 -2136 -1717 -750 -544 211 456 983 663 703 181 -326 -254 -158 -367 361 922 123 -386 -858 -1192 -883 -206 -1199 -1170 -913 -513 99 764 782 573 457 16 -83 -58 135 149 329 -118 -85 358 589 390 493 -140 28 790 255 17 -250 -261 -288 199 8 -50 268 475 14 -96 -217 -522 -509 -227 -198 -238 -362 -286 -363 -234 -306 -253 -458 -369 -380 -199 -144 -49 -113 9 20 27 81 -73 110 -20 -4 -198 -163 -412 -308 -314 -17 15 224 -154 -692 -636 -753 -518 -382 -206 -420 -224 -276 -64 -5 196 17 8 -203 -115 261 265 480 585 601 543 603 95 47 -24 566 908 1575 1534 752 261 -31 -208 465 743 519 818 478 641 59 -280 -907 -1127 -943 -959 -1068 -1288 -2000 -1688 -779 -605 246 503 1185 778 768 183 -306 -232 -152 -393 430 1119 161 -507 -1071 -1497 -1036 -243 -1538 -1461 -1193 -703 143 1180 1288 896 756 25 -120 -79 184 210 494 -189 -139 573 914 582 700 -191 36 1037 361 26 -410 -445 -503 335 14 -93 515 931 27 -184 -401 -930 -888 SS 20231118T185403.2Z 8722.787537 292 1 50.20 2 69.54 216.16 75.84 144.07 0.00 1 0.00 1 0 17 2.634e-02 6.443e-03 3.246e-03 3.643e-04 3.498804e-01 1.827224e-04 4.165047e-03 -6.000000e+00 1.501471e-02 223.00 -2.00 3.53 -2.00 319.03 0.00e+00 1.508016e-03 4.354906e-05 6.282578e-04 -6.000000e+00 6.668923e-04 279.36 -2.00 20.00 -2.00 318.37 0.00e+00 2.832 0.000 302.00 328.00 3 1.7383e-01 5.0123e-04 3.3267e-02 -6.0000e+00 3.6929e-02 1.5049e-02 5.8040e-04 1.7858e-02 -6.0000e+00 4.0262e-02 4.2963e-03 4.2594e-04 9.1409e-03 -6.0000e+00 2.4021e-02 -1.0291e-02 2.2442e-04 2.9339e-03 -6.0000e+00 1.0232e-02 1.7534e-02 1.0216e-04 1.1105e-05 3.4011e-05 -6.0000e+00 7.4719e-04 1.6381e-03 0.0000e+00 11 8 0 10 0 0 99.99 23.17 0.26 0.00164 0.00241 1519 331 1 5 0 32.420 27.05 20.00 23.17 19.28 21.4 987.66 -7594 -4594 -7962 -9441 -9139 -8912 -8175 -6926 -7209 -9889 -7899 -6628 -3701 -2960 -220 -1352 258 -353 660 164 -272 112 -182 -814 -1683 -1636 -2695 -2476 -2116 -534 -144 1058 -1098 -3548 -3656 -3749 -2643 -1337 -835 -1130 -765 -795 -478 -26 430 50 10 -634 -107 528 737 1032 1121 1010 1040 959 154 54 -59 1010 1624 2546 2415 1283 394 59 -425 664 1055 727 1010 660 852 99 -523 -1395 -1787 -1397 -1414 -1531 -1497 -2117 -1725 -834 -509 224 516 969 740 741 186 -393 -329 -202 -377 345 885 121 -414 -838 -1274 -916 -283 -1201 -1172 -890 -506 162 868 830 609 462 54 -96 -104 59 121 267 -95 -125 381 570 427 455 -233 -64 726 190 -49 -267 -323 -343 166 7 -71 319 492 70 -65 -188 -508 -512 -255 -161 -289 -318 -284 -281 -282 -266 -303 -439 -352 -326 -209 -197 -16 -123 24 -36 69 18 -30 12 -21 -102 -223 -222 -359 -311 -260 -69 -21 165 -188 -607 -601 -650 -519 -311 -230 -352 -255 -276 -169 -9 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