File name: Pandora185s1_EastProvidenceRI_20231120_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20231121T043858.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231120_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231120T122705.4Z 8724.518812 63 1 26.78 2 83.37 124.02 148.31 42.95 0.00 1 0.00 1 0 25 6.309e-01 4.111e-02 4.639e-01 3.230e-02 8.330978e-01 1.880064e-02 9.302811e-03 -6.000000e+00 3.724773e-01 222.97 -2.00 3.53 -2.00 322.16 0.00e+00 -1.327888e-03 9.666202e-03 3.142715e-03 -6.000000e+00 1.916386e-02 279.16 -2.00 20.00 -2.00 321.67 0.00e+00 7.884 0.009 302.00 328.00 3 1.5156e+00 6.9311e-02 9.1358e-02 -6.0000e+00 9.1779e-01 1.2463e+00 8.7498e-02 4.9176e-02 -6.0000e+00 1.0061e+00 -1.5519e+00 6.8794e-02 2.4576e-02 -6.0000e+00 5.9418e-01 5.8704e-01 3.3620e-02 7.1141e-03 -6.0000e+00 2.5231e-01 1.9143e-05 -8.2031e-04 9.7504e-04 1.2245e-04 -6.0000e+00 1.8337e-02 6.2200e-03 0.0000e+00 12 9 9 12 1 1 97.96 22.82 0.67 0.00622 0.00006 8 4 1 5 0 2974.730 26.62 19.99 22.82 8.19 20.3 910.44 -17923 900000 111764 -44891 900000 -77935 900000 -1574 900000 -110828 900000 163918 56462 -15449 900000 5687 900000 10817 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4442 -965 4142 2847 6958 3220 1534 -3682 634 3740 4083 4322 -5289 5080 -2158 4117 -325 4749 3884 3769 5051 4847 4972 658 5671 -2007 7282 -3618 5435 -955 6384 -1846 -658 -4595 384 -622 -2924 8940 3527 8408 -3492 -3358 4874 3840 -5905 -1119 -2446 3062 -5592 -5648 -1879 -3069 3643 -4466 4625 -4139 958 -10034 3181 -6723 1194 366 8738 -3011 2301 -1654 1377 812 -4393 483 20 -2428 -433 3646 1953 -1190 1078 217 7309 10407 -3217 -1028 1653 2399 -6036 1609 3309 -3203 1746 -102 2163 847 -970 -6219 SS 20231120T123731.8Z 8724.526063 66 1 49.69 2 81.78 125.90 146.97 46.65 0.00 1 0.00 1 0 17 5.548e-01 2.200e-02 3.375e-01 1.216e-02 7.242426e-01 6.984730e-03 8.592676e-03 -6.000000e+00 3.239249e-01 222.97 -2.00 3.53 -2.00 321.92 0.00e+00 -1.265348e-03 3.958938e-03 9.219841e-03 -6.000000e+00 1.618111e-02 279.16 -2.00 20.00 -2.00 321.43 0.00e+00 6.564 0.005 302.00 328.00 3 1.7514e+00 2.6448e-02 9.1763e-02 -6.0000e+00 8.0472e-01 4.3248e-01 3.7713e-02 8.0020e-02 -6.0000e+00 8.8328e-01 -6.6997e-01 3.7569e-02 3.2757e-02 -6.0000e+00 5.2201e-01 2.8005e-01 1.7195e-02 6.7767e-03 -6.0000e+00 2.2118e-01 6.9748e-05 -2.0593e-04 3.8003e-04 1.5693e-04 -6.0000e+00 1.6196e-02 6.1490e-03 0.0000e+00 12 8 8 10 0 0 97.27 22.78 0.54 0.00615 0.00460 47 10 1 5 0 1056.920 26.62 19.99 22.78 8.66 20.2 913.43 -161535 900000 900000 -190381 -160671 -197486 900000 -154613 900000 -160440 900000 -152592 900000 -71428 101840 57841 900000 900000 900000 900000 -74594 900000 -44848 175349 -85526 97521 -1043 121281 -49269 19656 -49743 64586 117691 26355 -9046 58707 119727 -27885 78780 601 114509 -18686 88674 20624 80646 10454 31922 14961 36000 27488 5142 27439 7931 60564 10580 57613 6436 39163 -6792 12458 1596 11366 6787 17477 11793 22032 19450 5640 16450 7890 8213 -2479 12049 -6612 7138 -6911 7134 -8251 -3228 2403 3560 -3231 -4379 760 -2492 6993 -2380 6438 -4139 2889 -2999 -1549 -4938 2168 -5062 -3791 -957 2110 -2278 -1590 -1579 -3931 -468 -6802 759 -3083 269 -3862 1758 1770 1525 401 -776 -867 -624 831 -490 1542 -581 1942 201 2926 889 1532 -9 471 1541 139 133 -627 152 -1158 1416 -957 732 -433 1142 -837 651 -781 -553 -580 -2939 900000 900000 -4691 -2692 -4866 900000 -3047 900000 -3795 900000 -4211 900000 -1337 1204 684 900000 900000 900000 900000 -2279 900000 -1105 2074 -3624 1153 -20 1434 -1483 338 -2032 972 1392 623 -292 1010 1416 -1589 1863 36 2339 -1507 2479 1131 2428 641 1613 933 1935 1773 464 2183 836 4037 1217 4274 796 3368 -891 1353 208 1515 1073 2668 2092 3491 3266 1187 3560 2071 2263 -756 3007 -1814 1528 -1577 1426 -2137 -943 784 1326 -1433 -2102 370 -1338 3589 -1382 3426 -2369 1445 -1497 -740 -2535 1164 -3406 -2941 -832 1954 -2231 -1463 -1316 -3064 -350 -5784 637 -2851 260 -4302 2096 2363 2189 591 -1132 -1209 -839 1109 -693 2261 -901 2908 294 4031 1211 1998 -11 590 2014 209 226 -1195 308 -2529 3215 -2381 1881 -1151 3031 -2247 1645 -1876 -1247 -1273 SS 20231120T124739.4Z 8724.533095 69 1 49.21 2 80.27 127.77 145.60 50.01 0.00 1 0.00 1 0 17 4.942e-01 9.231e-03 3.348e-01 6.186e-03 6.478449e-01 3.347404e-03 7.782302e-03 -6.000000e+00 2.815417e-01 222.97 -2.00 3.53 -2.00 321.51 0.00e+00 5.278319e-03 1.738193e-03 4.335296e-03 -6.000000e+00 1.250339e-02 279.16 -2.00 20.00 -2.00 320.99 0.00e+00 5.652 0.003 302.00 328.00 3 1.8471e+00 1.1727e-02 6.7934e-02 -6.0000e+00 6.9244e-01 1.1864e-01 1.6949e-02 4.1408e-02 -6.0000e+00 7.5517e-01 -1.2587e-01 1.8374e-02 2.4729e-02 -6.0000e+00 4.5050e-01 3.7621e-02 8.5995e-03 9.0692e-03 -6.0000e+00 1.9174e-01 1.5981e-04 -3.0202e-04 1.8541e-04 1.5682e-04 -6.0000e+00 1.4021e-02 6.2022e-03 0.0000e+00 11 8 0 10 0 0 99.86 22.75 0.35 0.00620 0.00393 53 12 1 5 0 928.340 26.62 20.00 22.75 8.78 20.2 913.94 -127555 -198541 -195391 -136588 -142115 -199571 -137012 -168177 -66951 -83268 -83507 -126880 -72529 69757 -65218 19953 -24275 -31846 -46651 190990 -2920 -42832 -18909 -3675 -39576 -35876 -16030 -10742 -1569 53117 -1863 74487 38988 -9811 58580 -25346 8567 7466 13170 -1777 9011 1910 -5627 9275 1672 8580 -3094 6622 -1322 6795 -1702 4429 2462 5921 447 -109 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