File name: Pandora185s1_EastProvidenceRI_20231214_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20240123T204951.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231214_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231214T130002.2Z 8748.541692 71 1 49.92 2 82.54 130.61 100.84 118.65 0.00 1 0.00 1 0 17 5.881e-01 2.633e-02 4.261e-01 1.755e-02 9.260186e-01 1.002312e-02 9.831022e-03 -6.000000e+00 3.361658e-01 222.63 -2.00 3.53 -2.00 322.30 0.00e+00 -6.691416e-03 5.533745e-03 4.520527e-03 -6.000000e+00 1.479329e-02 276.51 -2.00 20.00 -2.00 321.86 0.00e+00 7.138 0.007 302.00 328.00 3 1.3593e+00 3.7915e-02 9.1482e-02 -6.0000e+00 8.2879e-01 1.1793e+00 5.0640e-02 6.6116e-02 -6.0000e+00 9.0522e-01 -1.5641e+00 4.3376e-02 3.0664e-02 -6.0000e+00 5.3685e-01 6.1057e-01 2.0546e-02 9.4839e-03 -6.0000e+00 2.2734e-01 4.2624e-05 -7.4340e-04 4.8903e-04 1.2895e-04 -6.0000e+00 1.6858e-02 6.8274e-03 0.0000e+00 12 8 8 10 0 0 86.03 23.10 0.39 0.00683 0.00124 34 7 1 5 0 1468.060 26.94 20.00 23.10 5.40 20.0 915.33 -25736 27240 -56015 -17787 8137 75081 -102045 900000 -71912 233687 -157749 10887 -78533 -9918 298040 6702 -50670 12591 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1908 3852 3994 2269 3038 2779 3330 2518 5497 4203 3765 -664 3585 1728 3868 -3591 1932 2115 633 -2111 1038 -1666 1099 1546 -241 -182 938 -1788 -380 814 -4391 4302 -2088 -1895 -1253 -2864 -1525 -2931 -4958 -561 -1313 -2847 -2782 -892 -2421 -802 -955 568 -344 -2180 -1356 1352 -416 -1353 -1060 -716 -412 2783 -297 3198 3940 5377 3217 2232 -1025 3716 -2296 950 -140 185 -29 41 1724 -481 4159 -236 1169 -1238 -1598 -3411 -3242 SS 20231214T131031.3Z 8748.548973 74 1 49.01 2 81.08 132.54 99.21 120.17 0.00 1 0.00 1 0 25 6.065e-01 1.843e-02 3.479e-01 9.917e-03 8.365370e-01 5.677257e-03 9.263581e-03 -6.000000e+00 3.476633e-01 222.63 -2.00 3.53 -2.00 322.06 0.00e+00 6.243136e-03 3.218928e-03 2.594333e-03 -6.000000e+00 1.682077e-02 276.51 -2.00 20.00 -2.00 321.61 0.00e+00 6.108 0.004 302.00 328.00 3 1.9297e+00 2.1204e-02 7.5845e-02 -6.0000e+00 8.5753e-01 5.7095e-01 3.1141e-02 4.6880e-02 -6.0000e+00 9.3831e-01 -7.4212e-01 3.2888e-02 2.7157e-02 -6.0000e+00 5.5825e-01 2.9111e-01 1.5034e-02 1.1930e-02 -6.0000e+00 2.3717e-01 7.2264e-05 -6.9360e-04 2.8837e-04 1.9510e-04 -6.0000e+00 1.7628e-02 6.0415e-03 0.0000e+00 12 8 8 10 0 0 98.07 23.10 0.38 0.00604 0.00083 30 7 1 5 0 1633.430 26.94 20.00 23.10 5.61 20.0 916.91 -244618 -140301 -196588 900000 -131782 -222328 -225650 -148882 -231242 900000 -186841 900000 900000 -105051 -60874 900000 -90711 140598 900000 -49663 21562 -89098 7171 -28190 -40284 8795 123976 -61811 71802 -68056 -19741 28796 -21967 48841 -46489 41993 25913 21387 5490 16237 21797 68472 196 99562 73500 32255 48249 10415 30045 18019 34430 7013 37765 14269 31392 2631 27336 9694 24884 8539 19523 10283 18535 17304 19310 14537 3766 24645 2702 11566 9072 11758 4787 -1725 6730 -2997 -1640 4659 2302 881 -1257 -5821 -2859 -3022 -2250 179 1318 -2658 3509 2357 2513 -2480 -3704 -2577 -1897 -2138 -2 -1199 -2159 1532 -2236 2006 -2998 -1443 -3432 -1269 -1656 665 585 -1741 390 -609 -1155 -947 -733 -656 643 2192 622 259 2620 1011 2343 476 80 -1037 1023 1712 521 333 -944 -261 130 -93 -192 813 812 -177 245 -743 -631 -1288 -6103 -1355 -3323 900000 -1273 -3937 -4359 -1438 -5397 900000 -3158 900000 900000 -1691 -784 900000 -2044 1358 900000 -839 208 -2347 76 -446 -743 100 1197 -1357 693 -2032 -451 480 -675 729 -1714 664 546 563 202 613 842 1743 10 1923 1871 1274 1695 567 1451 1092 1995 591 2553 1303 2508 315 2535 1030 2187 891 1980 1311 2506 2590 2872 2275 684 3975 621 2703 2278 2839 1160 -403 1287 -588 -325 981 598 278 -470 -2541 -1295 -1456 -1141 93 692 -1451 1738 1107 1109 -1126 -1789 -1401 -1211 -1617 -2 -1157 -2137 1381 -1878 1451 -2227 -1116 -2870 -1102 -1566 686 691 -2387 568 -918 -1723 -1355 -1012 -913 922 3258 965 395 3717 1397 3087 617 101 -1299 1337 2556 906 648 -2021 -592 315 -240 -521 2230 2249 -491 642 -1822 -1441 -2862 SS 20231214T133251.1Z 8748.564480 86 1 11.43 2 78.12 136.80 95.82 123.49 0.00 1 0.00 1 0 17 4.851e-01 1.232e-02 2.104e-01 5.658e-03 6.774500e-01 3.002169e-03 8.408305e-03 -6.000000e+00 2.759888e-01 222.63 -2.00 3.53 -2.00 321.07 0.00e+00 8.234254e-03 1.350039e-03 4.772030e-03 -6.000000e+00 1.214011e-02 276.50 -2.00 20.00 -2.00 320.58 0.00e+00 4.710 0.002 302.00 328.00 3 1.9980e+00 9.5255e-03 6.0420e-02 -6.0000e+00 6.7890e-01 1.6958e-01 1.2956e-02 4.0115e-02 -6.0000e+00 7.4091e-01 -2.1299e-01 1.3587e-02 2.7150e-02 -6.0000e+00 4.4141e-01 8.0062e-02 6.5964e-03 1.2280e-02 -6.0000e+00 1.8756e-01 3.1016e-04 -3.9464e-05 1.5927e-04 1.8428e-04 -6.0000e+00 1.3761e-02 6.1603e-03 0.0000e+00 12 9 9 12 1 1 98.69 23.08 0.39 0.00616 0.00586 14 14 1 5 0 761.450 26.94 19.99 23.08 5.64 20.2 917.52 -235380 -53748 -214201 -167917 -178218 -114585 -149833 -140249 -171624 -131995 -122707 79042 -103236 -63130 -17392 -59024 15089 -2877 14209 -17776 -421 -38937 -37994 -6356 -12129 -36770 -42752 -21979 -31048 -1987 -10456 -20823 -24515 671 -7791 -3491 -28423 -4741 7309 8082 2077 5066 2210 10028 4285 12207 8335 2716 12831 6529 7420 4507 5449 3556 4037 1231 2425 3134 1899 -151 3552 8468 3253 6155 3993 3956 919 4627 2277 2657 2627 3454 773 1144 141 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