File name: Pandora185s1_EastProvidenceRI_20231216_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20240123T205135.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231216_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231216T130155.4Z 8750.543002 71 1 29.51 2 82.49 130.84 117.22 96.67 0.00 1 0.00 1 0 46 6.311e-01 2.990e-02 4.935e-01 2.510e-02 7.516624e-01 1.515003e-02 8.559871e-03 -6.000000e+00 3.777338e-01 222.63 -2.00 3.53 -2.00 322.13 0.00e+00 -1.218983e-02 9.025744e-03 1.253634e-02 -6.000000e+00 2.444602e-02 276.31 -2.00 20.00 -2.00 321.68 0.00e+00 7.098 0.007 302.00 328.00 3 2.4215e+00 5.8998e-02 1.1291e-01 -6.0000e+00 9.3314e-01 2.7212e-01 8.7239e-02 1.1547e-01 -6.0000e+00 1.0306e+00 -5.4532e-01 9.0557e-02 3.9357e-02 -6.0000e+00 6.0231e-01 2.2678e-01 4.0916e-02 1.0230e-02 -6.0000e+00 2.5827e-01 2.3382e-05 1.8218e-04 8.3380e-04 1.3478e-04 -6.0000e+00 1.9260e-02 5.8505e-03 0.0000e+00 12 9 9 12 9 1 -35.38 23.23 1.16 0.00585 0.00722 9 4 1 5 0 2949.900 27.05 20.00 23.23 11.60 20.4 962.69 900000 -19445 900000 900000 900000 900000 900000 -212656 900000 900000 -182018 900000 900000 -182918 900000 900000 -96828 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1641 3745 1948 2196 1763 1065 3160 946 4565 3824 2071 1419 -3318 -3714 912 75 1147 -900 5300 5373 3035 3671 -1799 2174 2571 2999 1855 -112 5636 1303 -926 1999 -702 3927 1293 902 132 -816 484 693 -3056 3249 -1726 2834 -1987 -5281 166 -1039 -860 -534 7323 -5574 -4248 -2922 348 1211 -905 762 -6966 154 -3340 -3792 4558 -348 1311 -3435 1801 1511 -1837 -1526 1188 -632 1791 7459 3306 4175 -3216 -931 -2251 5456 -853 535 -976 2012 -819 -2025 1384 -2959 2688 2382 1826 -4498 -1727 -467 1891 -1167 SS 20231216T131231.6Z 8750.550366 74 1 50.01 2 81.02 132.80 115.33 98.22 0.00 1 0.00 1 0 17 4.870e-01 2.425e-02 3.921e-01 1.713e-02 6.831328e-01 9.524538e-03 8.393000e-03 -6.000000e+00 2.866596e-01 222.63 -2.00 3.53 -2.00 321.72 0.00e+00 8.920558e-03 4.852914e-03 5.268711e-03 -6.000000e+00 1.233833e-02 276.31 -2.00 20.00 -2.00 321.24 0.00e+00 6.071 0.004 302.00 328.00 3 2.8228e+00 3.3254e-02 7.2336e-02 -6.0000e+00 7.0933e-01 4.8622e-01 4.4173e-02 4.1050e-02 -6.0000e+00 7.7773e-01 -6.5327e-01 4.2746e-02 2.6172e-02 -6.0000e+00 4.5426e-01 2.6040e-01 2.0405e-02 1.1948e-02 -6.0000e+00 1.8875e-01 3.7042e-05 -1.2216e-04 5.2539e-04 2.2541e-04 -6.0000e+00 1.4633e-02 4.9319e-03 0.0000e+00 12 8 8 10 0 0 95.55 23.24 0.28 0.00493 0.00401 18 4 1 5 0 2778.210 27.05 20.00 23.24 12.27 20.5 967.91 -152652 155214 -25115 33326 -176606 900000 900000 900000 -171154 74200 10767 7954 -61629 900000 -9437 -36605 -81920 -36088 31964 -16781 -64122 27374 900000 -53552 274048 3668 7754 -40174 -3353 -36481 -14018 -48491 193095 900000 129516 9911 -3654 785 -26250 20632 -24586 2829 -13684 129426 8822 54515 57359 -3277 15864 -7669 10947 30188 16273 -5263 24209 17058 28562 37964 20023 6349 12455 21895 19685 1924 4982 1022 -10924 19905 -11622 21184 4828 14806 -2284 15954 -3432 2737 -12381 6350 3783 -3671 6783 -5313 4596 -3821 -1326 -2997 6089 1080 3687 -4035 4815 -4085 714 -5107 -6629 1693 -267 1938 -2192 1982 -4426 -2326 -2614 -2962 -3950 -4181 -289 1505 500 1897 86 497 -2443 -1190 -530 -1350 1372 6 1138 318 3805 1481 2601 -2271 1377 1394 1254 350 -2178 585 52 412 351 976 -1538 1438 -169 98 32 201 -1288 -1038 -3919 2590 -419 556 -5403 900000 900000 900000 -5474 1238 180 133 -1114 900000 -157 -916 -3531 -1054 533 -420 -2497 457 900000 -1936 4573 83 165 -1341 -81 -1439 -532 -3016 3222 900000 2161 361 -172 42 -2150 1189 -2387 219 -1287 2945 683 2729 2871 -313 1324 -884 1163 2885 1926 -814 2865 2200 3250 3801 2339 867 1738 3155 3285 412 1028 216 -2652 4219 -3840 5585 1571 4324 -747 3967 -928 644 -3409 1611 1168 -1440 2750 -2686 2240 -2155 -777 -1875 3587 671 2159 -2390 2443 -2181 374 -3170 -4867 1336 -248 1931 -2301 1885 -4062 -1906 -2128 -2580 -3691 -4152 -297 1678 634 2643 131 758 -3726 -1706 -727 -1881 1949 9 1781 497 5550 2133 3580 -3161 1788 1771 1678 534 -3859 1112 107 887 804 2374 -4027 3739 -452 259 81 480 -2939 -2299 SS 20231216T133410.3Z 8750.565397 86 1 13.84 2 78.16 136.93 111.49 101.37 0.00 1 0.00 1 0 17 2.606e-01 9.935e-03 1.788e-01 5.054e-03 5.555111e-01 2.612959e-03 6.533653e-03 -6.000000e+00 1.482840e-01 222.63 -2.00 3.53 -2.00 320.65 0.00e+00 4.061312e-03 1.034313e-03 2.353934e-03 -6.000000e+00 6.515394e-03 276.31 -2.00 20.00 -2.00 320.12 0.00e+00 4.724 0.002 302.00 328.00 3 2.0851e+00 7.9318e-03 5.5220e-02 -6.0000e+00 3.6479e-01 8.9343e-02 1.0193e-02 3.0118e-02 -6.0000e+00 3.9807e-01 -9.7162e-02 1.0062e-02 1.8051e-02 -6.0000e+00 2.3713e-01 2.6618e-02 5.0438e-03 7.3534e-03 -6.0000e+00 1.0078e-01 3.3475e-04 6.6226e-05 1.5049e-04 9.8226e-05 -6.0000e+00 7.3910e-03 3.4028e-03 0.0000e+00 12 9 9 12 1 1 45.52 23.25 0.40 0.00340 0.00390 16 13 1 5 0 813.730 27.15 20.00 23.25 13.48 20.8 976.84 -91259 -113080 7451 -37172 -5988 -129912 -71602 -85406 -37299 -80582 -112101 -55463 -81495 -47090 -12565 -17866 -28760 2472 -36588 20376 -17531 24798 -19094 -23217 -16434 -5807 -21428 -14933 -11669 -15690 -4082 -6601 5593 -19183 -3325 -13053 -1379 3803 348 5694 4774 -159 -2395 4836 1032 3028 -3764 1599 -2167 6622 1186 4987 3223 7256 3312 545 -2771 -1311 -1451 1806 3228 1135 5460 1936 3012 892 723 2187 3179 1561 2540 1513 2673 203 -958 -2389 -5358 -2372 -4290 -155 -2558 -1886 -2686 162 -189 412 -50 1004 1247 183 -81 -1567 -44 -718 -540 -52 1134 454 -326 -664 -1010 -1149 -629 -804 -1633 -879 -795 249 1200 1427 364 -140 -483 -293 -554 593 -308 671 -34 -600 1355 1430 486 477 334 -2 599 -499 -253 -774 -392 -331 130 37 -112 466 730 231 -12 -303 -637 -433 -1063 -1824 37 -266 -30 -2270 -770 -1186 -351 -1227 -2511 -845 -2045 -1055 -242 -416 -825 56 -1311 429 -542 511 -650 -884 -618 -223 -950 -603 -472 -750 -205 -394 325 -1418 -203 -933 -101 321 37 648 595 -22 -352 672 152 446 -606 252 -373 1136 239 1057 753 1731 854 149 -784 -358 -390 481 919 372 1916 747 1131 332 272 872 1429 794 1351 814 1359 98 -420 -979 -2234 -1042 -2237 -90 -1740 -1401 -1943 121 -152 348 -44 874 1049 146 -66 -1233 -34 -618 -482 -53 1303 571 -415 -802 -1115 -1170 -637 -872 -1897 -1070 -1033 347 1682 2184 591 -227 -758 -433 -853 904 -453 1037 -55 -983 2118 2161 715 735 495 -3 891 -764 -429 -1436 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