File name: Pandora185s1_EastProvidenceRI_20231230_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20240113T083429.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20231230_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20231230 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231230T171552.1Z 8764.719353 454 1 49.67 2 65.31 187.06 110.81 321.53 0.00 1 0.00 1 0 17 9.008e-02 8.579e-03 6.990e-02 6.190e-03 3.611697e-01 3.137906e-03 4.402808e-03 -6.000000e+00 5.135905e-02 223.12 -2.00 3.53 -2.00 319.37 0.00e+00 1.524388e-03 8.138656e-04 9.997453e-04 -6.000000e+00 2.244457e-03 275.44 -2.00 20.00 -2.00 318.80 0.00e+00 2.378 0.000 302.00 328.00 3 5.0520e+00 8.6594e-03 3.0142e-02 -6.0000e+00 1.2652e-01 5.1709e-02 1.0102e-02 1.8817e-02 -6.0000e+00 1.3803e-01 3.6434e-03 7.7160e-03 9.7895e-03 -6.0000e+00 8.2152e-02 -1.1070e-02 4.0597e-03 3.1004e-03 -6.0000e+00 3.4858e-02 1.9635e-04 -1.7830e-04 1.9110e-04 3.7827e-05 -6.0000e+00 2.5553e-03 2.7413e-03 0.0000e+00 11 8 0 10 0 0 99.99 23.23 0.46 0.00274 0.00140 60 13 1 5 0 827.640 27.05 19.99 23.23 16.01 21.1 1002.74 -29146 31398 -29647 17856 -20357 23456 -44755 -11209 58514 -5167 61 -19545 -10475 1936 -981 -8398 7672 2664 -815 -3847 -6836 -330 -2293 277 2689 -10961 -1227 -2562 -8203 -1512 -3156 12339 -3450 -7119 -1787 -9860 -2663 1543 -704 -417 -783 -1298 540 858 3024 -213 -619 -823 485 569 3090 2411 619 1124 2248 2225 3007 990 -850 44 757 3312 2691 2275 1743 1532 -783 2252 -442 1095 15 -721 551 408 -1572 -564 -2559 -1270 -573 -1775 -411 -2293 -1019 -665 -211 -1061 196 438 501 151 -860 796 -1473 -133 -46 829 270 116 242 -1163 -1859 180 -95 -1085 -1814 -462 -996 306 1134 1589 650 111 510 -181 106 -558 -125 417 104 -512 382 509 768 585 -161 513 535 146 2 -168 -556 -375 62 -126 -572 152 587 282 333 -233 -582 -471 -1070 679 -1178 404 -625 472 -1958 -395 1118 -192 2 -963 -558 108 -65 -659 544 210 -70 -382 -701 -32 -239 30 298 -1425 -141 -281 -936 -172 -405 1503 -528 -1105 -252 -1585 -456 303 -168 -112 -226 -393 164 262 908 -66 -190 -253 149 184 1056 890 248 469 952 963 1295 427 -368 19 351 1643 1460 1279 1036 856 -437 1279 -290 783 12 -557 406 280 -995 -320 -1413 -721 -364 -1299 -331 -2041 -944 -653 -221 -1182 223 499 553 156 -822 693 -1276 -121 -46 926 338 156 325 -1494 -2205 195 -105 -1291 -2305 -608 -1386 445 1764 2625 1114 186 806 -266 147 -770 -179 631 167 -839 610 788 1139 826 -218 663 700 206 3 -275 -947 -655 112 -243 -1161 314 1233 594 681 -459 -1103 -873 SS 20231230T172450.8Z 8764.725588 457 1 49.38 2 65.55 189.32 111.81 323.45 0.00 1 0.00 1 0 17 7.485e-02 8.274e-03 7.771e-02 6.794e-03 3.559722e-01 3.441168e-03 4.180138e-03 -6.000000e+00 4.269207e-02 223.12 -2.00 3.53 -2.00 319.39 0.00e+00 2.822606e-03 9.020393e-04 3.286108e-04 -6.000000e+00 1.864853e-03 275.44 -2.00 20.00 -2.00 318.82 0.00e+00 2.400 0.000 302.00 328.00 3 5.2424e+00 9.5049e-03 2.9920e-02 -6.0000e+00 1.0517e-01 3.9187e-02 1.1087e-02 1.8173e-02 -6.0000e+00 1.1472e-01 -3.5377e-04 8.5424e-03 9.5545e-03 -6.0000e+00 6.8278e-02 -4.2042e-03 4.5006e-03 4.1423e-03 -6.0000e+00 2.8986e-02 1.6072e-04 6.0058e-04 2.1006e-04 4.2477e-05 -6.0000e+00 2.1229e-03 -6.2189e-04 0.0000e+00 11 9 0 11 8 0 100.00 23.23 0.61 -0.00062 0.00389 45 10 1 5 0 1097.100 27.05 19.99 23.23 16.03 21.2 1003.63 19459 20180 -8911 -31802 -3458 -2305 60363 -25790 -12306 -6942 -8795 -11479 8472 -1290 -8815 -4681 -82 7134 -2574 13296 648 10562 -2554 4087 -1506 7728 -23 -4822 -4885 -1446 -2167 2127 -1913 -5959 -6232 -5168 -1551 -2091 -1160 -549 2900 -4885 -2897 2813 2990 392 -1786 -1542 -2545 2758 840 -205 1044 1773 218 1615 1486 2189 1405 -2227 1255 1894 3183 570 832 -1020 709 578 -321 150 1358 388 754 -1141 120 -3320 -1347 227 -1544 993 -2523 -1310 -1018 -735 -437 779 -253 499 2282 1646 -356 -862 -714 -720 -20 -676 985 -506 350 -957 -285 -104 838 -1137 -1087 -1595 88 -343 1273 812 87 498 -232 -138 -658 -1022 220 688 237 570 -292 507 86 349 -362 -538 514 66 348 -335 100 -87 -488 -111 133 63 1049 -303 329 -41 -744 -379 451 501 -295 -1211 -92 -61 933 -1054 -476 -261 -345 -520 374 -75 -637 -357 -6 544 -226 1121 62 922 -266 421 -171 819 -3 -534 -535 -164 -275 287 -288 -911 -916 -791 -261 -423 -276 -146 796 -1512 -902 833 891 120 -554 -475 -803 870 292 -77 413 728 93 695 641 920 588 -988 576 949 1712 324 496 -581 388 332 -209 108 1015 294 550 -790 74 -1924 -731 126 -988 705 -2073 -1151 -939 -720 -457 849 -288 567 2467 1668 -338 -761 -613 -654 -20 -767 1227 -685 468 -1224 -332 -113 913 -1356 -1374 -2125 122 -505 1983 1355 150 835 -369 -202 -915 -1418 314 1040 380 925 -470 787 129 495 -493 -705 675 94 534 -550 169 -152 -892 -215 269 131 2193 -642 673 -80 -1413 -702 SS 20231230T172958.7Z 8764.729151 461 1 27.31 2 65.71 190.60 112.37 324.56 0.00 1 0.00 1 0 17 3.497e-02 7.167e-03 1.866e-02 2.268e-03 3.635451e-01 1.143942e-03 4.379680e-03 -6.000000e+00 1.994222e-02 223.12 -2.00 3.53 -2.00 318.75 0.00e+00 1.684344e-03 2.493347e-04 5.344485e-04 -6.000000e+00 8.713172e-04 275.44 -2.00 20.00 -2.00 318.17 0.00e+00 2.415 0.000 302.00 328.00 3 3.7231e+00 3.0989e-03 3.0330e-02 -6.0000e+00 4.9126e-02 3.7806e-02 3.5537e-03 1.8510e-02 -6.0000e+00 5.3592e-02 2.3813e-03 2.5502e-03 9.5550e-03 -6.0000e+00 3.1897e-02 -9.3455e-03 1.3534e-03 3.1777e-03 -6.0000e+00 1.3537e-02 7.1962e-04 1.0212e-04 6.8242e-05 3.5645e-05 -6.0000e+00 9.9196e-04 1.2361e-03 0.0000e+00 12 9 1 12 1 1 99.99 23.23 0.34 0.00124 0.00200 25 10 1 5 0 1050.100 27.05 20.00 23.23 16.27 21.2 1004.69 1210 -12827 -16 -26071 5801 -13200 -10824 -10498 -971 -10472 -6624 -1370 -420 -2047 -3105 -2253 -2202 940 1490 369 -2651 -176 -2793 -2069 -2322 1394 -4143 1330 -1059 -328 1266 1498 2198 -3744 -3189 -3822 -2221 -2559 -941 -1742 -941 -639 5 340 1174 40 -531 -260 393 1772 -21 645 1688 1523 1014 261 -241 349 30 598 1678 2646 2163 1279 638 -328 90 880 863 287 1359 554 1271 -126 -317 -1414 -1664 -1822 -1391 -1393 -1458 -1886 -2151 -798 -501 320 274 947 512 776 -197 -260 -175 31 -280 345 881 134 -357 -1002 -1022 -1062 132 -1376 -1219 -1249 -507 294 989 928 479 639 49 101 -176 116 -20 369 -51 -209 199 683 457 502 -156 -155 940 261 51 -306 -423 -465 138 -95 -37 341 520 143 47 -418 -505 -523 40 -529 -1 -1122 168 -470 -413 -449 -41 -503 -346 -76 -27 -161 -286 -226 -234 103 169 44 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