File name: Pandora185s1_EastProvidenceRI_20240311_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20250506T212109.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20240311_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20240311 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240311T121414.6Z 8836.509891 73 1 16.84 2 77.79 105.97 86.03 91.40 0.00 1 0.00 1 0 17 5.497e-01 2.285e-02 3.387e-01 1.146e-02 7.780432e-01 6.307439e-03 9.225157e-03 -6.000000e+00 3.189853e-01 225.93 -2.00 3.53 -2.00 321.41 0.00e+00 6.676244e-03 3.008764e-03 4.837178e-03 -6.000000e+00 1.391400e-02 276.14 -2.00 20.00 -2.00 320.93 0.00e+00 4.592 0.002 302.00 328.00 3 3.2552e+00 2.1079e-02 6.4541e-02 -6.0000e+00 7.9162e-01 4.5577e-01 2.8624e-02 4.7567e-02 -6.0000e+00 8.6285e-01 -6.3277e-01 2.8355e-02 2.7943e-02 -6.0000e+00 5.1031e-01 2.6717e-01 1.3475e-02 1.0401e-02 -6.0000e+00 2.1449e-01 8.2437e-05 -6.4598e-04 3.1818e-04 1.8884e-04 -6.0000e+00 1.5905e-02 3.9707e-03 0.0000e+00 12 9 9 12 1 1 99.64 22.85 0.57 0.00397 -0.00088 5 4 1 5 0 2804.420 26.73 20.00 22.85 7.77 21.2 976.93 -121558 -142586 -161719 -183891 -107632 -202487 900000 -156294 -30176 -131310 159539 -166367 900000 -135926 46180 -20081 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-378 2188 -263 4877 2646 3469 1622 1130 1161 807 2976 -784 2821 1635 3034 -272 975 -1324 27 -1484 107 -571 2403 -1502 -154 256 -2303 652 -1452 -47 -458 94 146 -1093 -3017 1191 -4945 -585 -1586 -2499 -501 -1594 -1502 -2426 -378 -2567 -972 -3723 -1020 438 1494 -1408 3679 -255 662 -1310 -1323 1173 655 -989 690 2230 199 3669 2008 2708 -1410 2150 2183 1229 270 475 1944 -1782 1459 -1402 328 -493 3440 -2670 470 -141 -1018 -3992 SS 20240311T121850.8Z 8836.513088 76 1 25.68 2 76.97 106.80 85.18 92.13 0.00 1 0.00 1 0 25 4.508e-01 9.660e-03 3.427e-01 5.945e-03 7.338611e-01 3.269892e-03 8.404524e-03 -6.000000e+00 2.631860e-01 225.93 -2.00 3.53 -2.00 321.30 0.00e+00 3.299566e-03 1.572429e-03 3.578315e-03 -6.000000e+00 1.146725e-02 276.14 -2.00 20.00 -2.00 320.81 0.00e+00 4.322 0.001 302.00 328.00 3 2.8545e+00 1.0898e-02 5.9784e-02 -6.0000e+00 6.5384e-01 8.6967e-02 1.5809e-02 4.3457e-02 -6.0000e+00 7.1321e-01 -8.2885e-02 1.7600e-02 2.6059e-02 -6.0000e+00 4.2208e-01 2.2022e-02 8.3106e-03 9.7273e-03 -6.0000e+00 1.7712e-01 1.7764e-04 -1.2669e-04 1.6918e-04 1.4939e-04 -6.0000e+00 1.3073e-02 4.0245e-03 0.0000e+00 12 9 9 12 1 1 99.71 22.83 0.44 0.00402 0.00307 16 7 1 5 0 1510.200 26.62 20.00 22.83 7.84 21.1 977.50 -85422 -94196 900000 -128817 -117624 -128101 900000 -202252 -160241 -177427 -186196 -179898 -20133 91910 -74502 -14137 900000 -33311 -9643 48083 -19886 -53656 -17296 37262 19415 -42621 -36916 71839 -7649 52349 10245 -41164 -26044 -31564 -6001 698 -17409 -18678 -6286 -11367 4480 -9840 4601 -2082 -132 13604 7631 -14029 8567 5919 926 3315 664 11067 4197 3916 -205 1731 -2691 3299 -3910 10035 4407 2118 3001 3438 4653 -2361 963 544 3408 761 2312 1826 62 -2996 -3747 -1926 -3078 -1410 -1786 -1217 -884 708 -211 1030 44 2102 1104 712 -1158 -2086 -1442 -1431 -1943 -416 842 481 481 -1057 -2478 -120 406 -1040 -1444 -281 -491 772 1477 1047 147 597 -787 -102 -1002 40 24 902 -33 457 861 1158 238 109 -1160 -882 562 -464 -61 -278 -437 -678 45 -96 -185 173 1209 240 471 -651 -280 -475 -495 -546 900000 -746 -681 -742 900000 -1855 -1181 -1682 -2157 -2463 -117 532 -785 -97 900000 -351 -86 279 -209 -819 -200 275 184 -786 -642 416 -105 469 173 -1387 -850 -1097 -158 18 -642 -856 -342 -757 280 -758 320 -158 -10 938 584 -1414 744 590 110 428 97 1571 671 651 -36 289 -458 539 -747 1907 1013 541 765 868 1202 -715 324 205 1321 302 856 621 19 -890 -1133 -637 -1225 -653 -959 -722 -558 469 -150 759 33 1578 809 490 -760 -1337 -948 -1052 -1672 -411 860 541 546 -1149 -2463 -116 385 -1061 -1565 -289 -545 930 1989 1579 238 978 -1271 -155 -1481 58 36 1439 -54 744 1338 1722 343 152 -1573 -1163 768 -724 -107 -541 -916 -1379 98 -221 -446 424 2966 589 1100 -1439 -632 -1043 SS 20240311T122839.6Z 8836.519903 79 1 14.70 2 75.23 108.57 83.39 93.68 0.00 1 0.00 1 0 17 3.325e-01 7.572e-03 1.865e-01 3.464e-03 6.596957e-01 1.829094e-03 7.597451e-03 -6.000000e+00 1.915224e-01 225.93 -2.00 3.53 -2.00 320.77 0.00e+00 4.202894e-03 7.642870e-04 1.888887e-03 -6.000000e+00 8.308312e-03 276.14 -2.00 20.00 -2.00 320.26 0.00e+00 3.844 0.001 302.00 328.00 3 2.2036e+00 5.6710e-03 5.1994e-02 -6.0000e+00 4.7467e-01 7.2943e-02 7.5576e-03 3.5525e-02 -6.0000e+00 5.1685e-01 -6.1016e-02 7.9204e-03 2.0712e-02 -6.0000e+00 3.0708e-01 1.4256e-02 3.9000e-03 8.4098e-03 -6.0000e+00 1.2954e-01 5.7523e-04 -2.5333e-04 9.7271e-05 1.0549e-04 -6.0000e+00 9.4389e-03 5.4170e-03 0.0000e+00 12 9 1 12 1 1 99.97 22.80 0.29 0.00542 0.00351 24 18 1 5 0 587.750 26.62 19.99 22.80 8.17 21.0 978.47 -104281 -119062 -1575 -55961 -154144 -77903 -139508 -40988 -130452 -109717 -133332 -33723 -85199 -54895 -60585 -33676 -11683 12024 -22393 -35690 -3148 -29280 -11560 -21651 -21431 -18688 -21561 -25452 -15393 -15081 -14250 -8861 -7199 2315 -15720 -4741 -14892 -5699 -7323 283 -394 1266 1305 3649 -1381 5774 587 -1354 2451 651 2175 887 4264 1342 3212 402 320 -490 765 -135 1947 1902 2733 3482 2827 1476 857 3192 1498 2535 968 1765 375 59 -2252 -1911 -2758 -1784 -2370 -1426 -1031 -2434 -1756 -675 -53 234 813 530 1609 336 242 -1127 -471 -707 -547 303 957 151 -540 -350 -927 -562 -787 -982 -1887 -551 -575 331 962 700 485 560 150 -348 -153 -26 515 -86 137 -455 630 600 476 65 -290 190 874 334 -57 -739 -370 -151 -171 -30 -326 380 516 112 28 -130 -245 -301 -608 -914 -5 -223 -1562 -383 -1414 -176 -1522 -1112 -1883 -217 -1203 -742 -1079 -538 -169 151 -426 -811 -52 -712 -254 -570 -601 -530 -626 -757 -437 -499 -568 -395 -353 103 -818 -235 -951 -404 -641 26 -41 136 146 408 -167 667 74 -182 340 101 375 171 869 301 740 98 79 -119 179 -33 500 555 897 1219 992 517 309 1218 665 1242 508 917 188 27 -955 -746 -1086 -765 -1205 -844 -633 -1676 -1279 -518 -43 200 709 464 1346 266 179 -809 -343 -571 -509 324 1066 186 -671 -410 -1076 -592 -823 -1094 -2245 -682 -699 436 1405 1133 769 891 251 -553 -232 -40 809 -144 237 -783 1032 946 723 94 -409 260 1236 532 -94 -1351 -719 -307 -369 -64 -731 864 1187 257 62 -270 -515 -615 SS 20240311T123807.9Z 8836.526481 82 1 49.45 2 73.56 110.31 81.65 95.19 0.00 1 0.00 1 0 17 2.288e-01 6.225e-03 6.604e-02 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