File name: Pandora74s1_EdwardsCA_20220816_L2Fit_fout2c8d20220504p1-8.txt File generation date: 20241115T232122.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: James Podolske Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 74 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora74_OF_v3d20211222.txt Instrument calibration file used: Pandora74s1_CF_v8d20220504.txt Level 1 file used: Pandora74s1_EdwardsCA_20220816_L1_smca1c8d20220504p1-8.txt Full location name: NASA Neil A. Armstrong Flight Research Center Short location name: EdwardsCA Country of location: United States Location latitude [deg]: 34.9600 Location longitude [deg]: -117.8811 Location altitude [m]: 692 Local noon date: 20220816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on VP4 to update SO2 MLE First and last pixel inside fitting window: 239 380 Nominal wavelengths inside fitting window [nm]: 305.1340 305.2752 305.4164 305.5576 305.6987 305.8399 305.9810 306.1221 306.2632 306.4043 306.5454 306.6865 306.8275 306.9686 307.1096 307.2506 307.3916 307.5326 307.6736 307.8145 307.9555 308.0964 308.2374 308.3783 308.5192 308.6601 308.8009 308.9418 309.0827 309.2235 309.3643 309.5051 309.6459 309.7867 309.9275 310.0683 310.2090 310.3498 310.4905 310.6312 310.7719 310.9126 311.0533 311.1940 311.3346 311.4752 311.6159 311.7565 311.8971 312.0377 312.1783 312.3188 312.4594 312.5999 312.7405 312.8810 313.0215 313.1620 313.3024 313.4429 313.5834 313.7238 313.8642 314.0047 314.1451 314.2855 314.4258 314.5662 314.7066 314.8469 314.9872 315.1276 315.2679 315.4082 315.5484 315.6887 315.8290 315.9692 316.1094 316.2497 316.3899 316.5301 316.6702 316.8104 316.9506 317.0907 317.2308 317.3710 317.5111 317.6512 317.7913 317.9313 318.0714 318.2114 318.3515 318.4915 318.6315 318.7715 318.9115 319.0515 319.1914 319.3314 319.4713 319.6112 319.7511 319.8910 320.0309 320.1708 320.3106 320.4505 320.5903 320.7302 320.8700 321.0098 321.1496 321.2893 321.4291 321.5688 321.7086 321.8483 321.9880 322.1277 322.2674 322.4071 322.5467 322.6864 322.8260 322.9657 323.1053 323.2449 323.3845 323.5240 323.6636 323.8031 323.9427 324.0822 324.2217 324.3612 324.5007 324.6402 324.7797 324.9191 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220816T134229.6Z 8263.571176 214 1 48.21 2 84.92 76.92 40.14 232.34 0.00 1 0.00 1 0 25 6.379e-01 5.686e-02 5.053e-01 5.064e-02 9.792796e-01 3.134046e-02 1.055199e-02 -6.000000e+00 3.941358e-01 230.82 -2.00 3.37 -2.00 322.28 0.00e+00 -2.006439e-02 1.369383e-02 1.110825e-02 -6.000000e+00 1.819490e-02 289.55 -2.00 20.00 -2.00 321.70 0.00e+00 9.695 0.014 302.00 328.00 3 1.3379e+00 1.1663e-01 1.3584e-01 -6.0000e+00 9.9060e-01 1.7761e+00 1.3970e-01 1.3525e-01 -6.0000e+00 1.0776e+00 -2.1362e+00 7.8059e-02 2.9598e-02 -6.0000e+00 6.3339e-01 7.9818e-01 4.2413e-02 2.5638e-02 -6.0000e+00 2.6396e-01 6.4968e-06 -1.1827e-03 1.4475e-03 2.4469e-04 -6.0000e+00 1.9369e-02 2.3883e-02 -1.6867e-04 12 8 8 10 0 0 -5.18 23.82 1.06 0.02388 0.01500 17 4 1 5 0 2835.570 26.94 20.00 23.82 27.88 12.5 899.91 141184 -46710 99273 -44159 -22110 -34261 900000 -22204 36470 106350 267390 900000 -22936 900000 -35076 900000 16270 83125 900000 30389 900000 900000 900000 67505 -10422 -24584 -12670 -62877 900000 46730 900000 -32603 207056 -2954 -61662 900000 276014 224523 54062 43452 -2383 900000 74735 110698 79081 16398 182491 133820 161002 68590 48152 900000 56658 900000 -29504 900000 31272 47944 -33477 -18044 -24768 39422 44831 -12427 66676 -44576 9523 15322 41911 116266 46916 -12870 -9480 91256 -55565 -25604 10146 -2787 12 36104 24194 11610 16182 7210 58222 8083 28291 12206 13751 -1248 2636 21117 11727 -5518 -17059 -172 -12023 -2669 -435 -213 -5918 -14259 12285 -8653 -10399 -11028 11655 -8247 5953 -3142 6268 6365 -1994 1775 -6178 3270 3260 4521 4703 4741 -2527 -2004 3367 -954 1568 -1700 1071 -4658 1659 2960 -2373 1068 952 -2924 -1854 218 1576 -1084 577 -179 -1083 2197 6949 -5748 4886 -3623 -1270 -2453 900000 -1689 1795 5235 13161 900000 -2155 900000 -4238 900000 1165 4092 900000 1632 900000 900000 900000 3323 -933 -2420 -964 -6753 900000 2300 900000 -3064 10192 -198 -6898 900000 13586 11051 3145 3111 -277 900000 3679 5449 3893 1174 8983 6587 7925 3714 3555 900000 4462 900000 -5545 900000 3540 4248 -5543 -2664 -3657 3687 4413 -2113 5579 -10372 1500 2489 5982 8584 7159 -3484 -2286 7187 -16684 -5293 1498 -521 3 6398 5597 3429 4859 2520 12896 3063 8912 4446 4738 -467 908 6028 3925 -2526 -10328 -103 -8447 -2089 -338 -157 -4194 -9896 6410 -5963 -7678 -8685 7974 -7713 5597 -3712 7435 7863 -2699 2263 -8333 4056 4220 6053 6482 6370 -3470 -2623 4094 -1174 1860 -2041 1334 -7176 2792 5566 -5185 2433 2351 -7381 -4903 573 4553 -3192 1588 -459 -2611 4900 SS 20220816T135331.5Z 8263.578837 217 1 48.24 2 82.71 78.45 41.90 235.44 0.00 1 0.00 1 0 17 5.212e-01 1.868e-02 2.803e-01 8.677e-03 7.866484e-01 5.124941e-03 9.528857e-03 -6.000000e+00 3.137778e-01 230.82 -2.00 3.37 -2.00 322.13 0.00e+00 1.122923e-02 3.216057e-03 8.954604e-03 -6.000000e+00 1.454976e-02 289.55 -2.00 20.00 -2.00 321.60 0.00e+00 7.273 0.006 302.00 328.00 3 1.2628e+00 2.1776e-02 8.9008e-02 -6.0000e+00 7.8495e-01 5.8842e-01 3.0018e-02 6.6213e-02 -6.0000e+00 8.4946e-01 -8.5945e-01 2.5404e-02 3.3743e-02 -6.0000e+00 5.0505e-01 3.5149e-01 1.1370e-02 9.5607e-03 -6.0000e+00 2.1257e-01 8.4543e-05 -1.4919e-03 2.6008e-04 2.5220e-04 -6.0000e+00 1.5193e-02 2.4616e-02 -1.4385e-04 12 8 8 10 0 0 -12.96 23.87 0.31 0.02462 0.01341 86 21 1 5 0 560.840 27.05 20.00 23.87 28.91 12.4 905.96 -163333 -141662 -142936 -159601 -132414 -201411 -73674 -152770 900000 -192608 -135701 -161589 -101985 53691 -60946 17909 -3545 14988 36682 -35153 -28848 -48561 -49322 -74856 35481 -58743 40622 -67119 73617 -43982 42721 -32787 57737 79742 3026 42136 -15072 52133 -3246 42613 15652 29400 17695 35556 76291 55026 85915 37214 55714 16313 51656 19956 17143 30430 19804 41264 9965 23113 13792 13086 10311 21098 17885 13281 19303 15305 14935 11159 21802 8026 14211 7316 5111 6203 -4078 1442 -1799 -454 -2388 1587 -2443 -738 -2741 -1204 -1756 182 2402 -104 1908 -2034 -997 -5010 -4938 -2432 -2656 -2783 -2340 -811 -2831 -629 -4629 -2394 -2296 -2387 -1684 -2167 462 -556 824 -550 1048 -348 174 -537 -376 290 451 1093 1055 387 1091 1762 900 155 1924 230 1580 204 848 -781 0 -509 121 203 -11 390 -65 138 -2 435 -577 -1627 -3643 -2724 -2748 -3191 -1833 -5421 -623 -2702 900000 -5332 -2296 -4473 -2039 454 -1265 212 -57 216 434 -862 -634 -1273 -1335 -2418 420 -1789 447 -2158 623 -1451 723 -1359 1074 1147 90 891 -637 1323 -167 1550 794 1368 958 1624 2388 2188 2616 1952 2592 1242 3102 1789 1711 2806 2077 3560 1163 2288 1470 1439 1273 2659 2407 2043 3070 2538 2590 1974 3990 1852 3213 1755 1179 1298 -850 294 -388 -108 -635 478 -885 -294 -1183 -546 -854 91 1212 -54 943 -984 -453 -2312 -2370 -1290 -1660 -2035 -1968 -748 -2713 -562 -3923 -1799 -1697 -1895 -1401 -1922 433 -582 969 -739 1498 -516 253 -759 -515 398 648 1644 1655 603 1623 2504 1259 210 2515 297 2110 316 1490 -1554 0 -1163 294 529 -29 1091 -187 393 -6 1111 -1402 -3839 SS 20220816T140353.6Z 8263.586037 220 1 47.86 2 80.62 79.88 43.61 238.17 0.00 1 0.00 1 0 17 4.625e-01 7.158e-03 1.781e-01 2.930e-03 6.809336e-01 1.684458e-03 7.842812e-03 -6.000000e+00 2.780829e-01 230.82 -2.00 3.37 -2.00 321.68 0.00e+00 4.662954e-03 9.604900e-04 5.593079e-03 -6.000000e+00 1.259606e-02 289.55 -2.00 20.00 -2.00 321.07 0.00e+00 5.839 0.003 302.00 328.00 3 1.0850e+00 6.5606e-03 6.9818e-02 -6.0000e+00 6.9408e-01 8.4688e-02 9.2722e-03 5.0436e-02 -6.0000e+00 7.5049e-01 -1.3771e-01 8.8790e-03 2.4607e-02 -6.0000e+00 4.4774e-01 4.6894e-02 4.0740e-03 6.1625e-03 -6.0000e+00 1.8853e-01 4.1909e-04 -7.6473e-04 9.0685e-05 1.3461e-04 -6.0000e+00 1.3479e-02 2.3855e-02 -1.5591e-04 11 8 0 10 0 0 -1.52 23.96 0.30 0.02385 0.01811 217 52 1 5 0 220.530 27.05 20.01 23.96 29.94 12.4 911.47 -135689 -175885 -172678 -186348 -179142 -183363 -45188 -138872 -116261 -132508 35830 -107709 -87275 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