File name: Pandora74s1_EdwardsCA_20221012_L2Fit_fout2c8d20220504p1-8.txt File generation date: 20241116T011826.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: James Podolske Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 74 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora74_OF_v3d20211222.txt Instrument calibration file used: Pandora74s1_CF_v8d20220504.txt Level 1 file used: Pandora74s1_EdwardsCA_20221012_L1_smca1c8d20220504p1-8.txt Full location name: NASA Neil A. Armstrong Flight Research Center Short location name: EdwardsCA Country of location: United States Location latitude [deg]: 34.9600 Location longitude [deg]: -117.8811 Location altitude [m]: 692 Local noon date: 20221012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on VP4 to update SO2 MLE First and last pixel inside fitting window: 239 380 Nominal wavelengths inside fitting window [nm]: 305.1340 305.2752 305.4164 305.5576 305.6987 305.8399 305.9810 306.1221 306.2632 306.4043 306.5454 306.6865 306.8275 306.9686 307.1096 307.2506 307.3916 307.5326 307.6736 307.8145 307.9555 308.0964 308.2374 308.3783 308.5192 308.6601 308.8009 308.9418 309.0827 309.2235 309.3643 309.5051 309.6459 309.7867 309.9275 310.0683 310.2090 310.3498 310.4905 310.6312 310.7719 310.9126 311.0533 311.1940 311.3346 311.4752 311.6159 311.7565 311.8971 312.0377 312.1783 312.3188 312.4594 312.5999 312.7405 312.8810 313.0215 313.1620 313.3024 313.4429 313.5834 313.7238 313.8642 314.0047 314.1451 314.2855 314.4258 314.5662 314.7066 314.8469 314.9872 315.1276 315.2679 315.4082 315.5484 315.6887 315.8290 315.9692 316.1094 316.2497 316.3899 316.5301 316.6702 316.8104 316.9506 317.0907 317.2308 317.3710 317.5111 317.6512 317.7913 317.9313 318.0714 318.2114 318.3515 318.4915 318.6315 318.7715 318.9115 319.0515 319.1914 319.3314 319.4713 319.6112 319.7511 319.8910 320.0309 320.1708 320.3106 320.4505 320.5903 320.7302 320.8700 321.0098 321.1496 321.2893 321.4291 321.5688 321.7086 321.8483 321.9880 322.1277 322.2674 322.4071 322.5467 322.6864 322.8260 322.9657 323.1053 323.2449 323.3845 323.5240 323.6636 323.8031 323.9427 324.0822 324.2217 324.3612 324.5007 324.6402 324.7797 324.9191 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221012T142448.5Z 8320.600562 248 1 47.86 2 84.86 102.92 63.76 275.26 0.00 1 0.00 1 0 25 6.050e-01 4.295e-02 4.948e-01 3.982e-02 9.032664e-01 2.573597e-02 1.009324e-02 -6.000000e+00 3.766761e-01 226.68 -2.00 3.37 -2.00 322.46 0.00e+00 -2.219027e-02 1.437527e-02 3.065878e-03 -6.000000e+00 2.095608e-02 284.91 -2.00 20.00 -2.00 321.98 0.00e+00 9.629 0.014 302.00 328.00 3 1.4149e+00 1.0425e-01 1.0742e-01 -6.0000e+00 9.3194e-01 1.2826e+00 1.2995e-01 7.7038e-02 -6.0000e+00 1.0183e+00 -1.7692e+00 8.9880e-02 2.4007e-02 -6.0000e+00 6.0360e-01 6.9100e-01 4.3813e-02 1.8332e-02 -6.0000e+00 2.6147e-01 8.4768e-06 -1.7105e-03 1.2935e-03 2.4603e-04 -6.0000e+00 1.9299e-02 3.5014e-02 -1.3956e-04 12 9 8 11 4 0 4.80 23.16 0.99 0.03501 0.02216 22 5 1 5 0 2175.300 26.41 20.00 23.16 20.04 12.3 856.82 54240 900000 213432 900000 -142727 900000 -6404 900000 -25865 64307 900000 900000 900000 900000 60070 -32780 900000 254681 181063 900000 900000 22073 900000 900000 -76043 900000 -49866 60372 900000 900000 -59469 118561 900000 116527 900000 47350 108651 900000 900000 139836 143723 900000 900000 30263 900000 900000 66342 900000 900000 57741 900000 330 78243 27365 65602 40842 57794 211870 16394 28684 52533 120688 35842 38786 -42488 31084 17978 57207 10094 32342 7484 -18004 87526 -2355 26073 -54224 13046 90345 6934 13676 9452 15670 -7167 33316 -4120 5718 -4172 -12833 -2697 632 -2272 1646 14758 -3635 8245 -340 -5369 -4142 -5661 -4812 -2156 2145 -3539 20486 -3598 1583 -1172 -1886 -455 24 222 -3001 1805 -2188 2135 4921 723 -1146 613 2577 558 1160 -1030 7936 -3440 -1602 -1387 -1506 1257 -333 1888 -2019 3346 -2389 2059 -1793 -359 -647 410 697 739 -756 2093 900000 8235 900000 -11932 900000 -247 900000 -998 2481 900000 900000 900000 900000 2318 -1897 900000 9827 6986 900000 900000 852 900000 900000 -7824 900000 -3367 2329 900000 900000 -4207 4575 900000 4496 900000 1827 4192 900000 900000 5396 5546 900000 900000 1698 900000 900000 2560 900000 900000 2633 900000 32 3842 2400 4142 3438 4054 8175 1495 2214 3317 4657 3269 3673 -8942 3162 2207 5217 1699 4765 1470 -4484 7061 -421 3109 -13504 1693 6021 1265 2734 2288 4012 -2464 8180 -1561 2046 -1683 -5582 -1022 217 -773 537 4504 -1530 3615 -189 -3597 -3036 -4269 -3427 -1361 1181 -2048 10060 -2372 1055 -876 -1588 -435 26 264 -3821 2197 -2701 2464 5593 895 -1519 826 3335 704 1404 -1250 8546 -4103 -1838 -1693 -2140 2006 -608 3689 -4412 7489 -6117 5337 -4913 -983 -1766 1055 1664 1650 -1650 SS 20221012T143559.2Z 8320.608325 251 1 48.29 2 82.64 104.58 65.97 276.73 0.00 1 0.00 1 0 25 6.359e-01 1.214e-02 3.434e-01 6.971e-03 7.757933e-01 4.095300e-03 8.897608e-03 -6.000000e+00 3.855341e-01 226.68 -2.00 3.37 -2.00 322.02 0.00e+00 1.001669e-02 2.610319e-03 5.139662e-03 -6.000000e+00 1.774618e-02 284.91 -2.00 20.00 -2.00 321.52 0.00e+00 7.218 0.006 302.00 328.00 3 1.1338e+00 1.6903e-02 7.9935e-02 -6.0000e+00 9.5955e-01 2.6996e-01 2.5693e-02 4.6729e-02 -6.0000e+00 1.0470e+00 -3.8960e-01 2.6602e-02 2.8346e-02 -6.0000e+00 6.1928e-01 1.5272e-01 1.1786e-02 1.1736e-02 -6.0000e+00 2.5720e-01 1.0891e-04 -1.2592e-03 2.1153e-04 2.3072e-04 -6.0000e+00 1.9022e-02 3.4384e-02 -1.4643e-04 12 8 8 10 0 0 17.13 23.20 0.38 0.03438 0.02492 106 26 1 5 0 455.490 26.41 20.01 23.20 21.04 12.3 862.97 -238344 -48443 -236176 900000 -293297 900000 -78619 900000 -207118 -207132 -145187 -199701 900000 -175741 900000 -45252 900000 900000 38191 10086 -98467 -27514 -127253 99539 -19286 266939 47108 -14175 -9735 -52169 51145 -33271 -2779 -37612 5744 -17273 25351 2115 9434 43217 -1298 27373 -4284 16796 3803 29833 25461 32506 22792 19118 28951 4877 25054 2463 15686 10019 13975 -3340 9427 10653 1481 17097 2287 8118 2878 6597 4966 9117 10711 3958 3467 59 5282 -1497 1651 -3455 3046 -3178 3053 -1811 -3861 657 -3176 572 -2097 310 287 2136 2361 -1386 202 -2782 -519 -3349 687 -1276 828 -387 -495 -839 -1691 -1194 -2208 -525 -2613 -617 -809 239 586 878 289 -742 -12 -879 361 -190 933 187 586 741 457 1018 382 886 -329 109 -240 571 -263 36 93 -779 157 -328 507 -280 561 -55 86 197 -331 -581 -2427 -329 -2672 900000 -5143 900000 -534 900000 -1992 -2109 -985 -2824 900000 -3479 900000 -358 900000 900000 259 68 -1782 -249 -3311 676 -185 1812 320 -136 -99 -1003 473 -772 -53 -1000 97 -401 445 56 277 1027 -52 883 -199 646 174 1097 1037 1324 1109 1081 1687 397 1828 240 1384 963 1288 -357 880 1018 172 1944 345 1263 472 1056 848 1635 2187 949 873 15 1219 -340 328 -686 586 -737 803 -589 -1481 269 -1434 266 -1068 162 154 1126 1207 -691 94 -1312 -251 -1898 440 -970 711 -372 -480 -775 -1429 -913 -1692 -425 -2273 -559 -798 258 718 1201 428 -1127 -18 -1266 498 -267 1355 288 932 1157 685 1463 538 1195 -441 142 -331 894 -473 71 200 -1797 355 -797 1288 -730 1471 -144 216 465 -805 -1368 SS 20221012T144627.9Z 8320.615601 254 1 48.28 2 80.57 106.17 68.02 278.09 0.00 1 0.00 1 0 17 4.212e-01 6.935e-03 1.109e-01 2.553e-03 6.557378e-01 1.434875e-03 7.611759e-03 -6.000000e+00 2.490917e-01 226.68 -2.00 3.37 -2.00 321.56 0.00e+00 6.531472e-03 7.675468e-04 4.573795e-03 -6.000000e+00 1.124612e-02 284.91 -2.00 20.00 -2.00 320.98 0.00e+00 5.811 0.003 302.00 328.00 3 9.4826e-01 5.2446e-03 6.5700e-02 -6.0000e+00 6.1655e-01 1.0542e-01 7.2817e-03 4.1584e-02 -6.0000e+00 6.6951e-01 -1.4048e-01 7.1620e-03 2.4079e-02 -6.0000e+00 3.9968e-01 4.5235e-02 3.3412e-03 8.4310e-03 -6.0000e+00 1.6873e-01 5.0593e-04 -7.8604e-04 7.8408e-05 1.5278e-04 -6.0000e+00 1.2256e-02 3.3299e-02 -1.4619e-04 11 8 0 10 0 0 12.21 23.28 0.26 0.03330 0.02739 253 61 1 5 0 190.790 26.51 20.01 23.28 22.59 12.3 870.52 -149517 -118322 -136863 -156493 -153672 -176987 -157521 -92877 -139740 -93254 -115182 -67676 -53028 -39036 -42735 -28560 -56517 -35311 -29480 -16801 -15597 -45074 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