File name: Pandora74s1_EdwardsCA_20221017_L2Fit_fout2c10d20220504p1-8.txt File generation date: 20241126T142129.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: James Podolske Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 74 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora74_OF_v3d20211222.txt Instrument calibration file used: Pandora74s1_CF_v10d20220504.txt Level 1 file used: Pandora74s1_EdwardsCA_20221017_L1_smca1c10d20220504p1-8.txt Full location name: NASA Neil A. Armstrong Flight Research Center Short location name: EdwardsCA Country of location: United States Location latitude [deg]: 34.9600 Location longitude [deg]: -117.8811 Location altitude [m]: 692 Local noon date: 20221017 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8 "redo SO2 MLE on 1.8" First and last pixel inside fitting window: 239 380 Nominal wavelengths inside fitting window [nm]: 305.1340 305.2752 305.4164 305.5576 305.6987 305.8399 305.9810 306.1221 306.2632 306.4043 306.5454 306.6865 306.8275 306.9686 307.1096 307.2506 307.3916 307.5326 307.6736 307.8145 307.9555 308.0964 308.2374 308.3783 308.5192 308.6601 308.8009 308.9418 309.0827 309.2235 309.3643 309.5051 309.6459 309.7867 309.9275 310.0683 310.2090 310.3498 310.4905 310.6312 310.7719 310.9126 311.0533 311.1940 311.3346 311.4752 311.6159 311.7565 311.8971 312.0377 312.1783 312.3188 312.4594 312.5999 312.7405 312.8810 313.0215 313.1620 313.3024 313.4429 313.5834 313.7238 313.8642 314.0047 314.1451 314.2855 314.4258 314.5662 314.7066 314.8469 314.9872 315.1276 315.2679 315.4082 315.5484 315.6887 315.8290 315.9692 316.1094 316.2497 316.3899 316.5301 316.6702 316.8104 316.9506 317.0907 317.2308 317.3710 317.5111 317.6512 317.7913 317.9313 318.0714 318.2114 318.3515 318.4915 318.6315 318.7715 318.9115 319.0515 319.1914 319.3314 319.4713 319.6112 319.7511 319.8910 320.0309 320.1708 320.3106 320.4505 320.5903 320.7302 320.8700 321.0098 321.1496 321.2893 321.4291 321.5688 321.7086 321.8483 321.9880 322.1277 322.2674 322.4071 322.5467 322.6864 322.8260 322.9657 323.1053 323.2449 323.3845 323.5240 323.6636 323.8031 323.9427 324.0822 324.2217 324.3612 324.5007 324.6402 324.7797 324.9191 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221017T142910.9Z 8325.603599 247 1 47.67 2 84.87 105.23 12.26 227.04 0.00 1 0.00 1 0 25 6.380e-01 4.980e-02 4.971e-01 4.104e-02 8.996616e-01 2.413747e-02 9.333003e-03 -6.000000e+00 3.797264e-01 226.27 -2.00 3.37 -2.00 322.25 0.00e+00 -2.198569e-02 1.113274e-02 1.003514e-02 -6.000000e+00 1.769373e-02 284.37 -2.00 20.00 -2.00 321.68 0.00e+00 9.643 0.014 302.00 328.00 3 1.2887e+00 8.7351e-02 1.2947e-01 -6.0000e+00 9.3829e-01 1.5121e+00 1.1185e-01 1.3286e-01 -6.0000e+00 1.0208e+00 -1.8603e+00 7.4180e-02 3.7399e-02 -6.0000e+00 6.0809e-01 6.8578e-01 3.6036e-02 1.8647e-02 -6.0000e+00 2.5777e-01 8.8074e-06 -1.6367e-04 1.1861e-03 1.6105e-04 -6.0000e+00 1.8742e-02 3.7448e-02 -1.2556e-04 12 9 8 11 4 0 27.17 22.82 0.77 0.03745 0.03622 21 5 1 5 0 2269.480 26.11 19.97 22.82 18.27 12.3 849.56 5489 900000 104864 244702 900000 -58785 114803 16134 -121199 134472 -30285 142149 67048 293368 900000 -9814 41656 56047 129853 29509 -25612 -2311 223920 4070 167948 -19813 -30225 64414 2344 -26544 -22316 94550 73049 145271 -10258 900000 4488 13714 58035 8509 30038 68215 900000 25554 6288 158202 29121 2715 54873 -31489 81387 58216 77450 159031 35051 34708 67948 15042 78797 62776 116157 -11051 135419 27969 69206 42625 4029 25545 31909 22650 49973 24801 67981 5889 -16023 41854 -14148 -17324 6644 -12468 12616 6679 17614 -8536 14472 -8971 6519 5822 -10219 6870 -13722 1830 584 6073 -4991 2740 -12623 -8149 -6892 -15238 -735 -11502 6006 2075 5780 4785 -12731 4417 -2864 6710 650 4945 -4132 4428 1364 1408 -886 -3180 -1763 2902 7222 153 6140 2283 3608 -1794 -738 -1805 1609 -2938 66 424 1848 11 934 509 435 -790 516 -2474 -327 -761 339 900000 4193 9784 900000 -4273 4590 704 -20594 5376 -2312 5683 2681 11729 900000 -785 1968 2241 5192 1394 -1955 -143 8953 296 6715 -1800 -2637 2575 119 -1930 -1703 3780 2921 5808 -671 900000 310 1047 3713 897 2620 4364 900000 2146 603 6325 2096 261 3291 -4464 4556 4422 5264 6358 4064 4163 5705 1985 5041 4518 5109 -1900 5956 3802 6087 4942 725 4085 5486 4618 7992 4958 8154 1177 -3524 4853 -2941 -4156 1488 -3938 3581 2243 5634 -3788 5381 -4376 2763 2444 -4821 2555 -6035 688 238 2695 -2894 1698 -10447 -7070 -5925 -13464 -509 -8093 3554 1377 3882 3463 -11962 3920 -3149 7619 853 6406 -5848 5595 1734 1818 -1222 -4716 -2651 4061 9241 204 7512 2821 4342 -2237 -983 -2829 2806 -6014 144 984 4573 29 2655 1474 1280 -2330 1425 -6568 -796 -1805 SS 20221017T144023.2Z 8325.611380 250 1 48.04 2 82.66 106.90 14.02 234.65 0.00 1 0.00 1 0 17 6.963e-01 1.139e-02 3.963e-01 7.167e-03 7.878982e-01 4.183217e-03 8.809359e-03 -6.000000e+00 4.138218e-01 226.27 -2.00 3.37 -2.00 322.10 0.00e+00 3.901770e-03 2.659685e-03 7.592608e-03 -6.000000e+00 1.873410e-02 284.37 -2.00 20.00 -2.00 321.60 0.00e+00 7.241 0.006 302.00 328.00 3 1.1262e+00 1.7325e-02 8.7539e-02 -6.0000e+00 1.0236e+00 2.5672e-01 2.6411e-02 6.6636e-02 -6.0000e+00 1.1125e+00 -3.5883e-01 2.7396e-02 3.2223e-02 -6.0000e+00 6.6184e-01 1.3762e-01 1.2141e-02 7.9142e-03 -6.0000e+00 2.7868e-01 1.0771e-04 -1.1852e-03 2.1427e-04 1.7630e-04 -6.0000e+00 2.0591e-02 3.7685e-02 -1.7414e-04 12 9 8 11 4 0 -5.63 22.87 0.35 0.03769 0.02878 104 25 1 5 0 461.910 26.21 20.00 22.87 19.23 12.2 855.17 -183429 -214132 -247689 -236713 -246220 900000 -235830 -107787 -167140 70347 -242334 -390 -180702 -159297 45745 -71747 210752 -28159 225653 10001 -1417 -15908 -67638 18949 -98133 -13061 -56934 900000 -17270 176083 42391 44784 44403 -12434 8455 -34146 15495 11694 38473 11944 46293 22440 97 35095 -11992 41969 -4447 6164 10876 18062 14441 7437 9354 2156 -345 3916 12921 3037 18524 4422 16637 10737 12127 6517 -2928 6471 3662 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-885 -1228 890 -451 1365 35 303 -358 64 -332 SS 20221017T145053.5Z 8325.618675 253 1 48.04 2 80.61 108.51 15.81 240.33 0.00 1 0.00 1 0 17 4.105e-01 6.310e-03 1.384e-01 2.626e-03 6.662983e-01 1.471372e-03 7.587997e-03 -6.000000e+00 2.422829e-01 226.27 -2.00 3.37 -2.00 321.52 0.00e+00 6.381814e-03 7.908762e-04 3.652767e-03 -6.000000e+00 1.093583e-02 284.37 -2.00 20.00 -2.00 320.94 0.00e+00 5.837 0.003 302.00 328.00 3 9.3579e-01 5.3554e-03 6.4905e-02 -6.0000e+00 5.9923e-01 9.0123e-02 7.5263e-03 3.8625e-02 -6.0000e+00 6.5106e-01 -1.0909e-01 7.6074e-03 2.2994e-02 -6.0000e+00 3.8867e-01 3.1532e-02 3.5388e-03 8.7968e-03 -6.0000e+00 1.6405e-01 4.9483e-04 -8.5646e-04 7.9312e-05 1.4627e-04 -6.0000e+00 1.1941e-02 3.6701e-02 -1.4897e-04 11 1 0 11 4 0 -5.62 22.96 0.26 0.03670 0.03027 250 60 1 5 0 192.120 26.21 20.01 22.96 20.42 12.2 861.41 -121519 -149836 -150384 -128144 -148017 -179985 -144168 -138222 -97229 -90843 -110302 -53541 -63066 -37848 -67437 -64597 -22804 -10960 5036 -23342 -25068 -25942 -23763 -16975 -40609 -25344 -40392 -30116 -23042 -2591 -8252 -3575 -5234 -16026 -14601 -16418 -8778 -6928 -1872 -3431 5246 -1257 1931 -755 58 566 2363 4360 2526 7147 5605 5549 4553 5605 1398 446 1268 635 3995 379 2575 4847 4778 2184 1087 1815 1380 2957 2670 2815 1369 1389 -823 -900 -3312 -2828 -1881 -2707 -152 -1914 -754 -2402 -2028 -749 -348 261 885 620 87 595 42 -534 -1090 -199 -304 71 236 -71 -236 -589 -857 -893 -316 -362 -1775 -667 -236 408 1155 845 238 134 123 -45 162 622 389 20 246 -245 471 71 574 -82 261 -855 35 254 -392 -165 -477 -377 88 -86 -13 -85 304 38 51 18 109 -116 -596 -1087 -1123 -711 -979 -1728 -1077 -1091 -560 -523 -871 -308 -525 -315 -935 -1006 -263 -124 52 -334 -364 -393 -380 -272 -866 -481 -888 -604 -467 -51 -210 -101 -167 -557 -498 -627 -363 -341 -105 -222 337 -92 143 -59 5 47 200 383 242 729 655 710 644 834 225 75 212 105 633 65 473 987 1099 554 275 455 361 829 866 999 516 519 -298 -301 -1028 -826 -553 -895 -58 -868 -387 -1385 -1234 -445 -220 172 596 418 57 395 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