File name: Pandora169s1_Egbert_20201216_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241102T222828.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20201216_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20201216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201216T161727.6Z 7655.678792 153 1 49.19 2 68.86 165.83 80.40 140.18 0.00 1 0.00 1 0 25 1.908e-02 6.314e-03 7.271e-03 1.433e-03 3.493420e-01 7.361929e-04 4.241617e-03 -6.000000e+00 1.123240e-02 222.14 -2.00 3.58 -2.00 318.03 0.00e+00 1.161031e-03 1.297704e-04 1.634935e-04 -6.000000e+00 4.881411e-04 272.83 -2.00 20.00 -2.00 317.49 0.00e+00 2.747 0.000 302.00 328.00 3 4.1488e+00 1.9469e-03 3.1868e-02 -6.0000e+00 2.7611e-02 5.9804e-02 2.2041e-03 1.7834e-02 -6.0000e+00 3.0100e-02 -1.5230e-02 1.4302e-03 8.9704e-03 -6.0000e+00 1.7915e-02 -4.9070e-03 7.3311e-04 2.7858e-03 -6.0000e+00 7.4989e-03 3.7892e-04 -1.4917e-04 4.5498e-05 3.4598e-05 -6.0000e+00 5.9251e-04 -2.3385e-03 6.1623e-05 10 0 0 10 0 0 99.95 22.65 0.16 -0.00234 -0.00346 60 13 1 5 0 819.730 26.41 20.00 22.65 -4.00 22.3 879.19 8047 -5906 1670 -6835 6362 -1493 7661 -94 -2500 -6561 -7429 -1421 -2166 -2617 -732 -274 -810 -1735 2629 -133 575 -577 2005 330 1231 -1991 -1383 -2706 1219 1223 599 2851 601 -2408 -3780 -897 -2419 -1117 -521 -997 -1575 -829 -691 -598 -636 451 -878 414 -816 354 1289 780 819 1707 981 1185 543 286 455 311 864 1908 1329 1588 -116 -861 11 -248 860 1658 551 775 -49 47 153 -612 -124 -579 -141 -132 -978 -1298 -2178 -1820 -548 -775 16 143 200 222 330 225 362 556 452 392 525 598 -385 -668 -442 -848 -204 310 -585 -1404 -658 -758 -99 351 135 81 116 11 197 853 889 335 354 -218 -228 -16 455 205 547 195 247 1313 758 11 -206 -659 -214 155 70 -437 -203 344 -35 -125 205 -367 -444 438 -402 110 -471 365 -89 440 -6 -189 -544 -640 -123 -212 -298 -94 -39 -124 -283 431 -23 102 -104 362 63 247 -426 -294 -566 239 241 126 644 149 -633 -987 -228 -666 -345 -186 -405 -698 -384 -330 -289 -309 218 -428 199 -396 174 657 423 468 1013 605 744 348 184 289 197 559 1292 963 1205 -90 -652 8 -180 647 1338 477 691 -44 41 127 -478 -91 -416 -105 -107 -866 -1238 -2202 -1911 -597 -880 19 171 238 258 368 238 365 556 470 437 629 764 -513 -892 -569 -1042 -241 369 -729 -1827 -879 -1049 -142 524 210 127 180 17 283 1180 1224 474 520 -331 -351 -24 680 301 777 269 334 1779 1073 17 -320 -1050 -346 256 119 -772 -365 624 -64 -224 360 -631 -756 SS 20201216T162344.0Z 7655.683149 157 1 44.09 2 68.60 167.35 79.72 141.39 0.00 1 0.00 1 0 17 1.614e-02 6.479e-03 7.186e-03 1.538e-03 3.479013e-01 7.906890e-04 4.225352e-03 -6.000000e+00 9.508289e-03 222.14 -2.00 3.58 -2.00 317.87 0.00e+00 1.088640e-03 1.332569e-04 1.377536e-04 -6.000000e+00 4.131233e-04 272.83 -2.00 20.00 -2.00 317.33 0.00e+00 2.715 0.000 302.00 328.00 3 4.2257e+00 2.0847e-03 3.1567e-02 -6.0000e+00 2.3373e-02 6.7696e-02 2.3582e-03 1.7736e-02 -6.0000e+00 2.5479e-02 -2.1749e-02 1.5060e-03 8.9069e-03 -6.0000e+00 1.5164e-02 -1.5231e-03 7.6636e-04 2.7584e-03 -6.0000e+00 6.3486e-03 3.6103e-04 1.0734e-04 4.8690e-05 3.4125e-05 -6.0000e+00 5.0146e-04 -2.5003e-03 1.0002e-04 12 9 1 12 1 1 99.97 22.65 0.21 -0.00250 -0.00169 39 10 1 5 0 1097.950 26.41 20.00 22.65 -3.80 22.3 880.25 -620 -4299 -4326 -4700 444 -943 6878 4123 -2224 -1947 -7209 -2951 -5796 -743 -627 1245 -843 -971 2296 564 344 -846 1065 537 1281 -2795 -1585 -2686 93 -471 1810 2792 1635 -1711 -3729 -2013 -1341 -1196 86 -1225 -697 -830 -543 -827 -814 388 -548 -257 -596 145 1591 1246 724 1464 1679 1192 1078 80 -54 -226 1671 1410 1438 1269 98 -1217 311 -104 1092 1154 348 412 166 258 188 -207 59 -307 -513 -308 -1138 -1328 -2096 -1609 -840 -917 55 280 -182 271 428 302 127 866 689 466 434 633 -623 -500 -650 -986 -272 596 -484 -1311 -838 -784 -68 355 136 -76 72 268 270 738 505 530 353 -90 -113 -109 269 284 614 309 457 1209 996 -240 -99 -655 -218 164 188 -564 -71 343 77 -134 68 -480 -504 -39 -313 -326 -342 28 -62 439 284 -180 -167 -670 -279 -640 -91 -85 186 -139 -169 406 105 66 -165 208 111 279 -657 -368 -608 20 -101 405 681 418 -468 -1016 -536 -383 -395 32 -533 -320 -404 -273 -424 -419 197 -280 -130 -302 75 853 692 432 916 1046 767 705 53 -35 -147 1096 995 1061 999 76 -952 228 -76 836 945 302 373 151 224 158 -164 45 -226 -383 -258 -1004 -1301 -2154 -1686 -930 -1047 66 332 -215 319 485 317 129 859 725 526 529 798 -842 -672 -828 -1203 -323 711 -600 -1686 -1127 -1078 -95 533 211 -118 111 403 388 1003 704 743 511 -138 -170 -167 399 417 859 427 608 1616 1380 -352 -154 -1035 -354 270 318 -980 -126 618 139 -238 119 -810 -859 SS 20201216T162852.9Z 7655.686723 160 1 3.80 2 68.40 168.60 79.16 142.39 0.00 1 0.00 1 0 25 2.809e-02 8.940e-03 2.328e-02 5.409e-03 3.474688e-01 2.782025e-03 4.282216e-03 -6.000000e+00 1.653077e-02 222.14 -2.00 3.58 -2.00 317.68 0.00e+00 1.787266e-03 4.452415e-04 1.394936e-04 -6.000000e+00 7.190026e-04 272.83 -2.00 20.00 -2.00 317.13 0.00e+00 2.693 0.000 302.00 328.00 3 3.9591e+00 7.3013e-03 3.1436e-02 -6.0000e+00 4.0635e-02 7.1942e-02 8.2393e-03 1.7858e-02 -6.0000e+00 4.4308e-02 -2.2973e-02 5.1770e-03 8.9668e-03 -6.0000e+00 2.6369e-02 -3.2408e-03 2.6164e-03 2.9068e-03 -6.0000e+00 1.1032e-02 4.7978e-04 -7.6205e-04 1.7015e-04 3.5919e-05 -6.0000e+00 8.7276e-04 -1.5564e-03 -7.9238e-05 12 9 1 12 1 1 999.00 22.65 0.16 -0.00156 -0.00728 2 9 1 5 0 1207.430 26.41 20.01 22.65 -3.67 22.2 880.99 7375 137 -10374 -1476 -6442 15845 9366 2359 -8865 3260 -10180 2748 -358 -255 958 3745 -2884 4983 -1058 5781 1437 -1886 -4235 1391 -4135 1256 -4100 -1205 -789 -3503 320 3361 944 173 -5267 -1808 -1101 -872 -966 -2772 -864 -1028 -217 -1689 1819 174 -1523 -780 -1214 188 2013 -790 2704 1873 588 1433 510 2119 -336 -762 2951 774 2723 687 1391 -736 682 -1453 2342 456 309 828 1197 179 387 -733 982 1127 182 -467 -1231 -1399 -3187 -2249 -622 -1078 -349 -370 82 -6 -1062 411 -138 1488 833 948 682 127 -604 -1065 -1225 -38 -451 643 -766 -1006 -1099 -515 -299 240 231 300 928 612 -136 650 449 788 -420 -273 -266 393 253 112 508 273 623 1476 747 466 -26 -518 142 393 -102 -576 -208 414 -212 -396 133 -673 -387 489 11 -922 -117 -501 976 637 187 -850 296 -1072 273 -41 -34 145 613 -535 911 -213 1132 298 -406 -948 310 -1013 303 -1035 -289 -183 -839 79 878 270 51 -1601 -533 -344 -306 -389 -1269 -421 -525 -113 -902 952 92 -817 -414 -648 101 1115 -471 1649 1195 389 960 349 1429 -229 -519 2004 561 2063 551 1121 -584 519 -1116 1831 387 277 762 1100 161 334 -597 748 841 142 -393 -1128 -1370 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