File name: Pandora169s1_Egbert_20210115_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241102T225452.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210115_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210115T171247.4Z 7685.717216 166 1 48.84 2 65.32 175.91 70.93 141.82 0.00 1 0.00 1 0 17 3.427e-02 7.825e-03 1.368e-02 2.410e-03 3.689328e-01 1.242463e-03 4.474573e-03 -6.000000e+00 2.027084e-02 223.34 -2.00 3.58 -2.00 318.13 0.00e+00 1.704025e-03 2.243465e-04 2.487329e-04 -6.000000e+00 8.705201e-04 271.02 -2.00 20.00 -2.00 317.63 0.00e+00 2.379 0.000 302.00 328.00 3 5.4530e+00 3.2963e-03 2.9750e-02 -6.0000e+00 4.9991e-02 6.1085e-02 3.7304e-03 1.8888e-02 -6.0000e+00 5.4469e-02 -1.9911e-02 2.4589e-03 9.5611e-03 -6.0000e+00 3.2355e-02 1.0004e-03 1.2697e-03 3.1473e-03 -6.0000e+00 1.3490e-02 1.3870e-04 -1.9255e-05 7.5914e-05 3.7671e-05 -6.0000e+00 1.0647e-03 -3.3381e-03 5.6620e-05 11 8 0 10 0 0 99.96 22.68 0.60 -0.00334 -0.00348 16 3 1 5 0 3051.480 26.41 19.99 22.68 9.63 25.2 1003.46 -3 3303 7008 9613 -22566 4614 6725 10911 -2908 -12682 -4724 -4160 -10460 -9157 6123 -486 -3836 -1138 5743 -8941 2921 -2255 -3346 -1267 -175 -687 -2202 2737 915 510 626 -305 706 -4137 -4851 353 -3048 1811 -505 -2521 -1014 -710 -1512 -1141 476 1220 345 426 241 665 1665 1353 1206 1154 818 1532 1909 933 678 -1145 1230 1784 1070 1010 1775 -444 606 -498 835 1920 1271 713 338 506 776 -580 -1084 -2115 -1314 -1188 -888 -552 -1948 -2010 -1176 -1760 151 -181 -37 0 353 -183 228 -102 155 264 917 908 -440 -532 -702 -937 -736 198 -483 -1264 -573 -289 225 502 691 284 377 452 84 -20 106 -389 271 -404 8 633 704 402 838 239 2 959 982 -127 -252 -613 -267 655 -12 -375 121 488 9 101 -254 -821 -668 0 182 387 504 -1486 229 342 587 -195 -983 -352 -328 -992 -1003 674 -64 -558 -171 851 -1570 471 -384 -589 -230 -33 -135 -439 508 168 95 125 -67 167 -1055 -1222 85 -807 523 -173 -997 -432 -317 -702 -536 222 568 161 199 113 317 828 717 675 676 497 944 1191 585 422 -721 779 1190 766 760 1346 -333 434 -359 624 1540 1091 634 301 438 636 -448 -791 -1521 -978 -963 -785 -524 -1968 -2117 -1286 -2015 177 -217 -44 0 393 -193 230 -103 162 295 1102 1166 -592 -715 -912 -1157 -876 236 -602 -1645 -767 -399 323 751 1071 448 588 681 121 -28 148 -557 400 -617 12 964 1051 587 1187 329 3 1301 1389 -190 -391 -979 -434 1088 -20 -665 218 887 16 182 -446 -1412 -1136 SS 20210115T172338.5Z 7685.724751 169 1 39.02 2 65.23 178.70 69.76 144.20 0.00 1 0.00 1 0 17 2.085e-02 6.372e-03 7.705e-03 1.580e-03 3.675931e-01 8.159786e-04 4.473858e-03 -6.000000e+00 1.232858e-02 223.34 -2.00 3.58 -2.00 317.87 0.00e+00 1.185466e-03 1.366809e-04 2.099012e-04 -6.000000e+00 5.295931e-04 271.02 -2.00 20.00 -2.00 317.36 0.00e+00 2.371 0.000 302.00 328.00 3 4.4688e+00 2.1534e-03 2.9646e-02 -6.0000e+00 3.0404e-02 6.1916e-02 2.4301e-03 1.8799e-02 -6.0000e+00 3.3130e-02 -1.9106e-02 1.5626e-03 9.4635e-03 -6.0000e+00 1.9679e-02 -2.1785e-05 7.9855e-04 2.9017e-03 -6.0000e+00 8.2037e-03 3.7526e-04 -3.0733e-04 4.9614e-05 3.6302e-05 -6.0000e+00 6.4766e-04 -3.0879e-03 1.5682e-05 12 1 1 12 1 1 99.90 22.68 0.34 -0.00309 -0.00540 29 8 1 5 0 1294.870 26.41 20.00 22.68 10.26 25.3 1008.10 470 88 6910 -3461 -4151 -4451 5332 -6659 -3129 -9881 -9978 -5728 -2904 -4621 4347 -1313 -1918 -2656 3200 -2625 2499 -2734 618 742 1110 -1846 -73 -1669 1466 -1262 813 421 1401 -2709 -3329 -1280 -1557 -773 -638 -1474 -599 -568 -187 -632 79 60 -11 177 -12 781 949 1578 1205 1678 592 561 1254 349 430 168 726 1749 1224 1514 329 -149 -69 -251 667 1535 487 617 -84 427 -40 -253 -126 -989 -715 -424 -1159 -1098 -2209 -1818 -670 -743 -21 -169 -143 117 365 30 104 386 348 323 660 703 -188 -554 -652 -1014 -215 115 -605 -1433 -604 -667 -89 521 377 275 189 91 218 446 420 130 395 -67 84 250 447 436 802 171 276 1043 837 -122 -285 -462 -289 138 215 -320 0 402 -139 -402 149 -456 -562 27 6 435 -233 -261 -290 329 -480 -241 -863 -901 -528 -297 -567 569 -192 -306 -452 540 -488 451 -524 117 148 234 -417 -16 -363 298 -266 180 104 373 -779 -942 -353 -464 -250 -245 -626 -279 -281 -90 -313 39 30 -5 87 -6 390 501 894 733 1021 379 370 833 234 282 110 488 1247 911 1200 267 -117 -52 -186 522 1264 441 559 -77 388 -34 -204 -94 -718 -546 -345 -1074 -1079 -2270 -1972 -735 -867 -25 -204 -172 135 410 32 105 400 367 363 794 899 -248 -731 -843 -1264 -252 135 -763 -1857 -816 -917 -125 778 578 432 290 137 317 613 574 184 569 -102 130 380 658 639 1117 238 370 1403 1159 -178 -442 -722 -466 225 367 -557 0 705 -246 -716 253 -772 -935 SS 20210115T173446.4Z 7685.732482 174 1 2.88 2 65.23 181.56 68.63 146.69 0.00 1 0.00 1 0 17 1.839e-02 6.764e-03 7.865e-03 1.758e-03 3.684407e-01 9.085308e-04 4.469170e-03 -6.000000e+00 1.087896e-02 223.34 -2.00 3.58 -2.00 317.76 0.00e+00 8.045783e-04 1.472964e-04 1.279458e-04 -6.000000e+00 4.670685e-04 271.02 -2.00 20.00 -2.00 317.25 0.00e+00 2.371 0.000 302.00 328.00 3 2.0768e+00 2.3920e-03 2.9641e-02 -6.0000e+00 2.6830e-02 4.3552e-02 2.6945e-03 1.8791e-02 -6.0000e+00 2.9230e-02 -1.8861e-02 1.7087e-03 9.4257e-03 -6.0000e+00 1.7363e-02 -1.4365e-03 8.6751e-04 2.8175e-03 -6.0000e+00 7.2416e-03 4.1496e-03 6.3819e-05 5.5219e-05 3.5705e-05 -6.0000e+00 5.7122e-04 -4.2624e-03 9.1623e-05 12 9 1 12 1 1 99.96 22.70 0.22 -0.00426 -0.00378 24 98 1 5 0 107.870 26.41 20.01 22.70 11.15 25.4 1013.17 -2500 1908 -1789 -4290 -9721 637 -6730 1937 -4895 -2623 -8650 -2326 -5720 -1421 -305 411 -3216 2271 75 1877 -670 47 118 2714 570 568 -2300 -1227 -2068 789 1755 3828 1197 -718 -3707 -1544 -2763 -1191 -464 6 -998 -576 -612 -417 -713 765 -75 -227 -790 243 1164 826 1294 1044 573 395 970 -683 713 279 1370 1359 1812 1439 129 -433 -60 -115 1649 1222 509 163 150 12 314 -232 -237 -438 -102 -428 -1163 -1691 -2099 -1780 -775 -647 -97 -60 252 33 510 418 209 633 962 150 174 613 -448 -613 -508 -683 -236 654 -687 -1288 -915 -755 -239 405 115 130 -191 328 207 803 770 523 425 -199 -752 -20 296 427 660 512 182 1534 789 251 -45 -440 -403 217 145 -337 -120 376 -161 -304 96 -507 -523 -164 134 -136 -322 -714 41 -485 142 -427 -238 -862 -232 -628 -176 -44 66 -576 408 15 370 -130 9 23 557 127 131 -548 -279 -457 171 403 954 334 -212 -1104 -448 -875 -405 -176 2 -467 -285 -314 -217 -374 396 -39 -117 -412 128 648 473 789 676 370 262 653 -466 473 185 923 982 1355 1155 102 -345 -45 -86 1296 1026 450 151 139 11 271 -191 -179 -337 -78 -356 -1053 -1641 -2208 -1903 -841 -746 -113 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