File name: Pandora169s1_Egbert_20210218_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241102T232019.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210218_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210218T134410.8Z 7719.572347 66 1 41.63 2 75.98 121.87 106.78 50.10 0.00 1 0.00 1 0 17 1.571e-01 9.986e-03 7.372e-02 3.585e-03 5.446139e-01 1.898897e-03 6.402143e-03 -6.000000e+00 9.400580e-02 224.70 -2.00 3.58 -2.00 319.89 0.00e+00 5.645038e-03 5.815705e-04 5.296779e-04 -6.000000e+00 4.049908e-03 271.31 -2.00 20.00 -2.00 319.41 0.00e+00 4.039 0.001 302.00 328.00 3 4.1132e+00 5.3645e-03 4.8212e-02 -6.0000e+00 2.3253e-01 1.5266e-01 6.3812e-03 2.8748e-02 -6.0000e+00 2.5334e-01 -1.0577e-01 5.5559e-03 1.5568e-02 -6.0000e+00 1.4983e-01 3.1775e-02 2.8944e-03 7.4611e-03 -6.0000e+00 6.2346e-02 8.8746e-05 -1.1233e-03 1.1057e-04 8.3507e-05 -6.0000e+00 4.9308e-03 -2.6649e-06 -5.1758e-05 12 9 9 12 1 1 99.93 22.68 0.30 -0.00000 -0.00844 16 4 1 5 0 2438.290 26.41 20.00 22.68 -2.74 24.0 999.23 42000 900000 -47490 23658 -66938 -48426 900000 30969 -40742 -43126 -62316 -34734 -49375 -69465 16965 -33272 -23422 -18454 15445 -24160 -14473 -10263 -4613 443 -11401 -418 1209 -5986 13872 4292 -3646 9859 -10732 -13148 -2724 9356 -3932 8154 -2188 -4260 4818 453 -684 -1942 -5961 -1096 1891 7266 4723 2580 2953 6729 4381 2031 8216 19 1985 1686 961 -1059 2512 2908 2325 2089 2932 -1693 1907 -588 463 181 1733 -118 263 733 -2640 -1196 -686 -2117 -2874 534 -426 -271 -3550 -2040 -926 -1687 85 -97 732 -360 1229 18 1406 143 505 431 931 214 0 -185 -755 -845 -938 32 -760 -1622 -1167 -392 152 487 141 -83 -173 390 -125 22 1437 244 310 -33 -403 790 793 992 837 -601 433 395 818 -296 -331 -357 -163 17 -63 -47 11 -94 12 73 203 -488 -424 309 900000 -956 249 -1501 -898 900000 318 -865 -992 -1792 -868 -1684 -3501 479 -1711 -1230 -1010 666 -1556 -876 -603 -264 25 -765 -26 76 -396 771 276 -285 786 -1153 -1523 -284 878 -448 956 -332 -760 877 92 -147 -433 -1406 -252 432 1616 1111 650 800 1919 1375 692 2773 7 740 629 356 -398 947 1179 1040 1013 1463 -868 932 -298 250 108 1094 -78 173 463 -1603 -663 -358 -1118 -1641 334 -301 -211 -3025 -1806 -854 -1638 85 -98 739 -357 1149 16 1202 125 470 443 1050 264 0 -241 -952 -1000 -1058 36 -892 -1995 -1488 -520 213 725 222 -135 -281 614 -190 33 2099 369 486 -54 -654 1251 1226 1495 1227 -866 609 568 1246 -486 -573 -642 -302 32 -124 -97 22 -197 26 150 405 -946 -809 SS 20210218T135458.2Z 7719.579840 69 1 10.40 2 74.36 124.03 105.30 52.23 0.00 1 0.00 1 0 17 8.776e-02 7.120e-03 5.538e-02 3.426e-03 5.016962e-01 1.791300e-03 5.935683e-03 -6.000000e+00 5.214247e-02 224.70 -2.00 3.58 -2.00 319.39 0.00e+00 2.713444e-03 4.723234e-04 4.571458e-04 -6.000000e+00 2.232449e-03 271.31 -2.00 20.00 -2.00 318.90 0.00e+00 3.644 0.001 302.00 328.00 3 3.1971e+00 4.9404e-03 4.3741e-02 -6.0000e+00 1.2897e-01 8.6312e-02 5.7561e-03 2.6082e-02 -6.0000e+00 1.4041e-01 -4.4824e-02 4.6572e-03 1.3492e-02 -6.0000e+00 8.3332e-02 5.0707e-03 2.4547e-03 4.8422e-03 -6.0000e+00 3.4635e-02 3.4488e-04 -7.9737e-04 1.0564e-04 5.6608e-05 -6.0000e+00 2.7280e-03 -1.2869e-03 -4.8662e-05 12 9 1 12 1 1 99.13 22.70 0.41 -0.00129 -0.00728 12 13 1 5 0 786.430 26.41 20.01 22.70 -2.61 24.1 1000.64 -18895 49888 -21247 -804 -38832 -19725 -11375 25837 -18717 -26605 -34884 -16952 -27637 -13036 1550 -16324 -4583 -11821 6532 -5171 -3071 3166 -2781 -4409 -2648 -4565 -4916 -10935 7212 -4063 374 -1118 -4031 -7705 -1114 -1138 -1370 -1732 -787 -3671 887 -1019 543 -2108 -877 -1914 158 1735 1837 -165 422 2626 2570 1498 3259 528 1199 76 -835 1139 1351 1139 2575 1462 2209 -190 1484 239 663 1191 665 816 221 1040 230 -468 347 -1333 -678 -418 -1134 -603 -2646 -1700 -725 -702 -506 487 -104 -196 132 92 259 156 -496 695 1136 501 -785 -437 -957 -618 -534 1054 -654 -1161 -749 -768 -131 530 -94 -114 -257 232 350 61 870 753 296 183 -278 235 532 326 740 -36 800 1066 560 -439 -477 -353 166 332 17 -435 -144 18 296 -169 185 -421 -529 -337 561 -473 -14 -952 -390 -219 381 -480 -793 -1195 -538 -1080 -543 68 -994 -277 -836 411 -384 -230 225 -217 -373 -235 -432 -471 -1091 593 -392 39 -135 -521 -1090 -146 -150 -196 -291 -157 -885 229 -268 147 -602 -251 -562 46 504 548 -53 145 968 1029 608 1367 236 542 35 -378 504 616 565 1393 819 1271 -110 870 135 404 809 469 600 163 767 158 -294 214 -828 -426 -300 -887 -526 -2430 -1647 -703 -724 -547 536 -115 -209 132 90 240 145 -505 749 1318 624 -1058 -588 -1224 -758 -614 1197 -798 -1441 -976 -1064 -186 782 -150 -181 -407 364 517 90 1270 1142 455 293 -451 371 811 499 1082 -51 1142 1489 854 -712 -801 -623 293 614 32 -868 -285 37 587 -340 353 -800 -986 SS 20210218T142031.6Z 7719.597588 79 1 21.21 2 70.68 129.34 101.62 57.09 0.00 1 0.00 1 0 17 4.422e-02 6.935e-03 2.337e-02 2.727e-03 4.239706e-01 1.415715e-03 5.085861e-03 -6.000000e+00 2.628014e-02 224.70 -2.00 3.58 -2.00 318.65 0.00e+00 1.828823e-03 2.970242e-04 2.339863e-04 -6.000000e+00 1.124782e-03 271.31 -2.00 20.00 -2.00 318.14 0.00e+00 2.989 0.000 302.00 328.00 3 4.1961e+00 3.8136e-03 3.6251e-02 -6.0000e+00 6.5001e-02 7.1849e-02 4.3425e-03 2.1949e-02 -6.0000e+00 7.0764e-02 -3.0043e-02 3.0907e-03 1.1073e-02 -6.0000e+00 4.1997e-02 6.5116e-04 1.6243e-03 3.6188e-03 -6.0000e+00 1.7459e-02 2.5696e-04 -5.4526e-04 8.5431e-05 4.3401e-05 -6.0000e+00 1.3743e-03 -1.4742e-03 1.5287e-05 12 9 1 12 1 1 99.96 22.70 0.38 -0.00147 -0.00557 13 7 1 5 0 1502.120 26.41 20.00 22.70 -1.75 24.3 1006.91 -16154 20018 -3698 11317 -17052 -812 22826 6694 -11940 1836 -20807 -6430 -8783 -2914 572 -3497 -3560 1935 1024 1477 -4750 5484 -1003 2311 -5416 2639 -219 105 1522 4011 -1509 3632 -2668 -2728 -3338 1887 -3820 -163 -915 -1261 -577 -249 -1580 -1653 -3143 -1209 -1370 1404 1245 -696 1185 1191 1207 1128 2163 -347 1964 -194 56 97 1875 1202 2038 1244 1449 -944 571 50 1398 925 1299 200 -71 279 -283 -47 -571 -812 -136 -732 -669 -896 -2701 -1882 -550 -994 132 117 300 227 618 267 344 288 468 539 683 846 -580 -493 -787 -902 -234 525 -404 -1721 -541 -693 -189 208 524 -22 -276 455 204 683 610 238 481 -27 -565 85 361 567 744 183 -118 946 596 -101 -481 -9 -342 391 53 -294 -454 147 41 -5 111 -349 -278 -595 596 -143 373 -685 -27 654 245 -568 82 -1191 -349 -559 -209 46 -334 -370 205 115 173 -602 641 -128 302 -803 378 -32 15 212 559 -240 614 -521 -555 -674 364 -832 -39 -259 -409 -204 -93 -616 -656 -1275 -486 -553 556 500 -292 519 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