File name: Pandora169s1_Egbert_20210410_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T010359.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210410_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210410T112624.7Z 7770.476675 63 1 49.40 2 83.27 85.19 81.60 103.95 0.00 1 0.00 1 0 38 1.256e+00 5.407e-02 3.594e-01 1.603e-02 1.035774e+00 9.688901e-03 1.220913e-02 -6.000000e+00 7.617882e-01 227.67 -2.00 3.58 -2.00 322.09 0.00e+00 3.246111e-02 4.564920e-03 5.248882e-03 -6.000000e+00 3.471728e-02 276.12 -2.00 20.00 -2.00 321.62 0.00e+00 7.788 0.009 302.00 328.00 3 1.8900e+00 3.3437e-02 1.1260e-01 -6.0000e+00 1.8911e+00 2.0837e+00 3.9121e-02 1.1163e-01 -6.0000e+00 2.0569e+00 -2.4228e+00 2.6517e-02 2.8985e-02 -6.0000e+00 1.2173e+00 9.3578e-01 1.4116e-02 2.9932e-02 -6.0000e+00 5.1206e-01 9.6451e-06 -3.2314e-03 4.3134e-04 4.2174e-04 -6.0000e+00 4.0072e-02 1.6708e-03 -8.5726e-05 12 8 8 10 0 0 68.42 22.65 0.58 0.00167 -0.02261 18 4 1 5 0 2709.380 26.41 20.00 22.65 16.62 27.4 992.54 192385 900000 174269 900000 213646 900000 372916 9895 30104 132346 7832 -4000 357876 90072 283304 -74557 237139 141423 83960 100907 260131 10460 900000 100512 116434 -44735 405971 -22380 254215 489863 900000 94967 637866 11284 118027 900000 900000 -2843 116269 42224 177259 53009 900000 -38817 100347 157526 103296 493364 900000 24229 73180 98891 56344 91795 62240 60549 48964 38436 88023 2864 81755 36824 29473 74922 21763 76897 40922 32856 23653 29988 31458 32725 35584 34639 34206 -2296 -4786 -41167 -37018 19264 -5008 10027 -11988 -9188 1961 -5573 1627 3880 -4185 7574 -3215 -1584 40386 -3018 -7605 10892 4647 -7280 2001 -5059 4488 -2215 -15009 -16828 2414 -2618 1172 849 2250 -3249 -1963 -1965 -3306 -2291 -65 -635 4136 -3000 4567 121 -3605 6125 6474 2953 -673 708 7431 -442 6562 -3476 -1030 1143 2713 -305 2690 -1228 -246 -968 -477 1338 -836 1452 -4612 5604 900000 6388 900000 3766 900000 5820 615 1309 2065 337 -210 5585 3410 4421 -19150 3729 5781 5792 5608 4059 1039 900000 3250 2802 -4268 6335 -1516 3967 7645 900000 3918 9954 1135 4091 900000 900000 -273 3927 2985 3641 3548 900000 -6131 4467 4162 4683 7699 900000 2646 5486 6275 5548 6718 5954 5694 4886 3961 5415 370 5263 3905 3785 7166 3627 7934 5914 5295 4453 5817 6375 6593 6680 5994 5290 -442 -898 -11317 -11332 4249 -1625 3226 -5154 -4060 816 -2573 725 1717 -1972 3090 -1368 -633 10938 -1302 -3941 5690 3057 -6201 1725 -4767 3700 -1753 -12024 -13133 1623 -1936 889 705 2076 -3627 -2456 -2689 -4771 -3292 -90 -874 5531 -4456 6609 185 -5575 8269 8319 3796 -870 884 8749 -599 9559 -6380 -2083 2473 6211 -762 6931 -3394 -687 -2721 -1318 3488 -2076 3286 -10541 SS 20210410T113629.8Z 7770.483679 66 1 49.69 2 81.47 86.94 79.87 105.71 0.00 1 0.00 1 0 17 6.111e-01 2.006e-02 2.458e-01 4.588e-03 9.292263e-01 2.679694e-03 1.038247e-02 -6.000000e+00 3.707964e-01 227.67 -2.00 3.58 -2.00 321.92 0.00e+00 1.310749e-02 1.481165e-03 1.878501e-03 -6.000000e+00 1.663295e-02 276.13 -2.00 20.00 -2.00 321.48 0.00e+00 6.353 0.005 302.00 328.00 3 1.8324e+00 9.7119e-03 8.1069e-02 -6.0000e+00 9.2199e-01 6.0079e-01 1.4171e-02 5.5496e-02 -6.0000e+00 1.0024e+00 -7.9942e-01 1.4860e-02 3.0769e-02 -6.0000e+00 5.9448e-01 3.2137e-01 6.8041e-03 1.6675e-02 -6.0000e+00 2.4775e-01 6.4835e-05 -1.7922e-03 1.2901e-04 2.6375e-04 -6.0000e+00 1.9085e-02 1.8313e-03 -1.3924e-04 12 8 8 10 0 0 50.09 22.65 0.46 0.00183 -0.01164 71 15 1 5 0 699.750 26.41 20.00 22.65 16.88 27.4 993.78 -169099 900000 900000 46279 147428 900000 -189838 -237807 -242456 -120581 -237863 -164822 -116873 -57225 86336 -205148 900000 -113896 -76283 -10988 48031 -91444 900000 -62245 1208 -111321 71322 -76602 55746 -18173 107669 7068 7688 -49224 -10572 110146 71319 -30617 28033 6794 33018 17516 53288 4035 26593 51496 33497 47600 57820 32578 21669 33061 24321 47027 36083 18632 27753 26682 19074 19446 14042 14352 17716 32644 13246 20786 13289 10033 10231 14634 12830 9900 2632 6895 6221 3536 724 -8151 -5366 2872 -898 374 -1977 -2662 -588 -2177 -1189 -567 -1156 712 -1137 -1527 2398 -2349 -2870 275 302 -1302 -726 -1782 -854 -1343 -1864 -2240 -1459 -3682 -1518 -1209 -202 -475 -409 -1008 -889 -743 -525 -507 829 237 1356 950 253 2206 2229 1642 559 292 1326 953 1379 -102 -105 51 8 12 222 -210 119 398 173 -167 -411 -147 -1687 -1443 900000 900000 207 659 900000 -2083 -4349 -4828 -735 -5026 -2009 -1187 -442 386 -10545 900000 -3379 -1674 -129 344 -2341 900000 -1214 14 -3664 414 -1774 399 -288 674 138 175 -2120 -305 1034 1052 -1306 786 273 1140 762 1711 220 1189 1862 1524 2012 2397 1920 1469 2254 2002 3346 3024 1916 2626 2505 1869 1869 1480 1679 2316 4207 2255 3384 2212 1835 2079 3220 3137 2577 719 1679 1375 726 147 -1909 -1421 849 -329 145 -875 -1273 -292 -1160 -654 -317 -645 376 -578 -743 1119 -1235 -1751 194 253 -1199 -731 -1842 -827 -1178 -1599 -1879 -1265 -3226 -1389 -1205 -224 -609 -556 -1499 -1365 -1132 -775 -734 1197 358 2120 1519 399 3242 3124 2234 793 404 1813 1313 2171 -189 -205 109 18 28 553 -550 317 1065 458 -421 -968 -340 -3822 SS 20210410T115112.9Z 7770.493899 71 1 49.81 2 78.83 89.49 77.38 108.34 0.00 1 0.00 1 0 17 5.241e-01 7.961e-03 6.985e-02 1.489e-03 7.691562e-01 8.257741e-04 8.706380e-03 -6.000000e+00 3.147300e-01 227.67 -2.00 3.58 -2.00 321.09 0.00e+00 5.309832e-03 3.786956e-04 1.474219e-03 -6.000000e+00 1.359289e-02 276.13 -2.00 20.00 -2.00 320.61 0.00e+00 4.983 0.002 302.00 328.00 3 1.4184e+00 2.6486e-03 6.3945e-02 -6.0000e+00 7.8252e-01 8.7998e-02 3.6815e-03 4.2348e-02 -6.0000e+00 8.4964e-01 -1.0029e-01 3.9326e-03 2.4424e-02 -6.0000e+00 5.0449e-01 2.8686e-02 1.8808e-03 1.0452e-02 -6.0000e+00 2.0921e-01 4.4112e-04 -9.4062e-04 4.2496e-05 1.3630e-04 -6.0000e+00 1.6311e-02 1.1259e-03 -1.1300e-04 11 8 0 10 0 0 65.73 22.65 0.21 0.00113 -0.00594 233 50 1 5 0 211.890 26.41 19.99 22.65 17.40 27.4 996.34 -200987 -143188 -184065 -153776 -155199 -108959 -172614 -174841 -207405 -116348 -171777 -134247 -107069 -87828 -72600 -98177 -47769 -66769 -43739 -21994 -7650 -53188 -27234 -39130 -29219 -47724 -21353 -38031 -25703 -8709 -1212 -7677 1512 -11333 -2500 2145 -1007 -6474 299 -3068 2247 496 3392 -2407 1826 4343 2424 6174 4488 3725 4279 4524 4151 4059 3801 1580 2074 262 605 1043 2107 3129 4649 3834 2024 2002 2528 1090 3413 2635 2013 1218 -53 989 231 -824 -1309 -2367 -769 -432 -1021 -733 -1919 -1956 -982 -761 -45 636 205 386 319 72 -299 -547 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