File name: Pandora169s1_Egbert_20210415_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T012102.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210415_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210415T150439.9Z 7775.628240 200 1 49.84 2 44.87 129.40 64.02 87.04 0.00 1 0.00 1 0 17 9.969e-03 7.032e-03 5.959e-04 2.906e-04 2.457223e-01 1.543557e-04 3.018679e-03 -6.000000e+00 6.003609e-03 228.07 -2.00 3.58 -2.00 316.15 0.00e+00 3.906980e-04 1.664271e-05 5.019918e-05 -6.000000e+00 2.591374e-04 276.72 -2.00 20.00 -2.00 315.56 0.00e+00 1.409 0.000 302.00 328.00 3 2.4390e+00 4.0044e-04 1.8892e-02 -6.0000e+00 1.4939e-02 3.4935e-02 4.4633e-04 1.2778e-02 -6.0000e+00 1.6206e-02 -7.3124e-03 2.5730e-04 6.3013e-03 -6.0000e+00 9.6240e-03 -3.3616e-03 1.1681e-04 1.7798e-03 -6.0000e+00 3.9952e-03 8.5169e-03 2.0719e-04 9.2400e-06 2.4634e-05 -6.0000e+00 3.1017e-04 -3.1841e-03 8.5464e-05 11 8 0 10 0 0 99.99 22.71 0.16 -0.00318 -0.00163 906 194 1 5 0 54.400 26.41 19.99 22.71 11.63 27.2 988.99 273 -781 -1604 -3510 -3249 -1505 -351 892 20 -1546 -3171 -1325 -413 -205 407 -277 -485 674 780 1021 720 481 1521 1500 1163 947 -394 -855 19 1092 1476 1964 1675 -1098 -3078 -1304 -1578 -787 -138 -739 -1293 -873 -642 -802 -367 -235 -800 -542 -477 132 1028 906 909 1053 629 874 1025 155 359 603 1114 1625 1620 1103 -191 -694 46 2 1502 1096 72 25 -89 237 96 -210 89 -197 309 -321 -1245 -1599 -2304 -1763 -852 -921 -232 -46 -79 -21 225 394 165 972 1045 513 561 514 -465 -735 -539 -775 -62 614 -514 -1429 -814 -781 -254 440 163 90 11 262 295 807 773 476 319 -83 -549 -69 207 319 821 636 468 1458 900 252 57 -413 -71 267 109 -432 -174 84 -253 -322 -27 -576 -437 49 -155 -327 -694 -586 -271 -65 168 4 -343 -723 -306 -103 -55 122 -91 -168 239 286 385 261 175 558 574 468 394 -164 -342 7 419 585 783 713 -490 -1355 -558 -726 -393 -77 -476 -874 -618 -466 -589 -268 -170 -572 -377 -325 90 721 676 684 828 512 694 823 125 298 498 901 1391 1426 1025 -180 -617 39 2 1304 1011 70 26 -91 232 92 -191 77 -162 262 -288 -1205 -1636 -2444 -1965 -964 -1112 -282 -57 -98 -26 262 436 175 992 1108 574 668 645 -598 -942 -675 -938 -74 716 -646 -1851 -1060 -1065 -349 636 238 133 16 361 389 1035 980 629 433 -116 -787 -98 295 436 1100 812 596 1840 1157 347 80 -596 -100 392 164 -682 -274 134 -408 -509 -43 -880 -656 SS 20210415T150932.9Z 7775.631631 203 1 49.82 2 44.20 130.82 63.16 87.84 0.00 1 0.00 1 0 17 1.014e-02 7.099e-03 5.121e-04 2.642e-04 2.429069e-01 1.398319e-04 2.986502e-03 -6.000000e+00 6.106503e-03 228.07 -2.00 3.58 -2.00 315.99 0.00e+00 4.214562e-04 1.458255e-05 5.073436e-05 -6.000000e+00 2.635908e-04 276.72 -2.00 20.00 -2.00 315.41 0.00e+00 1.393 0.000 302.00 328.00 3 2.3138e+00 3.6191e-04 1.8672e-02 -6.0000e+00 1.5195e-02 3.2763e-02 4.0344e-04 1.2625e-02 -6.0000e+00 1.6484e-02 -7.7476e-03 2.3206e-04 6.2249e-03 -6.0000e+00 9.7890e-03 -2.4053e-03 1.0462e-04 1.7588e-03 -6.0000e+00 4.0636e-03 9.8595e-03 1.7839e-04 8.3615e-06 2.5066e-05 -6.0000e+00 3.1550e-04 -3.0286e-03 7.9641e-05 11 8 0 10 0 0 99.98 22.71 0.18 -0.00303 -0.00169 821 175 1 5 0 60.010 26.41 20.01 22.71 11.85 27.2 989.90 301 -728 -1586 -3586 -3702 -1326 -791 493 -79 -1634 -3267 -1518 -714 -77 278 -218 -483 891 867 1245 776 532 1452 1577 1163 1079 -202 -914 -70 1042 1687 1947 1802 -963 -2985 -1360 -1505 -790 21 -678 -1187 -897 -564 -845 -299 -248 -725 -578 -473 19 1110 859 914 996 635 821 1037 179 324 536 1024 1516 1627 1087 -140 -634 1 14 1477 1064 32 12 -161 207 64 -209 4 -207 240 -294 -1230 -1585 -2369 -1771 -871 -905 -299 -87 -84 -2 197 340 84 905 1003 499 491 543 -482 -710 -523 -793 -87 597 -517 -1388 -809 -773 -230 497 227 160 59 246 303 831 778 512 361 -131 -510 -47 264 368 841 639 507 1450 876 215 4 -435 -89 217 64 -427 -181 101 -279 -293 -15 -627 -471 59 -156 -349 -765 -723 -258 -159 100 -18 -390 -801 -377 -193 -22 89 -76 -178 336 319 469 299 206 565 639 496 474 -89 -387 -28 425 667 821 809 -453 -1385 -614 -730 -414 12 -434 -837 -632 -407 -617 -217 -178 -515 -419 -336 13 811 636 714 777 513 675 862 149 266 439 859 1346 1481 1001 -130 -581 1 12 1327 1014 32 12 -163 210 61 -188 3 -177 201 -261 -1176 -1602 -2583 -1949 -1011 -1079 -360 -107 -104 -2 227 371 88 950 1050 551 576 671 -634 -928 -646 -946 -103 714 -640 -1773 -1077 -1038 -322 708 327 232 86 346 407 1048 1008 665 482 -186 -721 -65 371 496 1111 834 636 1802 1150 291 5 -617 -129 314 95 -664 -280 159 -441 -455 -24 -943 -696 SS 20210415T185919.2Z 7775.791195 352 1 50.42 2 40.46 220.00 26.93 146.99 0.00 1 0.00 1 0 17 1.836e-02 9.731e-03 7.551e-03 3.082e-03 2.513822e-01 1.623600e-03 3.071370e-03 -6.000000e+00 1.105566e-02 228.08 -2.00 3.58 -2.00 316.66 0.00e+00 9.412239e-04 1.974406e-04 1.224629e-04 -6.000000e+00 4.773659e-04 276.74 -2.00 20.00 -2.00 316.05 0.00e+00 1.313 0.000 302.00 328.00 3 6.8891e+00 4.2367e-03 1.8460e-02 -6.0000e+00 2.7510e-02 8.9517e-02 4.7401e-03 1.3062e-02 -6.0000e+00 2.9846e-02 -1.7914e-02 2.7624e-03 6.4456e-03 -6.0000e+00 1.7724e-02 -1.6644e-04 1.2866e-03 1.8902e-03 -6.0000e+00 7.3561e-03 1.0499e-04 -1.2788e-04 9.8053e-05 2.4480e-05 -6.0000e+00 5.7131e-04 -3.1989e-03 2.3880e-05 12 8 8 10 0 0 99.97 22.76 0.48 -0.00320 -0.00416 19 4 1 5 0 2652.010 26.51 20.00 22.76 13.70 27.2 992.71 -880 2242 3378 2291 -3170 1814 4949 -784 -849 1308 -6505 -3217 -2721 566 3595 -9898 1174 -1097 -779 2561 -1000 -785 1334 4135 -2131 754 -1658 281 850 2038 2371 3904 1315 -2316 -4295 1871 -3766 -2268 -1034 -473 -1352 1670 -291 -1867 85 1124 -533 1107 -961 -1149 -456 1470 -189 2529 1783 -35 1842 -183 977 -723 1459 1313 2026 1577 730 -805 635 -732 1955 372 521 422 1160 507 728 -1202 -899 -3807 -2449 -903 -856 -1580 -2157 -2548 -935 -1235 438 406 356 202 -20 -164 819 -353 -81 1793 1091 397 -25 -604 -12 -912 -1182 -256 -745 -1099 -675 -5 709 989 463 563 129 199 9 -617 396 -150 464 347 -957 824 455 586 172 448 5 601 896 -255 -650 -456 -297 464 372 -409 264 275 127 247 167 -690 -1186 -132 353 536 351 -471 247 676 -123 -145 228 -1232 -610 -560 127 878 -2961 334 -330 -241 790 -323 -254 430 1348 -764 270 -602 97 277 647 777 1345 489 -906 -1661 680 -1526 -1024 -532 -272 -844 1062 -192 -1260 56 737 -350 703 -612 -736 -300 1000 -136 1849 1345 -27 1426 -144 751 -562 1142 1081 1753 1421 661 -706 523 -598 1627 338 503 422 1153 494 673 -1047 -728 -3036 -1981 -779 -802 -1595 -2299 -2834 -1077 -1490 543 514 450 250 -24 -181 847 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