File name: Pandora169s1_Egbert_20210516_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T021342.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210516_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210516 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210516T113243.1Z 7806.481054 83 1 18.17 2 73.73 78.80 102.66 35.36 0.00 1 0.00 1 0 25 2.508e-01 1.234e-02 2.296e-01 5.980e-03 6.013158e-01 3.285395e-03 6.977592e-03 -6.000000e+00 1.526867e-01 230.89 -2.00 3.58 -2.00 320.48 0.00e+00 7.442600e-03 1.261092e-03 6.320665e-04 -6.000000e+00 6.678105e-03 280.30 -2.00 20.00 -2.00 319.89 0.00e+00 3.510 0.001 302.00 328.00 3 4.5882e+00 9.9931e-03 4.7550e-02 -6.0000e+00 3.8206e-01 5.6888e-03 1.2540e-02 3.3163e-02 -6.0000e+00 4.1331e-01 -6.3749e-02 1.1628e-02 1.8613e-02 -6.0000e+00 2.4550e-01 1.0931e-02 5.7964e-03 1.0008e-02 -6.0000e+00 1.0223e-01 8.6755e-05 -7.9568e-04 1.8315e-04 1.0828e-04 -6.0000e+00 7.8150e-03 -8.8223e-03 -1.4871e-05 12 9 9 12 1 1 96.00 22.73 0.18 -0.00882 -0.01480 9 6 1 5 0 1798.070 26.51 20.00 22.73 18.35 29.0 1010.88 -53219 900000 31686 51082 -64655 22969 -16414 -28514 -100930 -5800 -92262 -58802 -54689 -26083 25666 -106385 -28825 -33903 -38116 2158 28998 131678 35248 4354 -19609 -4135 -13396 48386 9370 32229 16295 48820 1765 -12049 -26894 49767 -26353 16500 -10190 6996 -5453 3358 -10696 87 -7044 -1034 1706 15118 4042 112 -1072 -923 -631 8499 5042 -244 2858 -1542 3287 728 2181 1386 4757 3536 5341 4673 36 -1780 3341 426 3198 -1506 894 -716 2542 -2207 3358 -1873 1107 480 673 -1881 -2789 -2841 787 -1634 -1214 -325 -272 -92 830 72 2583 -117 -28 1340 1365 -112 -849 -1301 503 -751 -652 195 -469 -2562 -1241 -899 340 -444 -180 -194 -589 628 677 686 427 522 1028 -77 -892 620 -666 1027 80 479 665 2147 683 270 -638 513 149 260 -405 -916 -425 976 -277 -585 480 -305 -387 -420 900000 185 298 -694 134 -117 -247 -1792 -48 -1725 -925 -1009 -471 365 -5611 -876 -1189 -1496 63 696 1314 834 141 -824 -158 -565 1198 330 1003 667 1758 108 -893 -2277 2156 -2403 1179 -1090 745 -725 445 -1698 13 -1154 -165 273 2215 684 21 -220 -208 -154 2046 1319 -69 806 -453 914 207 635 442 1633 1345 2099 1843 15 -751 1453 211 1676 -855 497 -388 1254 -1046 1433 -840 524 260 414 -1312 -2116 -2280 647 -1439 -1113 -303 -253 -83 714 59 2009 -95 -24 1282 1455 -133 -1070 -1661 611 -862 -708 209 -527 -3059 -1530 -1163 464 -655 -283 -316 -963 996 1035 1021 636 799 1628 -126 -1477 998 -1056 1570 120 696 949 3102 1066 455 -1151 959 290 524 -852 -1999 -943 2167 -620 -1287 1017 -626 -784 SS 20210516T121121.4Z 7806.507886 102 1 30.78 2 66.87 85.20 98.48 42.76 0.00 1 0.00 1 0 25 3.217e-02 6.444e-03 1.728e-02 1.455e-03 4.471787e-01 7.769811e-04 5.297298e-03 -6.000000e+00 1.958939e-02 230.89 -2.00 3.58 -2.00 319.17 0.00e+00 1.679532e-03 1.938093e-04 3.283649e-04 -6.000000e+00 8.486152e-04 280.30 -2.00 20.00 -2.00 318.50 0.00e+00 2.526 0.000 302.00 328.00 3 3.6816e+00 2.1643e-03 3.4572e-02 -6.0000e+00 4.9020e-02 -5.0578e-02 2.4977e-03 2.3889e-02 -6.0000e+00 5.3022e-02 4.3186e-03 1.8591e-03 1.1865e-02 -6.0000e+00 3.1484e-02 -1.3930e-02 9.6652e-04 3.6931e-03 -6.0000e+00 1.3050e-02 6.5624e-04 -3.9062e-04 4.5985e-05 4.4541e-05 -6.0000e+00 1.0017e-03 -8.8499e-03 4.1610e-05 12 9 1 12 1 1 99.98 22.74 0.12 -0.00885 -0.01179 88 31 1 5 0 339.990 26.51 19.99 22.74 21.16 29.0 1026.66 -4638 1532 595 -18817 1376 -10069 -1403 -4096 -13196 -11197 -8791 -11693 -8115 -3719 2665 -9462 -881 -4370 813 -145 3008 3474 1810 -1139 -1340 -1297 -3833 -1474 523 1010 2331 3810 2585 -2328 -4840 449 -3935 555 -1451 -807 -2233 -1299 -1765 -1596 -1437 -797 -1791 74 -479 589 1005 1014 280 1016 954 905 541 264 -258 662 1173 1824 2130 1562 388 42 786 815 2193 1399 508 270 -61 257 268 -53 440 -441 510 -221 -1207 -1318 -2038 -1896 -564 -748 -273 -120 136 -261 186 439 622 1073 905 534 483 517 -609 -910 -285 -615 70 744 -590 -1696 -864 -743 -22 481 26 -206 -104 177 309 892 934 693 227 -253 -646 -266 110 328 514 335 257 1593 716 -8 -237 -397 -83 149 -14 -488 -192 260 -63 -243 175 -263 -135 -100 36 15 -562 32 -253 -34 -114 -425 -381 -307 -459 -360 -191 145 -672 -64 -353 67 -12 262 306 159 -110 -138 -140 -431 -158 54 106 267 487 372 -371 -783 69 -649 102 -328 -202 -637 -394 -563 -521 -474 -265 -604 25 -163 207 377 396 119 460 454 427 262 128 -125 330 573 955 1224 937 243 26 479 499 1359 977 377 211 -48 193 195 -35 280 -278 325 -160 -971 -1143 -1865 -1845 -578 -789 -302 -132 149 -289 193 436 580 1029 896 572 565 651 -803 -1207 -369 -762 82 861 -732 -2183 -1126 -1023 -32 713 41 -331 -166 275 465 1272 1324 1020 344 -403 -1051 -424 170 502 750 484 360 2240 1059 -13 -390 -687 -144 265 -27 -944 -383 510 -125 -480 331 -491 -247 SS 20210516T121837.0Z 7806.512928 106 1 49.90 2 65.57 86.42 97.62 44.10 0.00 1 0.00 1 0 25 2.652e-02 6.552e-03 4.398e-03 4.999e-04 4.253613e-01 2.656217e-04 5.058130e-03 -6.000000e+00 1.614436e-02 230.90 -2.00 3.58 -2.00 318.81 0.00e+00 1.343812e-03 5.915639e-05 2.486647e-04 -6.000000e+00 6.995873e-04 280.30 -2.00 20.00 -2.00 318.13 0.00e+00 2.402 0.000 302.00 328.00 3 2.3048e+00 7.3100e-04 3.2831e-02 -6.0000e+00 4.0399e-02 -5.9031e-02 8.3528e-04 2.2632e-02 -6.0000e+00 4.3702e-02 -8.5978e-03 5.8721e-04 1.1167e-02 -6.0000e+00 2.5948e-02 -5.8868e-03 3.0416e-04 3.3158e-03 -6.0000e+00 1.0753e-02 3.0359e-03 -6.5098e-04 1.5799e-05 4.0172e-05 -6.0000e+00 8.2589e-04 -8.3554e-03 -1.9605e-05 11 8 0 10 0 0 81.47 22.73 0.17 -0.00836 -0.01325 497 106 1 5 0 99.380 26.51 20.00 22.73 21.74 29.1 1030.66 -6627 -2793 -7321 -6577 -8090 -9159 -8068 -9257 -9813 -9009 -9656 -8326 -4550 -3383 -458 -3342 -349 -596 445 -884 848 -402 1052 -268 -433 -1683 -2202 -3921 -1062 -662 1409 1329 2342 -1747 -3582 -1444 -1680 -1075 52 -1211 -1375 -1319 -994 -1083 -267 -200 -632 -443 -294 194 1139 1142 1020 1349 796 915 961 153 56 534 1255 1981 1858 1558 119 -201 580 526 1751 1408 266 117 -225 129 -63 -203 58 42 314 -162 -1071 -1328 -2197 -1666 -818 -792 -220 10 -80 67 271 533 372 1108 1009 556 528 543 -572 -906 -578 -622 122 726 -616 -1669 -965 -885 -229 344 45 -136 -59 209 439 952 1036 544 331 -346 -735 -167 218 235 680 350 488 1523 830 12 -65 -449 -68 206 12 -500 -212 168 -259 -281 154 -313 -81 -207 -95 -255 -222 -282 -314 -288 -345 -411 -402 -454 -418 -255 -225 -33 -281 -31 -58 45 -96 93 -45 121 -33 -57 -236 -314 -553 -142 -90 205 218 420 -320 -660 -260 -328 -244 14 -362 -461 -474 -371 -414 -102 -77 -246 -173 -116 79 463 505 487 686 403 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