File name: Pandora169s1_Egbert_20210601_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T024539.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210601_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210601T104349.9Z 7822.447106 171 1 49.87 2 80.40 68.40 61.20 176.10 0.00 1 0.00 1 0 25 7.418e-01 1.836e-02 2.255e-01 3.689e-03 9.300654e-01 2.171762e-03 1.035187e-02 -6.000000e+00 4.524242e-01 231.94 -2.00 3.58 -2.00 321.86 0.00e+00 6.862576e-03 1.248102e-03 1.743220e-03 -6.000000e+00 2.005809e-02 281.98 -2.00 20.00 -2.00 321.38 0.00e+00 5.717 0.004 302.00 328.00 3 1.9552e+00 8.2050e-03 7.6994e-02 -6.0000e+00 1.1345e+00 3.5819e-01 1.2098e-02 5.4413e-02 -6.0000e+00 1.2272e+00 -5.3726e-01 1.2269e-02 2.9643e-02 -6.0000e+00 7.2870e-01 2.2326e-01 5.5163e-03 1.1160e-02 -6.0000e+00 3.0267e-01 1.0771e-04 -2.2948e-03 1.0177e-04 1.7115e-04 -6.0000e+00 2.3125e-02 -2.3556e-04 -2.1522e-04 12 8 8 10 0 0 99.94 22.70 0.18 -0.00024 -0.01748 133 28 1 5 0 372.080 26.41 20.00 22.70 20.07 29.4 1007.94 -292678 900000 -166244 -209163 -182000 -90772 -199933 -319315 -300852 -180990 -264134 -111923 -178885 -96268 18370 -188799 -66778 -123357 -22717 -72013 900000 -66352 69268 -65761 4077 -112364 -13208 -82446 139398 -1487 101588 6717 62615 -47398 -32165 38525 25824 -1471 36619 14255 21839 15759 30730 -4462 29930 7893 30164 35855 41486 19812 37680 7258 19003 30147 36649 11830 23342 18288 15272 15953 12984 19579 9893 19968 13119 17168 12289 8351 10070 9993 10792 8116 -487 9531 850 2991 3118 1646 -2897 3457 -1747 1518 -2219 -1896 -364 -1779 -1426 291 -1677 498 -540 258 -269 -2034 -2216 -68 -930 -657 -1154 -1296 -1653 -2010 -1358 -255 -1398 -3644 -1657 -2393 -371 -421 -92 -425 -544 -322 -4 75 1529 370 753 232 722 1010 1512 1318 1744 -77 459 1192 2017 -42 48 -72 -66 -78 -130 -422 -27 468 126 33 47 -831 -1108 -4285 900000 -966 -1851 -1158 -326 -1549 -7732 -6635 -1502 -5156 -671 -2573 -826 72 -5839 -831 -2852 -226 -1235 900000 -1101 332 -1201 39 -3152 -161 -1864 501 -19 639 126 797 -1704 -995 682 564 -46 950 513 827 691 1230 -247 1284 410 1403 1685 2009 1242 2244 628 1636 2551 3116 1276 2299 1882 1574 1606 1393 2179 1399 2924 2125 2762 2140 1617 2146 2307 2719 2189 -141 2334 206 676 673 380 -767 1039 -630 615 -1041 -956 -192 -963 -805 165 -966 284 -294 133 -139 -1145 -1370 -49 -764 -623 -1209 -1384 -1679 -1853 -1183 -214 -1238 -3345 -1590 -2518 -430 -537 -132 -640 -848 -497 -6 110 2222 565 1197 379 1147 1526 2257 1899 2419 -105 622 1707 3141 -77 95 -150 -150 -181 -323 -1106 -73 1253 333 84 116 -1902 -2453 SS 20210601T105243.7Z 7822.453284 176 1 49.41 2 78.91 69.84 61.10 178.47 0.00 1 0.00 1 0 17 6.711e-01 9.285e-03 5.818e-02 1.301e-03 8.282594e-01 7.370988e-04 9.528208e-03 -6.000000e+00 4.097703e-01 231.94 -2.00 3.58 -2.00 321.31 0.00e+00 6.243133e-03 3.723980e-04 3.091430e-03 -6.000000e+00 1.783044e-02 281.98 -2.00 20.00 -2.00 320.77 0.00e+00 5.015 0.002 302.00 328.00 3 1.0120e+00 2.5213e-03 6.7888e-02 -6.0000e+00 1.0274e+00 1.1752e-01 3.5923e-03 4.7982e-02 -6.0000e+00 1.1106e+00 -1.5602e-01 3.7371e-03 2.8052e-02 -6.0000e+00 6.5945e-01 5.3571e-02 1.7409e-03 1.1131e-02 -6.0000e+00 2.7288e-01 5.9449e-04 -9.3943e-04 3.6056e-05 1.7215e-04 -6.0000e+00 2.0911e-02 -3.9724e-03 -9.0797e-05 11 8 0 10 0 0 9.18 22.70 0.19 -0.00397 -0.01103 330 70 1 5 0 149.690 26.41 20.00 22.70 20.54 29.5 1011.40 -245404 -163375 -203297 -216051 -219361 -208365 -209380 -244722 -212825 -191762 -199841 -147676 -144583 -122767 -84618 -115703 -73134 -80922 -66750 -61265 -45573 -49513 -23830 -60260 -54689 -54023 -42289 -51085 -22539 -32039 -10579 -9372 -1203 -18113 -11271 -1568 -3864 -7152 -4077 1120 3282 205 4462 -1114 3384 169 2343 6689 6384 5302 6244 5629 4386 8234 7747 4847 4383 3252 898 3195 3146 5595 4924 5998 3634 3459 3013 1721 3728 3583 2489 2241 355 1237 -702 -1103 -1207 -1293 -978 -55 -881 -404 -2029 -1691 -867 -1019 -108 -2 78 384 275 -271 -614 -832 -470 -184 250 745 8 -740 -721 -1195 -660 429 -946 -2086 -1105 -1015 -138 567 372 148 -103 -130 -153 461 785 672 541 72 -75 400 830 632 463 61 -40 1050 564 -287 -198 -456 -337 -33 -132 -393 -52 471 97 -80 130 -292 -257 -2024 -725 -1496 -1836 -1865 -1586 -1727 -2935 -2295 -1849 -2333 -1237 -1559 -1449 -902 -1922 -945 -1297 -1032 -961 -636 -737 -317 -1140 -1060 -1103 -790 -1055 -367 -654 -216 -236 -33 -590 -347 -49 -124 -281 -190 59 180 13 283 -78 234 13 179 522 542 504 665 637 562 1116 1134 768 718 539 149 516 529 1018 1036 1323 888 867 775 475 1124 1232 894 844 135 468 -247 -354 -370 -412 -354 -22 -424 -223 -1190 -1064 -577 -719 -79 -1 58 276 187 -176 -394 -564 -360 -156 247 796 10 -888 -818 -1235 -656 415 -969 -2291 -1210 -1201 -180 790 553 237 -169 -210 -239 693 1183 1052 888 121 -124 636 1257 969 685 88 -56 1563 906 -506 -388 -931 -703 -74 -300 -944 -127 1160 237 -188 298 -629 -560 SS 20210601T105829.0Z 7822.457280 179 1 50.02 2 77.94 70.78 61.06 180.01 0.00 1 0.00 1 0 17 5.379e-01 8.133e-03 4.248e-02 1.065e-03 7.728048e-01 5.952043e-04 8.832686e-03 -6.000000e+00 3.284550e-01 231.94 -2.00 3.58 -2.00 321.02 0.00e+00 4.964882e-03 2.783797e-04 2.338679e-03 -6.000000e+00 1.429026e-02 281.98 -2.00 20.00 -2.00 320.46 0.00e+00 4.642 0.002 302.00 328.00 3 1.0939e+00 1.9562e-03 6.2606e-02 -6.0000e+00 8.2354e-01 8.2916e-02 2.6710e-03 4.3672e-02 -6.0000e+00 8.9015e-01 -1.0305e-01 2.7045e-03 2.4614e-02 -6.0000e+00 5.2858e-01 2.9491e-02 1.2878e-03 9.3653e-03 -6.0000e+00 2.1874e-01 8.1795e-04 -7.9713e-04 2.9953e-05 1.3570e-04 -6.0000e+00 1.6759e-02 -4.0870e-03 -6.8569e-05 11 8 0 10 0 0 97.82 22.70 0.17 -0.00409 -0.01008 351 75 1 5 0 140.870 26.41 20.00 22.70 20.88 29.3 1013.06 -198297 -155424 -155710 -188556 -159116 -175646 -178337 -200841 -164090 -163342 -152017 -134431 -113881 -91289 -44018 -82124 -39839 -53614 -34750 -33433 -23192 -37937 -29269 -30457 -28401 -42782 -24994 -41733 -16151 -23045 -6806 -6643 -2017 -12206 -10194 -6933 -7677 -5862 1140 592 -1141 95 990 -236 2639 2194 1751 5067 3564 3401 3683 3617 3624 5482 4398 2773 3089 1198 389 1464 1293 3564 3861 5236 2976 2076 1915 1137 2322 2867 1910 1301 6 646 -982 -1242 -1449 -1100 -1247 -590 -954 -511 -2205 -1718 -688 -773 98 452 240 127 310 244 -216 -480 -111 5 360 697 -121 -565 -627 -1147 -341 307 -822 -1946 -996 -951 9 457 343 16 44 -44 41 486 758 528 422 -155 -206 388 842 590 549 -181 -184 1078 537 -196 -193 -575 -168 34 -126 -481 -70 419 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