File name: Pandora169s1_Egbert_20210608_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T032737.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210608_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210608T130648.4Z 7829.546393 184 1 38.72 2 55.08 91.00 43.63 113.60 0.00 1 0.00 1 0 17 1.388e-02 7.944e-03 4.321e-03 1.911e-03 2.534150e-01 1.023861e-03 3.062790e-03 -6.000000e+00 8.488671e-03 232.40 -2.00 3.58 -2.00 316.45 0.00e+00 8.034783e-04 1.192781e-04 9.407818e-05 -6.000000e+00 3.699203e-04 282.73 -2.00 20.00 -2.00 315.74 0.00e+00 1.742 0.000 302.00 328.00 3 5.5037e+00 2.6884e-03 2.1759e-02 -6.0000e+00 2.1303e-02 5.1661e-02 2.9956e-03 1.3444e-02 -6.0000e+00 2.3017e-02 -1.3240e-02 1.7269e-03 6.5048e-03 -6.0000e+00 1.3669e-02 -1.1489e-03 7.8825e-04 1.8366e-03 -6.0000e+00 5.6526e-03 2.8551e-04 1.4089e-04 6.0728e-05 2.4105e-05 -6.0000e+00 4.3257e-04 1.6977e-03 6.5671e-05 12 9 1 12 1 1 99.88 22.55 0.22 0.00170 0.00276 13 4 1 5 0 2753.180 26.32 20.01 22.55 28.93 30.2 1050.54 -1443 1334 746 -1211 -3169 -283 -512 4539 -2641 -2056 -4953 -1260 -2963 -313 2494 -6467 -110 353 -472 -418 1347 641 2075 1398 431 572 -1791 -139 714 1153 1945 3341 3215 -3151 -3391 -1595 -1762 -61 -353 -601 -1197 -371 -218 -311 258 188 -1146 -95 -594 12 1005 -114 594 1448 1761 1562 784 263 92 146 1176 2077 1042 1770 337 -322 151 -685 1474 749 346 748 99 401 -188 -598 -576 -1005 -461 -82 -1444 -1492 -2671 -2073 -793 -1058 -693 313 -14 -26 139 449 443 618 756 475 553 714 -530 -1012 -608 -855 102 205 -496 -1458 -859 -791 125 391 362 337 91 230 97 584 609 482 441 124 -206 66 360 405 975 355 558 1151 1106 118 -188 -277 49 164 199 -417 -170 159 -119 -257 -98 -667 -781 -235 229 131 -207 -511 -43 -81 747 -502 -405 -1014 -258 -671 -78 669 -2017 -34 113 -156 -142 459 221 717 504 162 221 -699 -52 253 403 699 1259 1276 -1335 -1404 -649 -761 -29 -191 -361 -771 -247 -148 -213 176 128 -778 -63 -391 8 680 -81 438 1094 1359 1224 624 209 73 116 946 1735 919 1605 307 -284 127 -574 1262 689 337 746 99 393 -177 -531 -482 -819 -383 -73 -1386 -1521 -2863 -2292 -905 -1258 -850 389 -18 -31 162 496 466 638 802 534 660 899 -692 -1321 -767 -1035 119 244 -617 -1886 -1140 -1079 175 564 535 501 133 323 130 759 787 639 607 177 -298 96 510 561 1308 464 711 1467 1455 162 -266 -398 72 244 306 -660 -274 258 -194 -415 -155 -1039 -1208 SS 20210608T135914.1Z 7829.582802 218 1 8.13 2 45.75 100.97 35.61 128.11 0.00 1 0.00 1 0 17 1.030e-02 7.386e-03 2.068e-03 1.291e-03 2.088017e-01 6.995233e-04 2.554148e-03 -6.000000e+00 6.297509e-03 232.40 -2.00 3.58 -2.00 315.37 0.00e+00 3.782950e-04 6.384275e-05 4.959231e-05 -6.000000e+00 2.745066e-04 282.73 -2.00 20.00 -2.00 314.73 0.00e+00 1.431 0.000 302.00 328.00 3 3.6782e+00 1.8151e-03 1.7897e-02 -6.0000e+00 1.5804e-02 2.5545e-02 2.0118e-03 1.1065e-02 -6.0000e+00 1.7077e-02 -9.0491e-03 1.1464e-03 5.3634e-03 -6.0000e+00 1.0141e-02 -8.3066e-04 4.9632e-04 1.4689e-03 -6.0000e+00 4.1929e-03 2.6143e-03 -2.7288e-04 4.0981e-05 2.1688e-05 -6.0000e+00 3.2103e-04 1.4043e-03 -4.0655e-06 12 9 1 12 1 1 75.26 22.56 0.19 0.00140 -0.00065 18 25 1 5 0 418.890 26.32 20.01 22.56 31.15 30.2 1063.59 228 -321 -1374 -3606 -3670 -1035 -266 1750 -107 -2069 -2937 -1191 -689 -110 1196 -584 -140 564 1022 799 1250 349 1544 1692 1597 1132 63 -708 476 1171 1727 2296 2179 -1193 -2993 -1263 -1318 -709 -122 -694 -1186 -1061 -374 -924 -419 -234 -1016 -460 -575 22 896 888 581 813 654 673 844 31 278 177 909 1853 1670 990 7 -352 -192 -43 1447 853 -155 424 132 340 26 -39 -81 -192 183 -134 -1381 -1691 -2339 -1764 -847 -723 -300 -85 -229 78 199 357 -30 853 863 301 547 413 -502 -700 -530 -953 -145 517 -751 -1249 -809 -648 -146 508 280 33 97 273 365 870 961 572 389 79 -421 74 194 304 934 543 413 1530 813 181 -21 -553 3 267 72 -471 -208 -17 -207 -203 -11 -753 -505 62 -94 -412 -1044 -969 -269 -67 475 -32 -664 -955 -389 -230 -41 463 -249 -62 243 452 363 574 162 718 817 806 589 33 -352 220 550 830 1106 1109 -637 -1567 -643 -687 -405 -78 -490 -881 -826 -296 -714 -334 -185 -789 -345 -421 17 670 702 467 680 564 569 720 27 235 150 786 1687 1571 945 7 -327 -172 -38 1299 819 -158 434 135 349 25 -37 -72 -162 158 -122 -1372 -1721 -2559 -1960 -962 -849 -370 -105 -283 96 233 394 -32 888 900 332 642 514 -641 -888 -654 -1137 -171 600 -912 -1571 -1061 -861 -196 716 399 47 134 371 471 1085 1187 736 519 109 -584 102 267 401 1199 685 517 1889 1026 237 -28 -756 4 374 104 -692 -315 -26 -313 -309 -17 -1113 -734 SS 20210608T140455.8Z 7829.586757 221 1 49.67 2 44.75 102.17 34.82 129.96 0.00 1 0.00 1 0 17 1.253e-02 7.489e-03 4.470e-03 2.070e-03 2.103353e-01 1.106729e-03 2.545405e-03 -6.000000e+00 7.664019e-03 232.40 -2.00 3.58 -2.00 316.41 0.00e+00 4.498728e-04 1.269357e-04 8.871224e-05 -6.000000e+00 3.339744e-04 282.73 -2.00 20.00 -2.00 315.69 0.00e+00 1.406 0.000 302.00 328.00 3 5.9853e+00 2.9061e-03 1.7772e-02 -6.0000e+00 1.9233e-02 5.2483e-02 3.2383e-03 1.1145e-02 -6.0000e+00 2.0781e-02 -1.9514e-03 1.8617e-03 5.3974e-03 -6.0000e+00 1.2341e-02 -6.5793e-03 8.4238e-04 1.4858e-03 -6.0000e+00 5.1036e-03 2.6185e-04 1.5755e-04 6.6453e-05 2.0147e-05 -6.0000e+00 3.9053e-04 1.5800e-03 6.8595e-05 11 8 0 10 0 0 99.99 22.57 0.03 0.00158 0.00276 80 17 1 5 0 620.760 26.32 20.01 22.57 31.55 30.3 1066.91 -857 232 201 -1824 -829 2421 -595 4370 -3259 918 -4650 572 -1298 1858 2517 -3697 -1714 101 361 -221 1077 630 1320 1641 526 52 -744 -559 1136 1728 3090 3032 3158 -2620 -2666 -917 -1364 -647 -86 -1142 -1814 -824 75 -1863 -206 -856 -1114 -792 -635 -36 750 87 181 1269 1013 575 1180 403 738 46 1153 1486 1705 1237 -60 -767 208 -883 1615 1413 902 844 181 1079 128 -877 147 -877 -432 -241 -1720 -1257 -2302 -1865 -553 -861 -159 279 34 272 23 560 222 441 395 768 498 625 -172 -465 -403 -962 -797 100 -345 -1558 -667 -624 -121 663 250 366 -363 253 142 426 497 290 223 -96 -92 328 324 239 719 -15 375 1407 874 -18 28 -536 -136 209 148 -456 -28 -3 298 -346 224 -432 -752 -155 45 39 -344 -143 390 -102 780 -675 191 -1021 123 -306 472 703 -1172 -555 33 122 -77 376 222 468 602 203 21 -294 -211 402 595 1079 1119 1222 -1080 -1065 -359 -571 -304 -46 -695 -1195 -561 52 -1316 -143 -595 -763 -529 -416 -23 501 61 133 955 783 452 935 320 581 37 926 1252 1512 1138 -56 -677 172 -722 1348 1276 872 843 183 1053 119 -767 118 -684 -343 -206 -1615 -1260 -2444 -2057 -634 -1038 -199 355 44 336 27 615 229 444 409 846 590 788 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