File name: Pandora169s1_Egbert_20210629_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T034103.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210629_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210629T112147.9Z 7850.473471 215 1 49.72 2 74.21 72.79 62.27 208.16 0.00 1 0.00 1 0 17 1.516e-01 9.315e-03 6.130e-02 3.646e-03 4.469871e-01 1.963886e-03 5.298347e-03 -6.000000e+00 9.279560e-02 232.95 -2.00 3.58 -2.00 319.70 0.00e+00 1.919507e-03 5.709801e-04 7.279163e-04 -6.000000e+00 4.072159e-03 284.74 -2.00 20.00 -2.00 318.96 0.00e+00 3.609 0.001 302.00 328.00 3 4.6329e+00 5.6583e-03 4.2756e-02 -6.0000e+00 2.3303e-01 4.3244e-02 6.6623e-03 2.4412e-02 -6.0000e+00 2.5165e-01 -3.0246e-02 5.0378e-03 1.2051e-02 -6.0000e+00 1.4954e-01 3.6029e-03 2.5730e-03 3.5276e-03 -6.0000e+00 6.1863e-02 9.0862e-05 -1.2332e-03 1.1765e-04 4.6437e-05 -6.0000e+00 4.7251e-03 2.1735e-03 -1.0255e-04 11 8 0 10 0 0 99.99 22.58 0.20 0.00217 -0.00709 39 8 1 5 0 1274.830 26.32 20.01 22.58 27.15 30.5 1022.43 -40587 6707 -22485 1675 114973 -13195 61919 -50391 -51135 -26800 -16897 -22922 -31761 -31741 10901 -6884 -18810 -20426 -10417 -11131 15932 -2884 -2702 8686 -4178 -11552 -13836 -3215 10775 4653 10513 12551 7793 -19722 -4754 5081 -1624 11620 -322 -80 1649 1889 -1535 647 193 3944 4 7253 -1806 2755 -1457 2875 731 4303 3317 -19 517 2050 -766 431 -849 2055 1855 1999 1021 258 896 -2370 902 1222 578 1316 707 1108 290 -2313 -1127 -1045 -995 -66 -598 -400 -1629 -2682 -218 -1476 -577 -97 819 -918 466 419 277 883 203 1103 668 389 -338 -864 -1 -1159 -735 -429 -512 -2003 -354 -1338 332 535 340 -21 -78 169 571 737 878 277 -359 -149 207 773 202 -174 778 381 561 1480 1131 -684 -474 -69 -417 300 29 -135 -315 249 -468 -89 12 -246 -111 -1077 134 -599 36 908 -300 794 -1800 -2014 -915 -554 -854 -1461 -1720 479 -397 -1308 -1545 -764 -858 1000 -216 -209 644 -367 -1127 -1387 -288 840 394 925 1213 861 -2907 -606 598 -219 1607 -59 -17 375 457 -398 168 51 1020 1 1847 -508 774 -455 934 260 1571 1278 -8 215 843 -320 178 -367 928 913 1051 555 137 461 -1266 501 747 383 902 487 736 182 -1373 -621 -568 -574 -43 -430 -315 -1390 -2435 -205 -1477 -600 -103 861 -953 455 385 243 774 190 1125 753 478 -439 -1128 -1 -1370 -830 -488 -612 -2532 -460 -1834 475 812 543 -34 -127 265 853 1064 1265 412 -562 -240 338 1239 317 -268 1151 547 788 2100 1702 -1112 -811 -122 -761 563 56 -274 -654 522 -988 -185 24 -479 -213 SS 20210629T113429.8Z 7850.482289 225 1 9.02 2 72.02 74.81 63.33 211.34 0.00 1 0.00 1 0 17 3.492e-02 6.629e-03 1.890e-02 2.477e-03 4.030380e-01 1.324437e-03 4.803067e-03 -6.000000e+00 2.139406e-02 232.95 -2.00 3.58 -2.00 318.65 0.00e+00 8.905116e-04 2.806764e-04 3.610299e-04 -6.000000e+00 9.384556e-04 284.74 -2.00 20.00 -2.00 317.87 0.00e+00 3.196 0.001 302.00 328.00 3 2.9953e+00 3.6439e-03 3.8021e-02 -6.0000e+00 5.3726e-02 1.7535e-02 4.1487e-03 2.1777e-02 -6.0000e+00 5.8009e-02 -2.1368e-02 2.7962e-03 1.0534e-02 -6.0000e+00 3.4473e-02 6.4776e-04 1.4336e-03 2.9052e-03 -6.0000e+00 1.4268e-02 7.3589e-04 -6.9672e-04 7.8589e-05 3.6433e-05 -6.0000e+00 1.0887e-03 1.0590e-04 -4.5177e-05 12 9 1 12 1 1 72.07 22.61 0.24 0.00011 -0.00513 16 20 1 5 0 520.600 26.32 20.00 22.61 27.43 30.5 1024.01 -11259 -12580 -12455 -9788 -1255 -10756 8459 -13757 3106 -17882 -7835 -6207 -3810 -5492 6394 -3839 796 -5967 1794 1206 4162 -1958 2315 164 1359 -2610 -838 -3679 -1133 -1162 1717 2052 1895 -4400 -4090 -1337 -3130 -1176 121 -128 -528 -192 -293 -1291 -129 957 -1043 -977 -488 323 653 1597 1356 1893 322 1231 237 615 -417 608 143 1990 2162 1789 763 149 250 -24 1121 1426 480 761 -227 522 -305 -871 -199 -703 -176 -329 -1006 -1718 -1921 -1899 -615 -461 -508 103 -96 216 416 560 -243 660 897 788 43 279 -233 -703 -361 -1034 -10 332 -490 -1672 -537 -1036 150 392 596 -5 241 213 96 570 860 701 120 -450 -449 -19 303 172 917 320 285 1091 726 -45 -154 -460 36 -8 -125 -407 11 224 -120 -387 435 -381 -313 -418 -533 -551 -409 -45 -414 308 -647 137 -1043 -431 -362 -251 -437 531 -372 80 -690 203 144 495 -251 294 23 198 -413 -131 -572 -167 -174 272 362 368 -950 -865 -276 -668 -288 35 -41 -187 -72 -115 -523 -52 385 -428 -400 -201 137 294 728 667 986 179 698 139 358 -243 349 80 1187 1408 1189 522 105 168 -16 760 1077 380 629 -190 416 -240 -627 -139 -481 -127 -255 -848 -1547 -1877 -1884 -643 -514 -571 118 -111 240 452 562 -242 648 938 878 52 356 -306 -926 -468 -1247 -11 397 -601 -2204 -708 -1451 214 577 931 -8 382 321 141 792 1235 1008 183 -701 -712 -29 456 260 1312 459 396 1529 1053 -68 -251 -758 60 -14 -221 -757 20 421 -226 -738 791 -693 -559 SS 20210629T114801.6Z 7850.491685 231 1 16.32 2 69.67 76.96 64.57 214.65 0.00 1 0.00 1 0 17 1.926e-02 6.657e-03 9.173e-03 1.696e-03 3.649703e-01 9.050396e-04 4.355807e-03 -6.000000e+00 1.180305e-02 232.95 -2.00 3.58 -2.00 318.18 0.00e+00 8.623132e-04 1.670095e-04 3.135649e-04 -6.000000e+00 5.176002e-04 284.74 -2.00 20.00 -2.00 317.39 0.00e+00 2.849 0.000 302.00 328.00 3 3.2370e+00 2.4567e-03 3.4031e-02 -6.0000e+00 2.9641e-02 2.7640e-02 2.7729e-03 1.9601e-02 -6.0000e+00 3.2001e-02 -1.6852e-02 1.7623e-03 9.4666e-03 -6.0000e+00 1.9018e-02 -9.5496e-04 8.8718e-04 2.6121e-03 -6.0000e+00 7.8729e-03 8.3316e-04 -4.3021e-04 5.3875e-05 3.2386e-05 -6.0000e+00 6.0037e-04 9.1043e-05 2.1602e-05 12 9 1 12 1 1 99.91 22.59 0.18 0.00009 -0.00314 32 22 1 5 0 489.380 26.32 20.00 22.59 27.75 30.6 1026.78 -4479 654 -3942 -7559 -305 -5889 -867 -4591 -6755 -7862 -7179 -4289 -6392 -101 -2694 -571 -2442 -93 88 492 1229 353 1417 1510 -1296 -243 -1603 -2602 324 1072 1025 2460 1562 -2837 -3982 -1492 -2534 -882 362 -857 -726 -1176 -698 -939 -318 254 -813 -37 -612 829 633 1268 1216 1217 1435 760 996 270 173 327 1303 1812 2045 1763 98 -484 271 -442 1583 1302 615 446 37 177 371 -508 -374 -628 -83 -490 -1275 -1507 -2160 -1836 -762 -552 -191 409 -5 90 115 347 -94 719 744 328 370 541 -367 -749 -683 -1036 -323 289 -726 -1604 -703 -860 -114 669 245 152 62 328 496 718 573 557 155 -277 -363 219 347 284 801 436 189 1234 792 189 -181 -440 -74 208 -44 -386 -101 131 -215 -186 135 -433 -428 -244 38 -248 -476 -17 -329 -49 -297 -496 -577 -541 -335 -581 -10 -323 -76 -356 -14 14 81 207 61 248 261 -244 -47 -316 -500 62 207 199 520 364 -716 -995 -363 -677 -270 122 -342 -302 -522 -320 -439 -149 119 -382 -17 -286 392 319 685 666 707 867 477 635 174 110 207 843 1186 1455 1276 73 -366 194 -317 1189 1038 514 391 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