File name: Pandora169s1_Egbert_20210722_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T042733.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210722_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210722T112304.7Z 7873.474360 171 1 49.36 2 76.53 74.84 124.28 265.45 0.00 1 0.00 1 0 17 2.764e-01 1.684e-02 9.374e-02 5.369e-03 5.628178e-01 2.962999e-03 6.629003e-03 -6.000000e+00 1.718737e-01 232.81 -2.00 3.58 -2.00 320.34 0.00e+00 2.001460e-03 1.077506e-03 1.877050e-03 -6.000000e+00 7.584066e-03 286.37 -2.00 20.00 -2.00 319.64 0.00e+00 4.187 0.001 302.00 328.00 3 4.7271e+00 9.0303e-03 5.1525e-02 -6.0000e+00 4.3194e-01 1.5234e-01 1.1080e-02 3.1998e-02 -6.0000e+00 4.6683e-01 -1.8607e-01 9.0418e-03 1.5703e-02 -6.0000e+00 2.7545e-01 7.2380e-02 4.5119e-03 4.3066e-03 -6.0000e+00 1.1379e-01 4.1073e-05 -3.4027e-04 1.6899e-04 6.6931e-05 -6.0000e+00 8.8393e-03 -2.8203e-03 -3.6084e-05 12 9 8 11 32 0 84.60 22.55 0.45 -0.00282 -0.00538 13 3 1 5 0 3795.850 26.32 20.00 22.55 18.94 30.6 964.28 -101160 900000 -62025 -36062 -97539 -125965 900000 900000 -82946 -121484 47002 -24047 -83130 29643 -4250 -26302 -23004 -13118 -43642 -14195 8650 -9864 26305 -12614 -52392 7087 -23797 19396 92901 12927 62840 40249 36013 -42711 3892 19408 -18016 23448 -3251 -14867 9963 8600 15564 -5189 1694 3254 4414 13704 5270 5310 9059 999 3788 11347 11266 5357 4949 -2388 2040 545 51 -882 1673 6643 6220 2251 3261 -1871 1624 -217 1894 3723 3450 2367 -2758 -2448 1789 -1568 -3024 1029 -3929 667 -1227 -3162 -1939 -2393 -1565 836 4 -70 -464 1059 560 423 -1589 1546 -818 100 -2861 -748 -564 -421 -890 -1088 -435 -1240 732 -2496 1181 372 -44 -550 206 923 -578 296 1890 211 443 -1256 738 1448 1770 40 687 -1265 768 1624 1848 -1064 431 -140 377 44 -10 -183 242 303 -82 -579 -286 -709 -632 -2359 900000 -1212 -545 -2437 -3993 900000 900000 -2291 -5077 447 -487 -3388 529 -123 -1070 -1004 -568 -2646 -689 351 -479 952 -691 -4380 360 -1610 871 2130 640 2221 1994 2061 -5269 311 1354 -1914 1975 -415 -2453 1455 1360 2406 -992 308 591 803 2333 1002 1063 1900 247 987 2951 3087 1603 1522 -784 634 171 17 -312 636 2618 2551 944 1333 -818 743 -112 1041 2092 1938 1290 -1466 -1194 792 -715 -1508 562 -2537 460 -927 -2568 -1648 -2150 -1458 782 4 -64 -405 863 442 340 -1397 1473 -884 118 -3638 -940 -679 -473 -956 -1175 -489 -1469 893 -3285 1608 548 -69 -896 333 1445 -879 435 2745 319 698 -2066 1200 2303 2740 61 1013 -1835 1078 2323 2823 -1787 761 -258 719 87 -20 -392 528 668 -180 -1253 -597 -1435 -1259 SS 20210722T114331.6Z 7873.488560 177 1 49.34 2 72.97 78.17 127.75 268.73 0.00 1 0.00 1 0 25 5.147e-02 6.582e-03 2.395e-02 1.677e-03 4.689895e-01 9.010991e-04 5.527942e-03 -6.000000e+00 3.153639e-02 232.81 -2.00 3.58 -2.00 319.36 0.00e+00 1.129497e-03 2.434537e-04 5.621016e-04 -6.000000e+00 1.392394e-03 286.37 -2.00 20.00 -2.00 318.59 0.00e+00 3.362 0.001 302.00 328.00 3 3.6473e+00 2.5551e-03 4.1575e-02 -6.0000e+00 7.9126e-02 1.7079e-02 2.9876e-03 2.5420e-02 -6.0000e+00 8.5397e-02 -1.8217e-02 2.2401e-03 1.2415e-02 -6.0000e+00 5.0809e-02 -5.3988e-03 1.1571e-03 3.4770e-03 -6.0000e+00 2.1086e-02 2.9856e-04 -6.8523e-04 5.2740e-05 4.3563e-05 -6.0000e+00 1.6041e-03 -3.6908e-03 -7.9398e-06 11 8 0 10 0 0 97.37 22.56 0.22 -0.00369 -0.00884 54 12 1 5 0 913.550 26.32 20.00 22.56 19.78 30.7 970.05 -4561 17470 -9975 -17081 -18188 -18793 10079 -2616 -20697 -28246 -1649 -7710 -15561 412 3412 -2891 261 -9445 -5455 -3902 928 -1065 1717 -3319 -6997 -5027 -2830 -3893 6733 -1095 4103 4430 4040 -8188 -2903 -1683 -5693 -1915 -2191 -2580 -645 -546 78 -1722 -1431 -1 -660 318 297 275 1411 748 1137 2392 1726 1036 1233 -480 -175 343 1024 1634 1828 2062 782 -144 1075 -201 1113 1434 245 364 281 913 208 -550 -24 -687 14 -189 -1504 -709 -2253 -1826 -872 -716 -74 429 211 535 467 537 22 522 596 611 379 622 -434 -693 -544 -1176 -477 241 -497 -1853 -757 -1104 20 492 458 -88 36 207 97 715 759 476 385 -291 -240 102 401 244 564 -10 212 1194 839 -76 -120 -592 -159 147 75 -417 -38 315 -263 -41 276 -411 -323 -80 280 -223 -403 -409 -417 178 -59 -628 -940 -47 -242 -621 17 164 -161 16 -675 -401 -297 70 -83 135 -294 -690 -511 -285 -386 589 -107 421 515 498 -1202 -400 -230 -883 -335 -463 -612 -168 -153 23 -522 -438 0 -204 98 94 91 473 276 453 1009 771 462 562 -223 -80 155 476 815 1003 1170 463 -84 625 -120 674 970 176 274 212 657 146 -354 -15 -422 9 -135 -1189 -599 -2022 -1739 -879 -739 -80 475 235 573 469 521 20 479 587 651 442 777 -567 -911 -700 -1454 -553 279 -614 -2378 -980 -1520 28 729 729 -141 57 324 147 1031 1091 711 590 -470 -380 164 619 376 829 -15 301 1712 1262 -122 -201 -1019 -285 266 140 -824 -74 632 -530 -80 531 -782 -603 SS 20210722T115037.2Z 7873.493486 181 1 49.62 2 71.72 79.33 128.96 269.90 0.00 1 0.00 1 0 25 3.903e-02 6.392e-03 1.399e-02 1.280e-03 4.396497e-01 6.851249e-04 5.203028e-03 -6.000000e+00 2.391451e-02 232.81 -2.00 3.58 -2.00 319.07 0.00e+00 9.829998e-04 1.680540e-04 3.584038e-04 -6.000000e+00 1.055809e-03 286.37 -2.00 20.00 -2.00 318.29 0.00e+00 3.147 0.001 302.00 328.00 3 3.3719e+00 1.9196e-03 3.8921e-02 -6.0000e+00 6.0002e-02 9.1791e-03 2.2168e-03 2.3759e-02 -6.0000e+00 6.4757e-02 -1.3826e-02 1.5867e-03 1.1528e-02 -6.0000e+00 3.8529e-02 -6.3875e-03 8.2070e-04 3.2091e-03 -6.0000e+00 1.5990e-02 4.9993e-04 -6.7783e-04 4.0386e-05 3.9981e-05 -6.0000e+00 1.2164e-03 -3.8118e-03 -8.7438e-07 11 1 0 11 8 0 60.39 22.56 0.29 -0.00381 -0.00891 90 19 1 5 0 551.160 26.32 20.00 22.56 20.43 30.9 973.72 -14682 7005 -10516 -9455 -14317 -8286 -2764 14477 -22546 -7385 -10746 974 -13638 2253 -2756 1527 -4890 -514 -3552 1825 -660 1599 2424 1648 -4515 -533 -2551 -2150 1663 -166 2534 1680 2331 -4190 -4301 -2279 -3768 -2438 -1103 -1704 -990 -1637 197 -1878 -241 -570 -1166 84 -430 411 1797 -27 1712 1396 1520 245 1433 -505 208 60 1225 1392 2256 1699 981 -245 752 -193 1834 1155 437 445 116 421 287 -488 -22 -574 -296 -277 -1316 -1198 -2206 -1784 -845 -732 26 421 -22 461 466 684 -93 813 606 716 340 591 -579 -555 -603 -795 -434 469 -513 -1449 -904 -994 -307 645 219 267 9 231 68 652 631 413 412 -188 -601 -30 205 162 678 190 243 1242 881 -38 -84 -547 -79 145 -39 -331 -110 309 -32 -250 212 -454 -234 -382 167 -315 -274 -409 -218 -73 361 -912 -276 -437 38 -668 113 -173 105 -396 -43 -326 167 -64 154 239 175 -507 -60 -298 -243 190 -20 300 226 346 -697 -707 -368 -672 -502 -269 -459 -296 -528 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