File name: Pandora169s1_Egbert_20210724_L2Fit_fwvt1c14d20201119p1-8.txt File generation date: 20241103T042224.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210724_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1798 Nominal wavelengths inside fitting window [nm]: 492.0247 492.1456 492.2665 492.3873 492.5082 492.6290 492.7499 492.8707 492.9914 493.1122 493.2330 493.3537 493.4744 493.5952 493.7159 493.8365 493.9572 494.0778 494.1985 494.3191 494.4397 494.5602 494.6808 494.8013 494.9219 495.0424 495.1629 495.2834 495.4038 495.5243 495.6447 495.7651 495.8855 496.0059 496.1263 496.2466 496.3669 496.4873 496.6075 496.7278 496.8481 496.9683 497.0886 497.2088 497.3290 497.4492 497.5693 497.6895 497.8096 497.9297 498.0498 498.1699 498.2900 498.4101 498.5301 498.6501 498.7701 498.8901 499.0101 499.1300 499.2500 499.3699 499.4898 499.6097 499.7295 499.8494 499.9692 500.0890 500.2088 500.3286 500.4484 500.5682 500.6879 500.8076 500.9273 501.0470 501.1667 501.2863 501.4060 501.5256 501.6452 501.7648 501.8844 502.0039 502.1235 502.2430 502.3625 502.4820 502.6015 502.7209 502.8404 502.9598 503.0792 503.1986 503.3179 503.4373 503.5566 503.6760 503.7953 503.9146 504.0338 504.1531 504.2723 504.3916 504.5108 504.6300 504.7491 504.8683 504.9874 505.1066 505.2257 505.3448 505.4638 505.5829 505.7019 505.8210 505.9400 506.0590 506.1780 506.2969 506.4159 506.5348 506.6537 506.7726 506.8915 507.0103 507.1292 507.2480 507.3668 507.4856 507.6044 507.7231 507.8419 507.9606 508.0793 508.1980 508.3167 508.4353 508.5540 508.6726 508.7912 508.9098 509.0284 509.1469 509.2655 509.3840 509.5025 509.6210 509.7395 509.8580 509.9764 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210724T100818.8Z 7875.422440 171 1 49.26 2 89.28 62.63 90.65 236.74 0.00 1 0.00 1 0 43 1.859e-02 1.836e-02 9.188e-04 9.137e-04 1.124904e+04 6.336448e+01 6.985633e+02 -6.000000e+00 1.075006e+03 286.40 -2.00 20.00 -2.00 505.45 0.00e+00 3.520807e-03 2.587608e-05 1.842357e-04 -6.000000e+00 5.309158e-04 286.40 -2.00 20.00 -2.00 501.22 0.00e+00 5.515013e-01 1.763991e-02 9.511109e-02 -6.000000e+00 3.723757e-01 232.73 -2.00 3.58 -2.00 502.69 0.00e+00 19.160 0.138 489.00 513.00 1 5.2151e+00 1.3538e-03 3.4127e-02 -6.0000e+00 2.8656e-02 -4.5104e-02 3.3454e-04 2.7506e-03 -6.0000e+00 7.3093e-03 6.7526e-04 3.7368e-03 9.4821e-05 9.4854e-05 -6.0000e+00 2.0542e-03 2.8965e-02 -1.1714e-04 12 8 8 10 0 0 95.52 22.53 13.20 0.02897 0.05489 21 4 1 4 0 2345.030 26.21 20.00 22.53 21.86 31.1 981.27 -5072 -3905 -2601 -556 920 2243 2723 2983 2492 1820 521 -234 -1157 -2047 -2160 -2102 -1309 230 1227 1644 1420 1524 1853 1705 2014 2035 1491 414 -749 -2495 -3335 -2976 -1571 -160 1432 1282 839 280 -160 -450 -64 369 1392 1864 2333 2537 2142 1333 469 -966 -2250 -3245 -3429 -3001 -1225 118 1030 1607 1905 1829 2065 2008 2530 2397 2032 1370 314 -388 -771 -1509 -2368 -1537 -1304 -679 -578 -1123 -1948 -2785 -2742 -3064 -2949 -2550 -2057 -1618 -1163 -897 -939 -813 -911 -515 421 1404 2084 2292 1823 1380 551 -641 -1992 -2876 -3472 -3046 -1485 -239 295 -77 -833 -1292 -1618 -780 -116 535 1692 2363 2907 3386 3424 3298 2610 1697 929 680 406 911 1357 1282 1169 1038 1063 688 139 -680 -1488 -1943 -1961 -1477 -807 27 765 1011 1135 982 1295 1059 1068 805 -368 -1500 -2693 -2862 -2435 -4516 -3495 -2286 -495 833 2055 2530 2792 2264 1652 473 -219 -1080 -1846 -2015 -1905 -1196 212 1145 1551 1353 1457 1775 1646 1953 1914 1407 390 -701 -2403 -3196 -2856 -1469 -153 1378 1250 821 273 -156 -439 -63 363 1375 1802 2272 2481 2099 1306 456 -934 -2226 -3183 -3349 -2951 -1176 115 1021 1606 1910 1840 2082 2039 2571 2442 2068 1389 317 -391 -772 -1508 -2377 -1535 -1313 -667 -572 -1113 -1923 -2735 -2754 -3077 -2873 -2492 -2020 -1600 -1158 -899 -945 -817 -915 -516 422 1412 2103 2308 1818 1349 528 -626 -1932 -2779 -3378 -2915 -1450 -240 296 -79 -859 -1333 -1673 -806 -120 562 1782 2497 2989 3497 3576 3479 2775 1805 981 711 422 947 1413 1346 1234 1100 1128 732 148 -721 -1575 -2058 -2087 -1589 -855 29 828 1108 1258 1069 1416 1165 1176 883 -404 -1635 -2935 -3122 -2676 SQ 20210724T101130.5Z 7875.424658 175 1 34.78 2 88.77 63.18 91.11 237.28 0.00 1 0.00 1 0 43 1.597e-02 1.574e-02 1.054e-03 1.048e-03 1.111404e+04 7.256304e+01 7.109907e+02 -6.000000e+00 9.232990e+02 286.40 -2.00 20.00 -2.00 505.45 0.00e+00 3.235043e-03 2.972592e-05 1.680198e-04 -6.000000e+00 4.561101e-04 286.40 -2.00 20.00 -2.00 501.19 0.00e+00 5.828164e-01 2.022981e-02 8.818073e-02 -6.000000e+00 3.201109e-01 232.73 -2.00 3.58 -2.00 502.67 0.00e+00 17.990 0.114 489.00 513.00 1 5.2579e+00 1.5526e-03 3.0860e-02 -6.0000e+00 2.4631e-02 -5.1476e-02 3.8382e-04 2.5635e-03 -6.0000e+00 6.2882e-03 7.6188e-04 4.7248e-03 1.0895e-04 9.4404e-05 -6.0000e+00 1.7636e-03 -3.7974e-02 2.2009e-04 12 9 9 12 1 1 35.57 22.53 11.37 -0.03797 -0.00520 14 4 1 4 0 2306.790 26.21 20.00 22.53 21.96 31.0 981.45 -4441 -3483 -2020 -626 678 1868 2196 2604 2333 1568 658 85 -1037 -1522 -1789 -1791 -1121 19 827 1158 1080 1369 1475 1358 1728 1829 1366 740 -671 -1922 -2934 -2479 -1457 -118 1064 1109 761 404 -19 -524 -204 243 1146 1560 1717 2048 1766 1277 428 -911 -1962 -2782 -3194 -2424 -1118 68 692 1461 1600 1589 1866 1834 2248 2198 1897 897 335 -210 -827 -1396 -1819 -1509 -1021 -695 -444 -777 -1523 -2454 -2411 -2450 -2637 -2228 -1894 -1471 -962 -876 -813 -722 -633 -245 224 1312 1819 1757 1834 1291 468 -350 -1392 -2602 -3157 -2781 -1433 -393 232 -36 -562 -1245 -1397 -706 -174 507 1280 1880 2503 2937 2965 2901 2231 1490 533 651 391 794 1104 1064 1129 965 721 509 29 -455 -1331 -1627 -1827 -1182 -654 107 510 908 847 1009 872 1012 843 673 -282 -1298 -2200 -2334 -2024 -3918 -3089 -1820 -557 614 1714 2048 2445 2200 1432 619 79 -968 -1415 -1663 -1674 -1023 17 776 1100 1034 1313 1421 1318 1631 1732 1297 700 -632 -1847 -2807 -2369 -1364 -112 1030 1087 748 396 -18 -514 -200 239 1136 1516 1687 2019 1745 1257 418 -885 -1882 -2721 -3113 -2366 -1071 66 688 1463 1611 1605 1887 1812 2225 2180 1879 889 330 -211 -829 -1396 -1817 -1507 -1024 -684 -439 -770 -1503 -2410 -2344 -2375 -2567 -2175 -1860 -1455 -958 -880 -819 -728 -637 -246 225 1323 1846 1784 1836 1269 451 -341 -1345 -2511 -3064 -2658 -1399 -397 234 -37 -581 -1290 -1448 -731 -181 520 1320 1946 2595 3060 3124 3086 2392 1596 568 684 409 829 1158 1123 1197 1027 770 529 30 -484 -1413 -1723 -1895 -1236 -695 115 556 975 921 1106 964 1122 937 744 -311 -1424 -2404 -2550 -2229 SQ 20210724T101620.8Z 7875.428019 180 1 49.70 2 88.00 64.01 91.80 238.09 0.00 1 0.00 1 0 29 1.380e-02 1.362e-02 9.502e-04 9.462e-04 1.007568e+04 6.497018e+01 6.257837e+02 -6.000000e+00 7.981936e+02 286.40 -2.00 20.00 -2.00 505.44 0.00e+00 3.029348e-03 2.680481e-05 1.666098e-04 -6.000000e+00 3.941598e-04 286.40 -2.00 20.00 -2.00 501.15 0.00e+00 6.530460e-01 1.834396e-02 8.583225e-02 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