File name: Pandora169s1_Egbert_20210811_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T063701.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210811_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210811T115555.8Z 7893.497173 92 1 49.54 2 73.93 84.37 106.08 65.11 0.00 1 0.00 1 0 25 4.229e-02 6.113e-03 1.306e-02 1.100e-03 4.477774e-01 5.897285e-04 5.311597e-03 -6.000000e+00 2.585502e-02 232.04 -2.00 3.58 -2.00 319.19 0.00e+00 1.562406e-03 1.512167e-04 3.860286e-04 -6.000000e+00 1.145818e-03 286.74 -2.00 20.00 -2.00 318.41 0.00e+00 3.550 0.001 302.00 328.00 3 2.7070e+00 1.6604e-03 4.2196e-02 -6.0000e+00 6.4740e-02 1.6012e-02 1.9279e-03 2.4201e-02 -6.0000e+00 6.9894e-02 -7.6520e-03 1.4107e-03 1.1831e-02 -6.0000e+00 4.1623e-02 -8.7553e-03 7.3075e-04 3.4985e-03 -6.0000e+00 1.7317e-02 6.6467e-04 -6.5965e-04 3.4724e-05 4.2873e-05 -6.0000e+00 1.3178e-03 -6.6971e-03 1.0806e-05 11 1 0 11 8 0 98.21 22.56 0.18 -0.00670 -0.01165 124 26 1 5 0 399.420 26.32 20.01 22.56 27.35 32.1 1005.23 -17069 -1545 -15771 -17744 -22192 -8189 -165 -3485 -22653 -7536 -6992 -9662 -7871 -5607 -2268 -1469 -26 -2763 -277 -148 1483 -338 2792 -672 -1009 -2600 -1447 -5842 1441 -1917 2360 1752 2553 -3403 -3749 -3090 -1897 -2530 -247 -1783 -794 -1227 -470 -1568 -49 -907 -367 -558 92 -207 1113 925 885 2155 987 685 1368 -205 25 36 615 1235 1856 1774 702 53 467 430 1232 1420 627 537 31 571 3 -421 -690 -440 -522 -344 -1290 -1258 -2177 -1538 -723 -546 -105 568 206 537 445 593 150 591 605 433 541 608 -334 -666 -587 -972 -303 255 -492 -1848 -774 -1000 -149 383 315 191 98 187 80 559 680 445 232 -171 -535 -137 344 390 690 167 147 1163 888 127 -68 -493 -109 31 -20 -378 -2 267 -112 -247 194 -402 -200 -395 -35 -438 -494 -607 -190 -4 -92 -807 -249 -242 -374 -327 -276 -129 -96 -2 -204 -21 -12 122 -29 239 -64 -103 -282 -157 -646 145 -205 267 226 363 -541 -592 -486 -320 -473 -54 -467 -218 -364 -145 -500 -15 -294 -119 -183 31 -72 409 372 365 939 458 331 671 -103 12 18 310 667 1042 1079 444 33 278 258 787 965 471 405 23 435 2 -288 -437 -273 -345 -246 -1013 -1106 -2011 -1505 -718 -577 -112 620 226 593 462 595 142 557 611 469 636 765 -438 -879 -763 -1171 -356 300 -593 -2400 -1011 -1387 -212 566 500 304 154 290 121 802 970 661 353 -274 -873 -220 531 601 1014 237 209 1669 1327 201 -113 -858 -190 55 -38 -728 -5 520 -219 -487 365 -752 -367 SS 20210811T120255.0Z 7893.502025 96 1 49.39 2 72.68 85.56 105.00 66.43 0.00 1 0.00 1 0 25 3.061e-02 6.180e-03 6.536e-03 7.108e-04 4.221042e-01 3.799274e-04 5.022570e-03 -6.000000e+00 1.871220e-02 232.04 -2.00 3.58 -2.00 318.89 0.00e+00 1.069927e-03 8.822087e-05 3.665737e-04 -6.000000e+00 8.292465e-04 286.74 -2.00 20.00 -2.00 318.10 0.00e+00 3.310 0.001 302.00 328.00 3 2.1239e+00 1.0541e-03 3.9467e-02 -6.0000e+00 4.6855e-02 1.3700e-02 1.2107e-03 2.2742e-02 -6.0000e+00 5.0584e-02 -9.0000e-03 8.4252e-04 1.1064e-02 -6.0000e+00 3.0124e-02 -7.1583e-03 4.3578e-04 3.1155e-03 -6.0000e+00 1.2533e-02 1.5394e-03 -6.6654e-04 2.2480e-05 3.7928e-05 -6.0000e+00 9.5372e-04 -6.9744e-03 9.6071e-06 10 0 0 10 0 0 70.96 22.58 0.21 -0.00697 -0.01198 262 56 1 5 0 188.490 26.32 20.01 22.58 27.83 32.2 1008.57 -8604 126 -9410 -9681 -14095 -8356 -6674 -4584 -14697 -7912 -12712 -7491 -7644 -2174 -1507 -1314 -606 -349 -263 -225 158 -310 1296 522 -7 -1351 -1743 -3092 -1205 -644 1509 1545 1770 -1840 -3791 -2671 -2439 -1826 -320 -1302 -1082 -1267 -243 -1143 127 -495 -612 -309 -410 -5 1375 835 1207 1322 1012 743 937 -251 112 307 1071 1555 2012 1650 633 -224 483 87 1484 1476 619 578 186 429 167 -322 -322 -691 -320 -357 -1239 -1308 -2035 -1736 -734 -557 -44 416 251 338 326 594 11 536 683 437 473 552 -348 -758 -735 -915 -350 465 -593 -1629 -933 -948 -219 425 254 148 2 211 222 635 767 456 290 -162 -474 -162 273 327 713 384 223 1230 889 139 6 -480 -138 21 87 -398 -139 195 -101 -124 98 -410 -325 -249 4 -329 -333 -475 -259 -215 -162 -642 -347 -613 -371 -406 -131 -107 -106 -54 -33 -27 -24 17 -34 146 63 -1 -174 -227 -428 -159 -86 216 231 292 -330 -685 -478 -472 -410 -79 -382 -355 -445 -88 -428 48 -188 -233 -118 -159 -2 543 361 561 655 528 379 488 -133 58 159 567 882 1246 1045 415 -144 313 57 964 1072 471 462 150 332 127 -224 -219 -461 -213 -269 -1015 -1199 -1938 -1756 -747 -604 -48 463 281 383 347 613 11 517 702 478 556 690 -470 -986 -947 -1142 -411 546 -745 -2101 -1260 -1298 -318 637 391 236 3 328 324 916 1097 679 440 -248 -743 -250 423 488 1057 548 308 1708 1328 218 10 -819 -234 38 159 -739 -265 378 -196 -236 185 -747 -580 SS 20210811T120825.1Z 7893.505846 99 1 49.45 2 71.70 86.50 104.14 67.47 0.00 1 0.00 1 0 25 2.415e-02 6.338e-03 4.838e-03 6.546e-04 3.993328e-01 3.492278e-04 4.771965e-03 -6.000000e+00 1.476536e-02 232.04 -2.00 3.58 -2.00 318.59 0.00e+00 9.477099e-04 7.374144e-05 3.004313e-04 -6.000000e+00 6.543322e-04 286.74 -2.00 20.00 -2.00 317.79 0.00e+00 3.143 0.001 302.00 328.00 3 2.1786e+00 9.5951e-04 3.7419e-02 -6.0000e+00 3.6972e-02 1.3082e-02 1.0949e-03 2.1491e-02 -6.0000e+00 3.9915e-02 -1.1198e-02 7.3138e-04 1.0415e-02 -6.0000e+00 2.3770e-02 -5.1828e-03 3.7466e-04 2.9014e-03 -6.0000e+00 9.8900e-03 1.7560e-03 -6.3030e-04 2.0788e-05 3.6397e-05 -6.0000e+00 7.5254e-04 -7.1068e-03 8.2567e-06 10 0 0 10 0 0 93.50 22.59 0.18 -0.00711 -0.01184 250 53 1 5 0 197.790 26.32 19.98 22.59 28.44 32.1 1011.79 -4601 -2268 -6367 -11050 -10757 -7759 -3362 -6652 -8289 -6531 -8306 -7140 -4213 -2325 -373 -410 884 -306 440 1001 1030 -232 2407 1106 143 -519 -1105 -2253 -903 -570 896 1907 1844 -1698 -3624 -2815 -2329 -1950 -406 -771 -1278 -1094 -781 -1018 -178 -85 -980 -479 -554 -269 1160 931 989 1386 824 972 969 89 -34 434 959 1584 1957 1803 522 -268 419 110 1471 1368 550 416 -22 391 -20 -253 -385 -654 -159 -413 -1263 -1417 -2142 -1775 -775 -685 6 367 250 237 424 533 134 599 757 425 500 578 -346 -774 -632 -994 -429 428 -544 -1553 -938 -854 -335 488 347 210 16 230 215 647 731 373 298 -214 -497 -94 248 348 659 415 176 1257 844 143 30 -507 -127 124 52 -413 -148 286 -83 -234 135 -423 -346 -166 -91 -278 -494 -448 -304 -133 -304 -430 -357 -482 -440 -290 -173 -32 -40 93 -35 53 126 133 -31 321 159 22 -85 -183 -366 -140 -89 150 330 351 -351 -752 -578 -515 -501 -115 -257 -479 -412 -305 -407 -71 -34 -398 -194 -226 -113 513 447 512 718 450 548 558 52 -20 248 562 991 1265 1255 377 -188 280 73 1036 1023 455 344 -18 328 -16 -191 -268 -443 -114 -316 -1055 -1322 -2085 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