File name: Pandora169s1_Egbert_20210819_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T074305.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210819_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210819T113443.4Z 7901.482447 116 1 49.29 2 79.12 82.94 138.14 279.97 0.00 1 0.00 1 0 25 3.168e-01 7.871e-03 1.171e-01 2.356e-03 6.339735e-01 1.305500e-03 7.353480e-03 -6.000000e+00 1.932929e-01 231.54 -2.00 3.58 -2.00 320.71 0.00e+00 2.481457e-03 5.565675e-04 1.297576e-03 -6.000000e+00 8.576667e-03 286.52 -2.00 20.00 -2.00 320.05 0.00e+00 5.101 0.003 302.00 328.00 3 2.3365e+00 4.1962e-03 6.0566e-02 -6.0000e+00 4.8343e-01 6.1250e-02 5.4406e-03 3.5201e-02 -6.0000e+00 5.2218e-01 -4.6127e-02 4.9787e-03 1.8067e-02 -6.0000e+00 3.1105e-01 4.4646e-03 2.4242e-03 5.6411e-03 -6.0000e+00 1.2948e-01 1.8516e-04 -9.1393e-04 7.1509e-05 7.9159e-05 -6.0000e+00 9.8714e-03 -5.9199e-03 -2.7606e-05 11 8 0 10 0 0 99.66 22.55 0.27 -0.00592 -0.01279 79 17 1 5 0 623.830 26.21 20.00 22.55 24.62 31.9 985.59 -127066 37381 -87977 -150712 -47539 -87328 -54449 -107758 -148267 -102536 -96861 -60117 -100558 -36793 -26815 -16298 -13908 -38991 -15219 -8812 -24271 -18319 17525 -9727 -20233 -15215 -24846 -24021 12713 -4579 -7836 4319 -8787 -11136 -11538 -784 -630 4249 -8580 1147 -1951 1014 -907 7 -643 3295 -2409 3960 1989 3940 2134 3861 3081 6036 3058 1476 2112 2971 352 236 956 2243 2143 2543 2230 1677 2404 -1368 2527 1083 2687 210 64 461 -526 -1881 419 -1768 -1252 -97 -555 -1518 -1612 -2272 -634 -1341 -14 400 621 296 714 657 551 -602 129 483 743 393 -44 -629 -621 -1382 -161 13 -818 -1779 -663 -1396 -109 400 475 107 -40 186 139 678 760 254 261 -263 -173 309 397 496 456 98 -194 1163 917 1 -254 -336 -406 25 -206 -279 -78 453 -30 -238 178 -149 -249 -1168 86 -772 -2279 -268 -730 -353 -1238 -2895 -1394 -1354 -728 -2079 -514 -426 -281 -269 -1082 -364 -211 -706 -516 362 -287 -665 -506 -931 -887 355 -164 -312 181 -483 -675 -706 -44 -38 292 -759 110 -219 120 -116 1 -87 439 -326 558 280 585 357 709 629 1302 726 373 547 766 92 61 255 646 651 854 794 600 848 -518 1009 497 1336 106 32 235 -250 -823 168 -731 -568 -51 -319 -1003 -1174 -1689 -496 -1124 -12 357 553 256 579 501 430 -460 108 461 771 463 -53 -778 -729 -1577 -168 13 -906 -2112 -783 -1780 -149 578 750 171 -64 290 217 1012 1134 395 428 -430 -282 512 635 763 676 140 -286 1674 1459 2 -478 -645 -823 52 -451 -618 -176 1040 -70 -532 393 -313 -509 SS 20210819T114029.0Z 7901.486447 119 1 49.42 2 78.09 83.92 139.10 281.14 0.00 1 0.00 1 0 25 2.447e-01 6.682e-03 1.118e-01 2.244e-03 5.920339e-01 1.231858e-03 6.841240e-03 -6.000000e+00 1.493154e-01 231.54 -2.00 3.58 -2.00 320.48 0.00e+00 1.942679e-03 4.861699e-04 8.042985e-04 -6.000000e+00 6.624171e-03 286.52 -2.00 20.00 -2.00 319.80 0.00e+00 4.696 0.002 302.00 328.00 3 2.6642e+00 3.8374e-03 5.5858e-02 -6.0000e+00 3.7344e-01 4.4012e-02 4.8598e-03 3.2380e-02 -6.0000e+00 4.0336e-01 -1.0268e-02 4.3389e-03 1.6388e-02 -6.0000e+00 2.4028e-01 -1.1815e-02 2.1456e-03 5.1161e-03 -6.0000e+00 1.0003e-01 2.0141e-04 -7.1778e-04 6.9025e-05 6.7670e-05 -6.0000e+00 7.6245e-03 -6.2416e-03 -7.8059e-06 11 8 0 10 0 0 99.86 22.55 0.21 -0.00624 -0.01164 82 18 1 5 0 602.580 26.32 20.01 22.55 24.77 31.9 986.76 -58989 156730 -110226 -48910 -80564 -29565 -14360 -42968 -119076 -17345 -65891 -26790 -78991 -27492 -26251 5251 -9932 -16426 -16821 3750 2486 -968 -8462 -1202 -11269 -17652 -13177 -13468 10428 -2888 -45 10984 2113 -12057 -6091 -4640 2972 -4262 3324 -3852 1367 -967 2550 -1872 1512 1199 230 1902 2288 3144 2927 892 3346 3808 3655 -688 2913 562 -896 -1894 753 1011 1823 1232 2135 -212 1393 -1722 1798 375 1227 474 -581 475 -1284 -1047 13 -1246 -1233 460 -1020 -688 -1809 -1623 -514 -440 -409 1090 205 845 238 728 376 1004 58 742 591 580 -508 -399 -345 -878 -843 172 -675 -1520 -640 -1103 99 122 371 374 -87 34 71 628 752 319 10 -150 -218 70 505 324 318 -63 -21 1135 784 -354 -259 -507 -175 -85 35 -311 -74 378 0 -85 214 -215 -149 -437 343 -1619 -420 -909 -216 -97 -405 -2531 -158 -1054 -329 -1864 -490 -574 100 -251 -460 -515 107 75 -29 -285 -41 -460 -816 -596 -605 370 -125 -2 559 126 -889 -424 -322 210 -360 317 -469 179 -141 379 -284 226 184 36 305 382 555 570 197 793 974 997 -194 818 162 -259 -550 220 321 643 482 870 -88 561 -735 809 183 656 268 -332 257 -653 -509 6 -568 -615 248 -648 -470 -1373 -1317 -420 -383 -375 1013 192 762 203 607 302 817 50 720 630 696 -637 -504 -414 -1013 -908 183 -765 -1842 -780 -1441 133 181 575 610 -143 54 111 939 1122 497 16 -247 -360 112 781 504 475 -91 -31 1631 1240 -604 -464 -968 -338 -175 73 -687 -163 839 1 -189 453 -450 -306 SS 20210819T114519.5Z 7901.489809 122 1 49.41 2 77.23 84.74 139.90 282.15 0.00 1 0.00 1 0 25 1.524e-01 5.952e-03 3.818e-02 1.402e-03 5.604485e-01 7.630883e-04 6.536150e-03 -6.000000e+00 9.300457e-02 231.54 -2.00 3.58 -2.00 320.23 0.00e+00 2.183677e-03 2.765766e-04 8.485318e-04 -6.000000e+00 4.125570e-03 286.52 -2.00 20.00 -2.00 319.53 0.00e+00 4.402 0.002 302.00 328.00 3 2.0974e+00 2.3117e-03 5.2510e-02 -6.0000e+00 2.3261e-01 2.4136e-02 2.8641e-03 3.0535e-02 -6.0000e+00 2.5123e-01 2.7867e-05 2.4684e-03 1.5413e-02 -6.0000e+00 1.4966e-01 -1.3794e-02 1.2399e-03 4.8491e-03 -6.0000e+00 6.2311e-02 4.8456e-04 -6.5375e-04 4.3413e-05 6.3891e-05 -6.0000e+00 4.7485e-03 -6.5849e-03 7.2572e-06 10 0 0 10 0 0 99.44 22.56 0.22 -0.00658 -0.01150 182 39 1 5 0 271.440 26.32 20.00 22.56 24.99 31.9 988.19 -49520 -23951 -45563 -76535 -40268 -56505 -1134 -46748 -66408 -48401 -45348 -42089 -33934 -26602 -7390 -18146 -1419 -13384 -9588 1557 -6293 574 -1438 2072 -5124 -3859 -10808 -10975 -2048 -2842 -2105 3223 -575 -2300 -7544 -3180 -3327 -671 -1067 1106 -2414 -224 -1288 318 -382 2099 -1992 2029 -956 2264 427 1820 1927 2865 1402 1013 807 -26 -522 -696 808 2078 1907 1787 1104 217 822 -258 1740 1373 1004 162 243 56 -155 -853 -571 -954 -115 -687 -490 -1188 -1767 -1885 -489 -903 230 595 403 173 531 605 242 487 767 145 771 635 54 -626 -482 -1083 -415 262 -511 -1726 -833 -1110 -166 538 322 197 -1 91 158 593 644 370 256 -247 -451 27 347 516 615 200 -213 1023 567 -49 -353 -458 -274 153 -56 -353 -170 290 -40 -41 198 -173 -123 -474 -208 -532 -1116 -425 -695 -9 -633 -1135 -824 -739 -748 -677 -618 -175 -569 -43 -463 -347 54 -244 21 -57 85 -246 -194 -593 -597 -102 -151 -126 199 -42 -183 -632 -258 -295 -68 -124 149 -381 -37 -230 58 -71 389 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