File name: Pandora169s1_Egbert_20210914_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T084554.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210914_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210914T155031.1Z 7927.660082 218 1 49.51 2 45.07 149.62 130.28 89.04 0.00 1 0.00 1 0 17 1.405e-02 7.279e-03 4.534e-03 2.049e-03 1.886720e-01 1.082203e-03 2.313563e-03 -6.000000e+00 8.510884e-03 229.09 -2.00 3.58 -2.00 316.54 0.00e+00 4.185478e-05 1.294575e-04 6.644034e-05 -6.000000e+00 3.768679e-04 284.27 -2.00 20.00 -2.00 315.80 0.00e+00 1.414 0.000 302.00 328.00 3 5.6797e+00 2.8279e-03 1.6982e-02 -6.0000e+00 2.1176e-02 1.0662e-02 3.1602e-03 9.9197e-03 -6.0000e+00 2.2908e-02 2.0690e-02 1.8244e-03 4.8479e-03 -6.0000e+00 1.3657e-02 -1.5792e-02 8.3607e-04 1.3440e-03 -6.0000e+00 5.7134e-03 3.7410e-04 6.8869e-04 6.6265e-05 1.8661e-05 -6.0000e+00 4.3707e-04 -1.4521e-02 2.0965e-04 11 8 0 10 0 0 100.00 22.59 0.10 -0.01452 -0.00935 263 56 1 5 0 188.210 26.32 20.01 22.59 25.34 32.6 987.30 2704 -103 -1839 -4860 -2205 595 8656 1921 508 -3592 -263 -2663 1597 -756 2678 -1281 -1155 -1531 677 225 1043 73 2755 -166 1687 -786 441 -1293 2363 332 3035 2276 2580 -1919 -2804 -670 -1345 -607 -70 -685 -1718 -850 -1278 -929 -1006 -436 -1351 -348 -1058 -117 554 896 463 1563 495 927 707 763 -478 767 739 1931 1102 1391 -32 -546 -255 -393 914 1663 176 331 30 427 510 107 84 -161 -15 -154 -1203 -1343 -1859 -1830 -392 -928 18 149 12 230 725 130 454 474 1157 606 958 495 -432 -816 -380 -1075 -200 38 -269 -1889 -385 -1225 -233 292 533 127 216 0 77 282 455 251 375 -152 -364 -69 135 268 955 328 389 1062 1123 70 -116 -278 -404 495 162 19 -215 607 -330 -209 -136 -311 -692 465 -19 -360 -936 -384 97 1344 343 100 -767 -55 -578 356 -189 717 -382 -359 -490 218 75 351 25 930 -60 621 -304 168 -480 804 111 1013 804 954 -751 -1075 -249 -531 -269 -36 -398 -1094 -562 -869 -636 -688 -295 -905 -225 -674 -74 356 602 327 1134 372 706 547 590 -370 588 580 1577 959 1256 -29 -475 -207 -310 738 1447 167 326 30 415 470 92 66 -121 -11 -127 -1087 -1311 -1928 -1985 -443 -1111 22 190 15 287 855 143 464 468 1162 653 1111 619 -567 -1072 -479 -1287 -230 44 -332 -2475 -518 -1718 -335 437 819 198 326 0 103 361 574 327 511 -219 -540 -102 196 378 1289 427 489 1320 1441 94 -162 -398 -589 737 251 30 -356 1017 -560 -350 -224 -500 -1103 SS 20210914T160214.9Z 7927.668228 227 1 9.02 2 44.08 153.55 128.29 91.01 0.00 1 0.00 1 0 17 9.860e-03 7.438e-03 9.056e-04 6.004e-04 1.830813e-01 3.215712e-04 2.276333e-03 -6.000000e+00 5.971475e-03 229.09 -2.00 3.58 -2.00 315.09 0.00e+00 3.281767e-04 2.848590e-05 3.670779e-05 -6.000000e+00 2.644664e-04 284.27 -2.00 20.00 -2.00 314.46 0.00e+00 1.390 0.000 302.00 328.00 3 2.4106e+00 8.2667e-04 1.6618e-02 -6.0000e+00 1.4858e-02 2.1885e-03 9.1689e-04 9.6386e-03 -6.0000e+00 1.6075e-02 -2.4546e-03 5.2325e-04 4.7134e-03 -6.0000e+00 9.5830e-03 -3.5653e-03 2.2739e-04 1.3132e-03 -6.0000e+00 4.0076e-03 1.0286e-02 1.5329e-04 1.8992e-05 2.0109e-05 -6.0000e+00 3.0683e-04 -1.3686e-02 1.4113e-04 12 9 1 12 1 1 99.93 22.61 0.22 -0.01369 -0.01253 100 120 1 5 0 87.640 26.32 20.00 22.61 25.89 32.6 989.49 985 -468 -970 -2879 -3331 -1611 -138 1035 401 -1067 -2621 -1324 -261 -110 518 39 -721 654 973 1305 892 523 1229 1542 1237 1270 120 -761 224 1002 1861 2140 1795 -560 -3230 -1645 -1798 -1039 -27 -633 -1309 -1062 -630 -768 -528 -182 -810 -607 -643 -185 974 783 871 1027 587 728 1036 135 170 396 928 1398 1655 1167 150 -764 -123 -142 1357 1260 120 142 -7 286 174 -110 -6 -167 129 -230 -1292 -1581 -2414 -1854 -938 -900 -284 -11 -92 37 156 282 -9 857 898 556 499 543 -264 -708 -540 -889 -312 476 -316 -1499 -855 -773 -355 527 364 319 67 228 245 679 840 439 442 6 -457 -139 251 329 894 756 420 1248 1007 257 76 -364 -150 202 140 -373 -304 111 -219 -403 -30 -575 -581 306 -149 -314 -902 -1022 -457 -40 320 137 -361 -902 -455 -95 -44 217 18 -344 316 482 622 434 256 602 780 655 691 66 -399 115 494 924 1116 931 -303 -1731 -850 -988 -613 -17 -453 -985 -838 -508 -626 -428 -146 -638 -486 -499 -142 760 613 718 881 496 626 899 118 147 341 816 1295 1563 1159 150 -722 -112 -124 1211 1183 119 148 -7 292 174 -105 -6 -142 112 -207 -1249 -1608 -2542 -2048 -1051 -1078 -345 -13 -116 45 184 316 -10 868 932 601 570 652 -337 -904 -655 -1048 -364 563 -386 -1896 -1086 -1024 -473 731 508 449 94 309 318 856 1040 544 582 8 -624 -189 346 435 1160 934 516 1509 1270 332 100 -490 -204 275 200 -543 -458 165 -329 -597 -45 -832 -829 SS 20210914T161411.8Z 7927.676526 236 1 4.24 2 43.20 157.68 126.26 92.97 0.00 1 0.00 1 0 17 1.152e-02 8.418e-03 5.442e-03 3.573e-03 1.790344e-01 1.918127e-03 2.227307e-03 -6.000000e+00 6.974412e-03 229.09 -2.00 3.58 -2.00 315.12 0.00e+00 4.208227e-04 1.702444e-04 2.285272e-05 -6.000000e+00 3.089165e-04 284.27 -2.00 20.00 -2.00 314.49 0.00e+00 1.370 0.000 302.00 328.00 3 4.8920e+00 4.9301e-03 1.6342e-02 -6.0000e+00 1.7353e-02 1.9484e-02 5.4678e-03 9.4481e-03 -6.0000e+00 1.8776e-02 7.2103e-04 3.1249e-03 4.6162e-03 -6.0000e+00 1.1193e-02 -4.9923e-03 1.3582e-03 1.3113e-03 -6.0000e+00 4.6798e-03 8.7669e-04 2.0524e-05 1.1335e-04 1.9675e-05 -6.0000e+00 3.5848e-04 -1.3081e-02 1.0562e-04 12 9 1 12 9 1 99.89 22.59 0.11 -0.01308 -0.01293 3 10 1 5 0 1017.440 26.32 20.00 22.59 26.24 32.6 991.61 2795 -1667 -249 -1685 -2299 -3828 340 610 971 -2024 -3033 -2042 -409 -66 750 257 -773 291 1645 1167 1074 1414 1614 1770 1632 260 -397 116 719 842 2096 1626 2337 -1161 -3885 -1396 -2949 -605 -502 -328 -1661 134 -734 -529 -559 -409 -1646 -441 -607 -1208 347 400 -124 1723 924 1285 664 -479 604 446 1359 1714 1362 1617 564 -578 -187 -826 1395 1514 -306 476 262 367 1022 -525 91 -463 -135 -522 -1306 -991 -2525 -2360 -659 -1292 -337 241 221 -334 238 145 73 209 937 1389 662 811 103 -493 -149 -1052 -229 968 -702 -1504 -925 -851 -312 266 536 -181 250 -122 293 625 191 -180 71 194 -548 109 267 657 1211 -81 296 1653 665 660 155 119 -30 280 5 -369 -149 -88 2 -414 -94 -490 -742 816 -536 -80 -528 -673 -1084 95 183 311 -690 -1046 -706 -147 -26 314 114 -358 136 780 566 529 696 800 899 855 140 -214 61 356 406 1013 819 1215 -626 -2084 -727 -1621 -359 -332 -238 -1286 106 -593 -430 -454 -330 -1321 -344 -467 -927 269 320 -103 1449 796 1115 584 -424 528 390 1202 1569 1300 1584 554 -551 -169 -734 1253 1440 -310 493 273 377 1010 -495 81 -397 -116 -475 -1271 -1016 -2717 -2620 -751 -1537 -412 299 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