File name: Pandora169s1_Egbert_20211031_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T104348.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211031_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211031T152208.8Z 7974.640380 317 1 1.38 2 62.87 152.44 39.73 222.36 0.00 1 0.00 1 0 17 1.437e-02 7.829e-03 1.071e-02 4.498e-03 2.763343e-01 2.350908e-03 3.430940e-03 -6.000000e+00 8.533354e-03 223.82 -2.00 3.58 -2.00 316.56 0.00e+00 3.557214e-04 2.845195e-04 8.650893e-05 -6.000000e+00 3.761221e-04 278.33 -2.00 20.00 -2.00 315.94 0.00e+00 2.181 0.000 302.00 328.00 3 2.8973e+00 6.0794e-03 2.5423e-02 -6.0000e+00 2.1017e-02 3.3233e-02 6.8123e-03 1.4224e-02 -6.0000e+00 2.2847e-02 -1.1448e-02 3.9758e-03 7.0742e-03 -6.0000e+00 1.3627e-02 4.1577e-04 1.8670e-03 2.0227e-03 -6.0000e+00 5.7272e-03 2.5225e-03 -7.3489e-04 1.4252e-04 2.7946e-05 -6.0000e+00 4.4653e-04 6.5002e-03 1.0395e-05 12 9 1 12 1 1 999.00 22.58 0.22 0.00650 0.00098 2 26 1 5 0 400.260 26.32 20.00 22.58 15.42 33.5 949.01 2617 461 -917 -5098 -2292 215 -2727 4642 -4314 -532 -2130 -1579 -4527 -2631 574 1998 -665 -694 801 1120 425 1762 18 1899 1950 3428 -1853 48 -3093 -573 2177 1882 1069 -2019 -3268 -2950 -3762 270 442 53 -2448 -618 -354 701 -807 -326 -364 -178 370 -459 1204 1045 750 2296 1861 1077 1083 303 92 -486 726 901 1821 1357 994 -1970 490 -595 759 1301 331 -543 749 502 469 -583 -31 -1623 157 -879 -1349 -1408 -1832 -1513 -732 -822 -467 174 114 214 430 -259 235 323 1316 660 39 -140 117 -890 -266 -535 130 -217 -447 -1266 -918 -772 69 981 -85 550 -393 408 308 -246 789 275 238 471 -707 355 -59 336 873 932 -36 1339 490 321 -46 -467 398 290 122 -559 -133 88 -79 -145 -36 -799 -452 367 73 -152 -847 -340 31 -413 718 -777 -98 -406 -309 -968 -631 147 557 -196 -213 253 364 137 583 6 646 699 1256 -694 18 -1101 -201 749 700 418 -840 -1343 -1189 -1626 125 228 30 -1538 -394 -233 462 -541 -217 -239 -114 239 -301 789 713 532 1688 1392 832 851 240 72 -380 575 740 1563 1214 883 -1754 407 -499 642 1182 318 -542 743 484 442 -517 -26 -1348 129 -784 -1269 -1433 -1937 -1654 -829 -957 -563 212 139 258 503 -291 248 335 1403 743 46 -176 151 -1162 -341 -649 155 -257 -552 -1615 -1205 -1043 96 1410 -125 824 -580 582 421 -323 1030 366 331 669 -1028 516 -84 467 1191 1232 -46 1717 654 443 -66 -687 585 436 190 -895 -215 145 -129 -238 -58 -1266 -710 SS 20211031T154042.4Z 7974.653268 326 1 31.34 2 61.46 157.27 42.10 228.11 0.00 1 0.00 1 0 17 1.279e-02 7.450e-03 3.798e-03 1.590e-03 2.635439e-01 8.305789e-04 3.261999e-03 -6.000000e+00 7.600417e-03 223.82 -2.00 3.58 -2.00 316.56 0.00e+00 6.589703e-04 1.005137e-04 8.077764e-05 -6.000000e+00 3.349187e-04 278.33 -2.00 20.00 -2.00 315.94 0.00e+00 2.083 0.000 302.00 328.00 3 4.4664e+00 2.1483e-03 2.4262e-02 -6.0000e+00 1.8720e-02 4.4420e-02 2.4074e-03 1.3562e-02 -6.0000e+00 2.0346e-02 -6.8601e-03 1.4062e-03 6.7387e-03 -6.0000e+00 1.2136e-02 -3.8563e-03 6.6059e-04 1.9736e-03 -6.0000e+00 5.1030e-03 5.8422e-04 2.0636e-04 5.0582e-05 2.6502e-05 -6.0000e+00 3.9740e-04 6.0790e-03 1.4474e-04 12 9 1 12 1 1 99.94 22.58 0.24 0.00608 0.00763 18 6 1 5 0 1640.130 26.32 20.00 22.58 17.19 33.4 958.19 1158 1553 -2597 -2893 -4429 -3160 -955 625 -1708 -1557 -4904 -3586 -2603 568 456 861 -1101 677 760 758 685 1971 861 2428 -248 1127 -789 46 496 1205 862 2595 2050 -883 -4603 -1725 -3088 -356 301 -156 -789 -841 -441 -1035 -1005 166 -1017 -342 -262 -809 973 869 900 1330 632 846 969 327 201 27 927 1337 1642 1576 627 -758 369 -448 1148 1498 496 265 494 459 591 -766 94 -585 103 -180 -1364 -1445 -2199 -2117 -1046 -1071 -403 -241 -225 -202 393 456 186 485 761 702 382 605 -217 -551 -515 -845 -629 767 -342 -1006 -912 -1076 -312 543 269 237 299 267 49 671 649 340 507 141 -540 -20 286 207 795 641 323 1441 1135 62 91 -602 -252 -74 376 -457 -95 226 -254 -339 57 -516 -513 168 248 -426 -477 -681 -455 -138 98 -301 -290 -921 -685 -541 130 114 237 -329 207 241 239 221 654 282 816 -90 418 -298 16 168 412 307 940 800 -366 -1855 -690 -1282 -165 153 -89 -485 -547 -295 -684 -665 111 -682 -223 -168 -524 644 594 653 978 485 663 769 261 159 21 741 1097 1407 1391 563 -675 312 -372 980 1366 472 258 485 448 555 -683 77 -476 85 -156 -1299 -1478 -2313 -2354 -1193 -1272 -490 -296 -277 -246 457 512 198 497 806 790 454 753 -282 -719 -653 -1024 -740 900 -421 -1294 -1202 -1456 -431 773 395 354 443 381 66 887 846 449 693 200 -795 -29 405 289 1077 847 421 1849 1499 86 131 -878 -375 -112 582 -734 -155 372 -423 -556 92 -806 -803 SS 20211031T155013.4Z 7974.659878 329 1 6.90 2 60.84 159.80 43.40 230.87 0.00 1 0.00 1 0 17 1.481e-02 8.008e-03 1.090e-02 4.638e-03 2.585201e-01 2.418626e-03 3.180088e-03 -6.000000e+00 8.793740e-03 223.82 -2.00 3.58 -2.00 316.53 0.00e+00 4.460535e-04 2.905399e-04 1.036189e-04 -6.000000e+00 3.876202e-04 278.33 -2.00 20.00 -2.00 315.91 0.00e+00 2.043 0.000 302.00 328.00 3 4.7652e+00 6.2505e-03 2.3762e-02 -6.0000e+00 2.1658e-02 3.9461e-02 7.0054e-03 1.3228e-02 -6.0000e+00 2.3546e-02 -8.2913e-03 4.0871e-03 6.5724e-03 -6.0000e+00 1.4044e-02 -3.5787e-03 1.9154e-03 1.8859e-03 -6.0000e+00 5.9012e-03 4.5580e-04 -3.6795e-04 1.4731e-04 2.5674e-05 -6.0000e+00 4.6026e-04 6.8941e-03 -1.2495e-05 12 9 1 12 1 1 999.00 22.58 0.14 0.00689 0.00413 2 5 1 5 0 2240.310 26.32 20.00 22.58 17.45 33.3 959.44 3699 -625 -2067 -5827 -3462 1737 -1603 4245 -965 -1491 -4074 -2513 -4416 -415 897 -2034 -902 611 4100 805 -1044 738 2749 1259 285 -947 -116 952 -85 -2019 1680 4131 1172 -1536 -3075 -1146 -3754 1081 -660 -234 281 -313 -508 -1405 -1599 -651 -1783 -440 752 -692 374 1323 1000 1573 1525 1880 956 -100 -232 646 1634 2129 2069 959 -93 -777 211 -803 1161 1831 -292 562 426 412 1027 -652 -147 -1501 -369 -619 -1003 -1198 -2128 -1784 -1180 -1430 -137 -392 -703 153 815 -11 167 835 252 343 476 309 -47 -811 -314 -275 -614 246 -437 -769 -402 -1063 -60 184 966 168 -61 -181 121 943 344 96 428 152 113 77 12 734 822 273 343 1138 1368 -391 -206 -431 -452 290 208 -160 -171 -165 323 -15 -78 -477 -957 538 -103 -353 -994 -538 247 -241 662 -172 -280 -796 -499 -964 -98 233 -587 -271 188 1265 262 -351 246 914 440 104 -360 -44 345 -30 -708 589 1507 462 -632 -1255 -456 -1601 494 -346 -136 175 -204 -338 -950 -1084 -438 -1197 -289 485 -452 249 915 722 1169 1162 1451 752 -79 -183 504 1289 1745 1781 862 -85 -686 178 -668 984 1647 -282 556 423 402 960 -581 -123 -1225 -304 -545 -950 -1207 -2255 -1954 -1339 -1689 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