File name: Pandora169s1_Egbert_20211101_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T104333.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211101_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211101T123040.2Z 7975.521299 181 1 49.79 2 85.19 115.77 44.93 139.24 0.00 1 0.00 1 0 17 6.607e-01 5.053e-02 2.832e-01 2.179e-02 9.782656e-01 1.282863e-02 1.144223e-02 -6.000000e+00 3.969950e-01 223.74 -2.00 3.58 -2.00 321.98 0.00e+00 -1.399496e-02 4.728006e-03 1.110070e-03 -6.000000e+00 1.756564e-02 278.22 -2.00 20.00 -2.00 321.41 0.00e+00 10.119 0.020 302.00 328.00 3 9.9987e-02 4.1434e-02 1.1134e-01 -6.0000e+00 9.8049e-01 1.9270e+00 4.9344e-02 5.3328e-02 -6.0000e+00 1.0684e+00 -2.1850e+00 3.2113e-02 2.6499e-02 -6.0000e+00 6.3385e-01 8.0218e-01 1.7030e-02 1.3601e-02 -6.0000e+00 2.6532e-01 9.5871e-06 -1.7946e-03 6.1519e-04 2.4345e-04 -6.0000e+00 2.1108e-02 1.3193e-02 -1.1055e-04 12 8 8 10 0 0 17.23 22.65 0.77 0.01319 -0.00029 26 6 1 5 0 1914.480 26.41 19.97 22.65 9.98 32.7 917.65 41721 900000 3268 409212 105544 127496 97757 900000 -1366 116459 -5914 -6339 -65377 65465 900000 900000 81562 47595 58758 5334 209990 258304 49262 58054 21996 -2388 -8095 -548 900000 -82387 66208 81521 26481 -48414 -59903 75776 -13439 260543 14571 46620 101432 82359 124651 4305 25438 26755 22762 129897 13309 -28457 31101 11549 103682 62568 900000 57 68329 77032 80672 -24761 -18108 22710 4966 56644 40823 -6916 8662 -18901 2897 6549 53206 53682 2073 33771 45090 -34106 -3462 -21980 -10087 31648 1265 35757 1469 -6598 6176 -8458 800 2781 -15795 9699 120 24588 35932 11422 -9190 19240 3973 -7665 -5568 903 2307 -1836 -7244 -6489 -2911 -577 6407 -9731 8762 -5402 -3812 -3614 244 -2016 2042 5107 2856 -1591 169 -3618 8395 82 -911 -3341 6092 -191 1515 3465 8350 -2975 -112 -87 -757 -2634 1845 -321 1745 7 577 -471 -2296 1240 -854 3911 900000 399 8684 3173 2952 3018 900000 -116 3370 -533 -594 -11100 3589 900000 900000 4878 3619 3845 557 4456 5482 3041 3472 1828 -253 -845 -51 900000 -13696 2938 3460 2095 -7449 -9641 3216 -1426 5529 1546 4137 5675 5720 5531 598 2650 2581 2196 4260 1438 -4529 3240 1604 6201 6036 900000 10 6855 6836 6381 -4729 -3389 2936 843 6338 5671 -1431 1688 -4680 635 1552 9341 9632 554 6581 6959 -9409 -715 -5598 -2569 6289 369 9313 551 -2882 2512 -4173 372 1284 -8631 3928 50 7697 10953 4383 -4973 9255 2621 -6044 -4727 734 1759 -1432 -5419 -4682 -2111 -434 4793 -8626 7295 -5997 -4774 -4980 339 -2887 2754 6553 3781 -2289 250 -5676 11457 115 -1247 -4543 7340 -240 1863 4469 11805 -5493 -229 -196 -1731 -6649 4788 -899 4908 20 1633 -1288 -5937 2868 -2089 SS 20211101T124224.9Z 7975.529455 184 1 49.34 2 83.32 117.92 43.68 142.91 0.00 1 0.00 1 0 17 6.269e-01 1.770e-02 2.200e-01 4.889e-03 8.633258e-01 2.805357e-03 9.636203e-03 -6.000000e+00 3.741528e-01 223.74 -2.00 3.58 -2.00 321.95 0.00e+00 8.863205e-03 1.607639e-03 1.274872e-03 -6.000000e+00 1.695185e-02 278.22 -2.00 20.00 -2.00 321.49 0.00e+00 7.832 0.009 302.00 328.00 3 3.9325e-01 1.0562e-02 9.0120e-02 -6.0000e+00 9.1977e-01 4.9430e-01 1.5359e-02 5.2015e-02 -6.0000e+00 1.0006e+00 -6.7312e-01 1.5652e-02 2.7744e-02 -6.0000e+00 5.9501e-01 2.7573e-01 7.1215e-03 1.2349e-02 -6.0000e+00 2.4946e-01 8.4027e-05 -1.8504e-03 1.4163e-04 1.8415e-04 -6.0000e+00 1.9664e-02 1.1264e-02 -4.1244e-05 12 9 8 11 8 0 22.59 22.60 0.26 0.01126 -0.00264 98 21 1 5 0 503.350 26.32 20.01 22.60 10.40 32.7 920.30 -212043 142532 -238950 -145829 900000 900000 -181854 -114714 -261062 -140765 -253667 -192794 -223943 -97359 19479 -41025 -53064 -88848 -76943 -87448 16615 -13365 -55238 -11554 -72777 -73353 -42833 -84808 78934 -57410 27326 22800 -3912 -23156 -31857 75863 -20705 13877 -532 23763 39651 59719 21197 -1077 25405 37621 16440 49552 13296 21975 26210 19258 29345 34317 37998 9975 13283 25137 9242 6101 4804 8291 16190 13764 18158 13019 14269 1132 11459 4579 12931 12735 6134 6779 8469 -1437 2093 -3443 145 2814 1418 3894 -81 -2873 -18 -1861 -672 228 -2607 -724 -86 1501 1199 -735 -2965 114 -1107 -1682 -1513 -1538 -1069 -1983 -2370 -846 -653 -3510 -1402 -2436 -674 -881 -407 -378 -908 -846 166 581 743 434 231 215 496 1246 1560 1202 1477 719 768 1884 1133 63 173 224 -229 61 38 -250 290 293 42 -20 -238 -693 -1196 -2664 679 -4650 -1200 900000 900000 -1891 -646 -6221 -1159 -6347 -3341 -6314 -1139 102 -444 -759 -2040 -1700 -2235 151 -162 -1029 -145 -1766 -1843 -798 -2388 489 -1418 355 385 -102 -793 -1088 1048 -727 397 -19 865 1391 1863 943 -62 1150 1554 875 2007 834 1388 1780 1461 2238 2717 3092 1119 1471 2451 1027 687 564 1033 2143 1982 2732 2127 2351 225 2270 1104 3160 3264 1662 1717 1920 -325 433 -782 36 825 470 1464 -35 -1394 -9 -947 -354 123 -1440 -406 -45 742 588 -389 -1714 75 -881 -1561 -1459 -1525 -1007 -1822 -1990 -680 -545 -3205 -1337 -2404 -732 -1097 -571 -546 -1367 -1265 239 859 1106 637 355 341 774 1964 2347 1755 2084 995 1052 2699 1754 113 351 471 -520 148 93 -653 774 790 111 -51 -607 -1655 -2766 SS 20211101T125318.9Z 7975.537025 187 1 49.28 2 81.61 119.95 42.61 146.47 0.00 1 0.00 1 0 17 5.859e-01 9.727e-03 9.361e-02 2.016e-03 7.506184e-01 1.117609e-03 8.673899e-03 -6.000000e+00 3.475223e-01 223.74 -2.00 3.58 -2.00 321.38 0.00e+00 6.840803e-03 5.610880e-04 2.316020e-03 -6.000000e+00 1.532512e-02 278.22 -2.00 20.00 -2.00 320.88 0.00e+00 6.448 0.005 302.00 328.00 3 3.6399e-01 3.8097e-03 7.4395e-02 -6.0000e+00 8.5577e-01 1.3394e-01 5.3935e-03 4.1932e-02 -6.0000e+00 9.3064e-01 -1.5368e-01 5.6788e-03 2.5436e-02 -6.0000e+00 5.5505e-01 5.5163e-02 2.6698e-03 1.1148e-02 -6.0000e+00 2.3307e-01 3.5235e-04 -1.2029e-03 5.9068e-05 1.6385e-04 -6.0000e+00 1.8208e-02 1.0986e-02 -3.0200e-05 12 8 8 10 0 0 36.11 22.59 0.21 0.01099 0.00195 219 47 1 5 0 224.980 26.32 19.99 22.59 10.83 32.7 922.45 -235297 -103618 -208060 -204760 -190244 -178861 -130765 -142676 -201109 -136255 -194940 -188028 -150841 -118556 -55267 -81421 -45506 -85751 -19518 -55813 4801 -31691 -6295 -48317 -8685 -63718 -21666 -63848 11413 -61200 9299 -17918 11417 -22985 -10223 -6421 -1982 -7699 1671 -4435 9261 233 7564 -1782 5163 2581 2849 4644 7743 1628 9567 6285 9321 9765 8607 4085 4313 3007 1180 1291 93 4812 4480 6583 4732 4649 1616 2133 2207 4806 2763 3136 -672 1725 379 -262 -1589 -1138 -808 912 -1485 460 -1584 -2067 -1361 -769 -418 399 -525 427 3 366 -834 -222 -774 -192 -17 431 -95 -388 -708 -1519 -687 -99 -801 -1986 -1042 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