File name: Pandora169s1_Egbert_20211129_L2Fit_fwvt1c16d20210920p1-8.txt File generation date: 20241103T111638.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211129_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1649 1798 Nominal wavelengths inside fitting window [nm]: 492.0971 492.2180 492.3388 492.4597 492.5805 492.7013 492.8221 492.9428 493.0636 493.1843 493.3050 493.4257 493.5464 493.6671 493.7878 493.9084 494.0290 494.1496 494.2702 494.3908 494.5113 494.6319 494.7524 494.8729 494.9934 495.1139 495.2343 495.3548 495.4752 495.5956 495.7160 495.8364 495.9568 496.0771 496.1974 496.3177 496.4380 496.5583 496.6786 496.7988 496.9191 497.0393 497.1595 497.2797 497.3998 497.5200 497.6401 497.7602 497.8803 498.0004 498.1205 498.2405 498.3606 498.4806 498.6006 498.7206 498.8405 498.9605 499.0804 499.2004 499.3203 499.4401 499.5600 499.6799 499.7997 499.9195 500.0393 500.1591 500.2789 500.3987 500.5184 500.6381 500.7578 500.8775 500.9972 501.1169 501.2365 501.3561 501.4757 501.5953 501.7149 501.8345 501.9540 502.0735 502.1930 502.3125 502.4320 502.5515 502.6709 502.7904 502.9098 503.0292 503.1485 503.2679 503.3872 503.5066 503.6259 503.7452 503.8645 503.9837 504.1030 504.2222 504.3414 504.4606 504.5798 504.6990 504.8181 504.9373 505.0564 505.1755 505.2946 505.4136 505.5327 505.6517 505.7707 505.8897 506.0087 506.1277 506.2466 506.3656 506.4845 506.6034 506.7223 506.8412 506.9600 507.0788 507.1977 507.3165 507.4353 507.5540 507.6728 507.7915 507.9102 508.0289 508.1476 508.2663 508.3850 508.5036 508.6222 508.7408 508.8594 508.9780 509.0965 509.2151 509.3336 509.4521 509.5706 509.6891 509.8075 509.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211129T143356.2Z 8003.606901 198 1 14.42 2 74.60 143.19 46.66 212.37 0.00 1 0.00 1 0 15 2.858e-03 2.851e-03 1.213e-04 1.212e-04 1.325762e+03 6.933504e+00 9.962285e+01 -6.000000e+00 1.577313e+02 274.81 -2.00 20.00 -2.00 505.28 0.00e+00 3.990716e-04 3.300734e-06 2.326905e-05 -6.000000e+00 7.946034e-05 274.81 -2.00 20.00 -2.00 500.55 0.00e+00 2.967827e-01 2.398623e-03 1.144521e-02 -6.000000e+00 5.716451e-02 222.27 -2.00 3.58 -2.00 502.12 0.00e+00 3.696 0.001 489.00 513.00 1 2.1475e+00 1.8372e-04 5.2516e-03 -6.0000e+00 4.3800e-03 3.7542e-03 4.7165e-05 3.8496e-04 -6.0000e+00 1.1278e-03 1.3359e-01 1.2761e-03 1.3072e-05 1.5956e-05 -6.0000e+00 3.1599e-04 7.1131e-03 1.3588e-04 10 0 0 10 0 0 99.35 22.68 1.37 0.00711 0.01596 576 123 1 4 0 24.430 26.41 19.98 22.68 3.46 32.8 905.60 -466 -230 34 100 190 469 581 543 421 270 131 -58 -253 -366 -389 -373 -132 151 153 -3 58 172 237 372 439 289 276 117 -252 -527 -414 -371 -9 353 194 -74 -21 -17 -175 -177 -78 14 102 220 277 301 224 107 -83 -372 -589 -717 -704 -498 -187 -104 -63 -48 -3 97 240 353 338 369 326 208 97 33 -116 -248 -288 -181 -92 93 -13 -299 -410 -349 -324 -372 -372 -361 -322 -154 -72 -170 -142 -98 -82 -12 102 326 361 283 203 149 -32 -230 -353 -562 -599 -388 -23 48 -161 -295 -291 -295 -196 -15 30 99 231 275 377 469 557 500 337 239 195 101 221 238 89 131 227 169 219 246 11 -199 -211 -316 -228 38 2 -99 43 171 157 242 345 247 197 35 -199 -362 -379 -291 -454 -225 35 102 194 487 599 562 434 279 134 -58 -257 -369 -392 -374 -135 154 160 -3 60 178 246 386 456 300 288 120 -257 -528 -412 -373 -9 366 201 -77 -22 -18 -180 -181 -80 14 105 228 288 312 231 109 -83 -373 -578 -705 -692 -488 -187 -105 -64 -48 -4 98 244 359 343 373 327 209 96 33 -114 -243 -281 -177 -90 91 -13 -292 -402 -338 -311 -358 -361 -352 -312 -150 -71 -169 -142 -98 -81 -12 101 328 360 282 204 147 -31 -221 -339 -535 -574 -373 -23 48 -160 -292 -290 -292 -193 -15 30 100 231 276 382 476 566 506 338 240 194 99 217 234 88 130 224 167 215 241 11 -194 -203 -302 -219 37 2 -99 42 170 158 244 343 247 196 35 -195 -355 -367 -282 SQ 20211129T143411.0Z 8003.607072 198 2 14.57 2 74.57 143.24 46.68 212.45 0.00 1 0.00 1 0 22 2.537e-03 2.529e-03 1.547e-04 1.545e-04 1.308882e+03 8.829354e+00 9.770832e+01 -6.000000e+00 1.399772e+02 274.81 -2.00 20.00 -2.00 505.27 0.00e+00 3.576098e-04 4.211473e-06 2.131847e-05 -6.000000e+00 7.051781e-05 274.81 -2.00 20.00 -2.00 500.53 0.00e+00 3.157701e-01 3.060341e-03 1.133663e-02 -6.000000e+00 5.073424e-02 222.27 -2.00 3.58 -2.00 502.11 0.00e+00 3.691 0.001 489.00 513.00 1 2.6173e+00 2.3450e-04 5.2369e-03 -6.0000e+00 3.8873e-03 6.0645e-03 6.0198e-05 3.8291e-04 -6.0000e+00 1.0010e-03 8.3508e-02 1.2337e-03 1.6689e-05 1.5351e-05 -6.0000e+00 2.8044e-04 6.6466e-03 1.3328e-04 10 0 0 10 0 0 98.33 22.68 1.37 0.00665 0.01520 576 123 1 4 0 24.430 26.41 19.98 22.68 3.64 32.8 907.04 -328 -183 60 90 186 446 525 470 386 253 127 -34 -205 -277 -319 -305 -85 121 100 -26 32 140 236 337 391 231 240 137 -208 -442 -332 -303 32 303 104 -115 -28 -36 -181 -178 -82 22 69 190 225 251 175 95 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-269 -151 60 -15 -111 32 141 140 215 309 204 155 15 -177 -280 -288 -192 SQ 20211129T143425.6Z 8003.607241 198 3 14.45 2 74.54 143.29 46.71 212.52 0.00 1 0.00 1 0 15 2.461e-03 2.456e-03 1.881e-04 1.878e-04 1.314154e+03 1.077977e+01 9.736840e+01 -6.000000e+00 1.357819e+02 274.81 -2.00 20.00 -2.00 505.27 0.00e+00 3.609389e-04 5.120265e-06 2.157365e-05 -6.000000e+00 6.840601e-05 274.81 -2.00 20.00 -2.00 500.52 0.00e+00 3.158693e-01 3.720786e-03 1.150470e-02 -6.000000e+00 4.921950e-02 222.27 -2.00 3.58 -2.00 502.11 0.00e+00 3.685 0.001 489.00 513.00 1 2.9876e+00 2.8506e-04 5.2317e-03 -6.0000e+00 3.7711e-03 7.8501e-03 7.3147e-05 3.8418e-04 -6.0000e+00 9.7127e-04 5.7706e-02 1.3322e-03 2.0253e-05 1.5148e-05 -6.0000e+00 2.7205e-04 7.2818e-03 1.2108e-04 10 0 0 10 0 0 51.29 22.68 1.36 0.00728 0.01652 576 123 1 4 0 24.430 26.41 19.98 22.68 3.64 32.8 907.04 -300 -147 23 99 165 441 525 434 400 231 124 -13 -217 -247 -333 -293 -126 90 52 -66 46 150 176 300 379 248 264 146 -214 -408 -302 -287 58 296 101 -112 -10 -8 -156 -120 -55 25 76 181 203 190 140 86 -94 -309 -538 -588 -627 -444 -176 -160 -118 -135 -66 131 215 300 286 352 340 192 65 48 -78 -191 -218 -129 -97 108 5 -290 -399 -262 -264 -366 -335 -333 -341 -152 -114 -183 -136 -42 -69 -26 96 246 272 228 194 102 -86 -201 -253 -510 -484 -334 -46 6 -190 -314 -247 -231 -128 11 20 60 209 270 333 413 500 418 297 212 190 128 238 248 115 156 177 106 179 209 23 -203 -205 -207 -182 49 -18 -75 42 130 153 232 311 218 124 20 -191 -279 -316 -209 -294 -144 23 100 171 454 546 454 415 237 128 -13 -219 -248 -335 -298 -127 93 55 -68 48 155 183 312 395 258 278 151 -217 -414 -304 -292 59 309 105 -117 -10 -8 -162 -124 -56 25 78 188 212 198 144 87 -95 -306 -533 -574 -611 -439 -174 -163 -119 -136 -67 132 218 304 291 356 340 194 65 47 -76 -184 -210 -125 -94 107 5 -284 -385 -256 -256 -355 -327 -321 -331 -149 -112 -182 -136 -42 -67 -25 95 247 274 230 193 100 -84 -193 -239 -489 -456 -321 -44 6 -191 -316 -245 -227 -125 10 20 60 210 273 338 421 510 425 299 210 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