File name: Pandora169s1_Egbert_20211206_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T111433.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211206_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211206T172157.3Z 8010.723580 191 1 18.47 2 66.86 182.91 77.88 148.56 0.00 1 0.00 1 0 25 3.342e-02 8.509e-03 1.868e-02 3.630e-03 3.543679e-01 1.874477e-03 4.326040e-03 -6.000000e+00 1.972748e-02 222.18 -2.00 3.58 -2.00 317.92 0.00e+00 9.586371e-04 3.233353e-04 2.416958e-04 -6.000000e+00 8.594873e-04 273.99 -2.00 20.00 -2.00 317.36 0.00e+00 2.525 0.000 302.00 328.00 3 4.8232e+00 4.9469e-03 3.0340e-02 -6.0000e+00 4.8485e-02 6.2527e-02 5.5955e-03 1.8080e-02 -6.0000e+00 5.2794e-02 -3.2205e-03 3.6122e-03 9.1276e-03 -6.0000e+00 3.1446e-02 -8.2689e-03 1.8517e-03 2.7861e-03 -6.0000e+00 1.3215e-02 2.3143e-04 1.9233e-04 1.1486e-04 3.4736e-05 -6.0000e+00 1.0373e-03 4.8203e-03 1.1954e-04 12 9 1 12 1 1 99.98 22.68 0.12 0.00482 0.00627 6 4 1 5 0 2612.870 26.41 20.00 22.68 8.75 33.5 941.31 470 14381 -15968 7728 -2855 10404 8271 7710 -4791 -4121 -13891 -778 -10740 -576 -4068 1245 -5475 4053 -2185 707 -456 3600 -4084 5927 -4464 4043 -1661 -634 -2212 1415 -308 5168 2816 -1738 -7753 2842 -3638 2449 -291 59 -2662 -1003 -981 -2010 -882 2173 -195 -126 394 543 763 2052 458 711 2238 -165 2910 454 842 -1409 1106 616 718 1179 1818 -1536 1030 -1323 769 982 1165 -449 306 992 778 -1403 -159 -1339 100 -914 -1388 -1414 -2304 -2368 -677 -162 220 239 520 426 392 523 331 -49 -66 909 520 929 -192 -650 -496 -1534 -1217 -180 -323 -1561 -1451 90 237 960 55 1067 28 81 238 1204 321 213 178 21 -498 237 -208 488 514 478 95 578 698 64 109 -774 -319 -292 435 -234 -64 0 360 -193 -126 -397 -241 27 801 -1224 467 -178 555 466 479 -368 -335 -1275 -67 -1131 -64 -539 176 -885 637 -380 124 -83 639 -793 1106 -963 841 -365 -135 -460 285 -67 1167 701 -468 -2166 720 -1032 745 -105 24 -1217 -477 -481 -1010 -442 1065 -97 -62 194 273 399 1126 268 434 1399 -107 1879 299 547 -926 728 428 530 912 1424 -1200 761 -985 587 806 1018 -410 279 881 659 -1131 -119 -986 75 -748 -1242 -1360 -2353 -2517 -743 -185 259 287 624 502 444 561 339 -49 -69 1011 623 1185 -257 -873 -645 -1914 -1460 -215 -402 -2030 -1945 124 337 1421 85 1663 43 121 343 1665 443 300 259 32 -764 360 -311 711 728 658 128 781 978 95 166 -1220 -511 -479 735 -408 -113 1 647 -342 -219 -675 -405 SS 20211206T172656.4Z 8010.727041 194 1 27.72 2 66.91 184.16 77.44 149.56 0.00 1 0.00 1 0 17 2.272e-02 6.315e-03 1.651e-02 2.513e-03 3.579788e-01 1.295526e-03 4.344359e-03 -6.000000e+00 1.341239e-02 222.18 -2.00 3.58 -2.00 318.51 0.00e+00 1.067711e-03 2.620175e-04 1.875507e-04 -6.000000e+00 5.843359e-04 273.99 -2.00 20.00 -2.00 317.96 0.00e+00 2.531 0.000 302.00 328.00 3 4.2970e+00 3.4692e-03 3.0526e-02 -6.0000e+00 3.2964e-02 4.3355e-02 3.9535e-03 1.8334e-02 -6.0000e+00 3.5892e-02 1.1690e-02 2.7006e-03 9.2806e-03 -6.0000e+00 2.1378e-02 -1.7017e-02 1.4053e-03 2.9138e-03 -6.0000e+00 8.9853e-03 3.8979e-04 2.1769e-04 8.0815e-05 3.6316e-05 -6.0000e+00 7.0520e-04 4.8040e-03 1.5115e-04 12 1 1 12 1 1 100.00 22.70 0.24 0.00480 0.00644 74 29 1 5 0 367.190 26.41 20.00 22.70 8.99 33.5 942.76 6104 -2205 3470 -1765 9748 3683 16620 5217 744 752 -3987 -5910 3242 -500 2036 1844 -463 -2389 -161 288 2650 -413 -51 -518 -401 -1809 -2802 -1712 777 -606 3934 3400 1565 -357 -5360 -82 -3170 -678 -988 -554 -1415 -1177 -855 -2005 -1636 -111 -2074 378 -22 -138 1068 548 251 1296 1262 714 1141 55 27 510 775 984 742 2080 124 -780 -99 -2 1116 1990 908 -355 82 536 374 -94 -12 -730 176 -254 -1376 -1701 -1273 -2059 -645 -594 43 625 535 424 419 690 339 90 1018 519 574 716 -202 -613 -199 -1154 -646 321 -810 -1772 -865 -579 -161 578 561 424 78 -180 21 286 819 333 289 -302 -553 -19 174 177 538 498 -112 783 702 -108 42 -392 -241 116 -64 -335 -59 439 -33 -140 54 -66 -376 261 -112 176 -92 436 168 702 265 43 46 -263 -417 235 -43 198 201 -56 -309 -21 40 364 -59 -7 -79 -65 -310 -488 -288 124 -98 647 617 312 -76 -1170 -17 -715 -170 -292 -187 -529 -466 -351 -843 -690 -47 -884 157 -9 -59 473 260 127 683 690 402 656 32 15 291 449 604 491 1439 89 -547 -66 -1 768 1479 733 -302 70 443 292 -68 -8 -482 119 -189 -1146 -1542 -1230 -2090 -682 -658 49 732 628 488 461 710 331 86 1016 561 674 910 -271 -827 -258 -1421 -759 375 -1002 -2297 -1156 -804 -232 875 887 684 124 -277 31 403 1139 475 430 -468 -873 -30 266 264 775 692 -153 1068 1000 -163 66 -639 -402 198 -113 -618 -112 833 -64 -264 100 -117 -663 SS 20211206T185828.8Z 8010.790611 238 1 38.17 2 71.25 206.30 71.80 169.24 0.00 1 0.00 1 0 17 2.557e-01 1.016e-02 1.240e-01 4.753e-03 4.530104e-01 2.480224e-03 5.426406e-03 -6.000000e+00 1.519247e-01 222.18 -2.00 3.58 -2.00 319.33 0.00e+00 4.116654e-03 6.542479e-04 2.171432e-04 -6.000000e+00 6.599516e-03 273.99 -2.00 20.00 -2.00 318.81 0.00e+00 3.073 0.001 302.00 328.00 3 5.1427e+00 6.8290e-03 3.7793e-02 -6.0000e+00 3.7338e-01 9.2588e-02 7.9809e-03 2.3779e-02 -6.0000e+00 4.0680e-01 8.6081e-03 6.3829e-03 1.2352e-02 -6.0000e+00 2.4150e-01 -1.7722e-02 3.3666e-03 5.5338e-03 -6.0000e+00 1.0104e-01 8.5043e-05 -7.6604e-04 1.5009e-04 5.9910e-05 -6.0000e+00 7.9945e-03 6.0415e-03 -6.3099e-06 12 9 9 12 9 1 100.00 22.69 0.12 0.00604 0.00029 17 5 1 5 0 2110.650 26.41 20.00 22.69 7.90 33.4 936.27 3697 203313 -47798 91369 88782 34951 900000 147351 -19324 20385 -33036 32497 -3501 5028 -15346 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