File name: Pandora169s1_Egbert_20211216_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T114943.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211216_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211216T133641.6Z 8020.567148 244 1 49.22 2 83.96 131.22 113.81 334.76 0.00 1 0.00 1 0 25 7.923e-01 3.585e-02 3.091e-01 1.391e-02 9.174246e-01 8.240690e-03 1.045458e-02 -6.000000e+00 4.765185e-01 222.09 -2.00 3.58 -2.00 322.01 0.00e+00 6.733039e-03 3.788091e-03 3.505927e-03 -6.000000e+00 2.288307e-02 272.90 -2.00 20.00 -2.00 321.55 0.00e+00 8.511 0.012 302.00 328.00 3 1.2028e+00 2.7685e-02 9.6963e-02 -6.0000e+00 1.1783e+00 1.4413e+00 3.4795e-02 5.3770e-02 -6.0000e+00 1.2900e+00 -1.8474e+00 2.8191e-02 2.9200e-02 -6.0000e+00 7.5506e-01 7.5083e-01 1.4167e-02 9.2522e-03 -6.0000e+00 3.1696e-01 1.5784e-05 -3.8237e-03 4.0391e-04 1.6483e-04 -6.0000e+00 2.5530e-02 1.0706e-02 -8.3120e-05 12 8 8 10 0 0 91.85 22.68 0.43 0.01071 -0.01803 29 6 1 5 0 1697.020 26.41 20.00 22.68 18.46 34.9 1005.80 134705 900000 -461 900000 144617 60794 900000 900000 -72744 900000 -76700 900000 -97930 900000 47640 221354 86257 65794 31341 282010 119370 900000 -40080 900000 -56631 31839 -16619 76944 139435 121386 424428 900000 145272 -27577 -10375 900000 -4459 211271 40229 60430 75361 32402 122660 12506 73517 130017 57059 292088 60664 60467 143420 86165 50250 85849 226906 -5789 108682 64338 79397 -16461 4685 -7117 11900 6552 61305 -7147 39027 -12286 15247 16693 37787 13598 21371 18232 37403 -19465 31674 -17261 11757 1450 -1928 16300 2612 -5158 -1229 -3686 -1080 3023 -6594 771 -2378 1102 15909 759 -8842 6451 -2058 -1551 -7591 -516 -2789 -5910 -9400 -2097 -5155 -6506 -1137 2567 -147 1399 -3933 -1862 -687 1268 852 1195 -130 56 255 773 1624 2594 3751 5360 406 1338 -7 738 216 -488 508 203 152 114 -553 246 1400 -58 230 -297 -1100 -1582 -706 2416 900000 -30 900000 1958 1481 900000 900000 -5225 900000 -5446 900000 -10266 900000 1938 2996 3008 2870 1871 3817 2887 900000 -3611 900000 -5733 1418 -1086 1998 1920 2071 5745 900000 2954 -2800 -864 900000 -333 2860 2442 3416 4016 2634 4464 1215 4060 4227 3607 3954 3932 4146 5006 5500 4738 6229 4695 -995 6758 5764 5914 -2734 641 -1145 1794 1150 7113 -1548 5655 -2905 3047 3640 7380 3392 4883 4018 6316 -4911 4770 -4094 2397 380 -610 5003 1002 -2267 -550 -1765 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22.68 0.30 0.01008 -0.00397 33 7 1 5 0 1485.550 26.41 20.00 22.68 18.65 34.9 1006.50 -201411 900000 -208180 900000 900000 -97194 900000 900000 -220795 900000 -238254 900000 -168273 142398 -94841 43308 -39432 146040 -23070 16177 35460 99073 -17454 57705 -66673 -32088 -73019 -46322 900000 -4574 900000 58286 187022 -66135 -28954 900000 6779 49806 53915 384 35422 2144 84011 -1331 33715 59490 18855 52074 23738 25903 46745 33479 30985 36684 66965 -684 28520 17199 22916 -1649 2564 -4922 10135 11339 23341 3688 14357 -4315 7140 2714 8590 9689 2470 10045 6741 -8644 6783 -6182 -349 2254 -4780 4761 -2257 -5129 -2335 -910 -1187 282 -4080 -818 -1186 1836 4073 -717 -3792 3098 -130 23 -2393 -771 -947 854 -4567 -1469 -1916 -3405 -852 -640 -110 285 -1136 -534 -359 -166 674 65 856 -71 -500 839 1049 1260 1305 1560 920 -446 884 1110 1462 -491 793 72 572 -135 -759 -304 335 84 198 258 -614 -716 -720 -3900 900000 -5439 900000 900000 -775 900000 900000 -5768 900000 -7853 900000 -4307 905 -2130 331 -755 928 -454 230 423 633 -330 552 -2033 -725 -2382 -1189 900000 -93 900000 983 1189 -4195 -1315 900000 232 1300 1570 21 1537 134 2674 -93 1783 2586 1219 2644 1647 1901 3138 2791 2879 3475 5101 -97 3166 2086 2579 -228 352 -790 1608 2001 3991 770 2757 -1022 1662 734 2398 2781 749 2695 1713 -2306 1497 -1580 -95 706 -1870 1947 -1082 -2696 -1267 -512 -701 169 -2534 -480 -666 955 2043 -393 -2389 2128 -107 22 -2468 -802 -949 776 -4009 -1226 -1664 -3152 -814 -656 -123 355 -1581 -791 -544 -250 981 93 1221 -105 -776 1321 1636 1900 1900 2207 1274 -609 1182 1550 2250 -858 1503 146 1225 -305 -1816 -751 841 214 500 632 -1445 -1601 -1567 SS 20211216T135847.2Z 8020.582491 250 1 49.16 2 81.08 135.43 115.22 340.07 0.00 1 0.00 1 0 25 4.565e-01 8.908e-03 1.959e-01 3.073e-03 7.422122e-01 1.696120e-03 8.434541e-03 -6.000000e+00 2.714239e-01 222.09 -2.00 3.58 -2.00 321.25 0.00e+00 7.723921e-03 7.933921e-04 1.081293e-03 -6.000000e+00 1.194044e-02 272.90 -2.00 20.00 -2.00 320.81 0.00e+00 6.113 0.004 302.00 328.00 3 1.5420e+00 5.4934e-03 7.0993e-02 -6.0000e+00 6.6675e-01 1.2567e-01 7.8660e-03 4.1231e-02 -6.0000e+00 7.2689e-01 -1.1865e-01 8.7330e-03 2.4947e-02 -6.0000e+00 4.3083e-01 3.6767e-02 4.1699e-03 1.2858e-02 -6.0000e+00 1.8006e-01 1.4829e-04 -9.8580e-04 9.0603e-05 1.5776e-04 -6.0000e+00 1.4398e-02 9.3749e-03 -3.5409e-05 11 8 0 10 0 0 98.49 22.68 0.21 0.00937 0.00197 79 17 1 5 0 622.100 26.41 20.00 22.68 18.66 34.9 1006.84 -201037 -67938 -172329 -70614 900000 -155851 900000 -164015 -182248 -8710 -149798 -126112 -126311 -112750 -38947 -11358 5624 -96003 39868 -53268 44752 -35518 -19170 -59171 -42417 -77887 -24373 -59905 59624 -35816 64723 430 25626 -38895 -8548 26074 -3155 4925 -1996 -9719 5268 -1593 8097 -4916 -1583 13733 -4522 19797 4541 10242 7166 11183 5090 8129 9152 617 5308 5471 -1651 -328 -4195 2731 -388 3898 5362 3748 2657 295 253 3379 1530 875 -1154 1483 703 -2664 -927 -1497 -535 996 -2086 -249 -2776 -2619 -1024 -587 322 877 -954 231 238 739 986 -462 -374 1026 772 1007 225 -529 -246 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