File name: Pandora169s1_Egbert_20211217_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T115133.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211217_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211217T144030.3Z 8021.611462 317 1 49.27 2 76.33 143.77 111.66 340.01 0.00 1 0.00 1 0 17 4.663e-02 5.407e-03 1.806e-02 8.933e-04 4.897275e-01 4.671175e-04 5.759320e-03 -6.000000e+00 2.750095e-02 222.14 -2.00 3.58 -2.00 319.95 0.00e+00 2.022233e-03 1.479310e-04 2.934965e-04 -6.000000e+00 1.193281e-03 272.84 -2.00 20.00 -2.00 319.45 0.00e+00 4.133 0.001 302.00 328.00 3 1.2081e+00 1.3317e-03 4.7138e-02 -6.0000e+00 6.7608e-02 -3.2945e-04 1.5981e-03 2.5677e-02 -6.0000e+00 7.3654e-02 3.8687e-02 1.4138e-03 1.3207e-02 -6.0000e+00 4.3841e-02 -3.0789e-02 7.3404e-04 4.7056e-03 -6.0000e+00 1.8390e-02 1.7023e-03 -1.8059e-04 2.8434e-05 5.6704e-05 -6.0000e+00 1.4477e-03 9.4624e-03 9.4055e-05 10 0 0 10 0 0 99.99 22.77 0.14 0.00946 0.00811 838 179 1 5 0 58.780 26.51 20.00 22.77 7.26 33.4 939.16 -2367 -22325 1033 -15247 -2723 -24694 13940 -15253 -12143 -16591 -17113 -13684 -7744 -3312 1684 2681 -478 -2778 -4 831 1006 1851 712 1965 -409 -770 -3560 -4240 -1176 1859 1118 5234 3236 128 -5022 1052 -2036 -674 -1426 -940 -2814 -1907 -1738 -1083 -1216 734 -1000 727 -458 755 743 1116 723 1242 519 121 338 -448 -718 103 318 1456 1798 1564 385 -524 488 -403 1185 1420 556 174 40 122 357 -324 -96 -568 25 -233 -984 -1389 -1911 -1994 -618 -526 203 413 522 509 738 556 360 607 878 483 695 961 -13 -491 -350 -758 -156 578 -300 -1686 -992 -983 -303 506 304 63 -66 56 59 497 569 345 278 -166 -608 -71 111 267 324 148 -209 1129 747 -8 -104 -522 -423 -16 -49 -302 -109 389 75 -13 212 -141 -197 -27 -367 14 -250 -37 -414 168 -257 -224 -348 -384 -329 -195 -99 55 101 -21 -128 0 42 53 99 40 116 -25 -50 -245 -289 -77 123 83 430 306 13 -519 103 -222 -85 -207 -161 -553 -383 -367 -234 -268 161 -227 165 -108 184 196 323 229 401 178 43 124 -167 -264 37 119 583 795 758 188 -266 238 -201 625 801 348 115 27 78 211 -175 -50 -294 14 -141 -689 -1053 -1592 -1704 -555 -504 203 426 538 508 692 507 312 525 815 487 763 1180 -17 -637 -432 -897 -172 631 -349 -2112 -1255 -1321 -436 760 476 103 -107 88 90 721 820 515 439 -265 -988 -117 177 410 476 217 -299 1625 1128 -14 -181 -934 -790 -31 -98 -639 -230 830 160 -26 436 -278 -393 SS 20211217T145046.1Z 8021.618589 320 1 49.76 2 75.27 145.94 112.21 342.40 0.00 1 0.00 1 0 17 5.972e-01 1.195e-02 1.493e-01 5.457e-03 4.566299e-01 2.854746e-03 5.420072e-03 -6.000000e+00 3.521568e-01 222.14 -2.00 3.58 -2.00 319.74 0.00e+00 2.353025e-03 8.357437e-04 3.094647e-04 -6.000000e+00 1.541929e-02 272.84 -2.00 20.00 -2.00 319.23 0.00e+00 3.855 0.001 302.00 328.00 3 4.7477e+00 8.0127e-03 4.3901e-02 -6.0000e+00 8.6570e-01 9.0336e-02 9.5070e-03 2.3766e-02 -6.0000e+00 9.4329e-01 1.2590e-02 7.9907e-03 1.2355e-02 -6.0000e+00 5.6171e-01 -1.6950e-02 4.1731e-03 4.4719e-03 -6.0000e+00 2.3682e-01 6.2753e-05 -4.8985e-04 1.7599e-04 5.4934e-05 -6.0000e+00 1.8560e-02 9.9580e-03 3.3328e-05 12 8 8 10 0 0 99.97 22.80 0.37 0.00996 0.00628 36 8 1 5 0 1382.010 26.51 19.97 22.80 7.24 33.4 938.87 32232 900000 -9255 71265 216246 -20219 645926 45414 -8334 11186 -28454 -14274 -39716 19640 -8033 -2886 -10172 18294 -1969 15458 -1114 21813 -17637 701 -23652 -1066 -12775 -653 9609 10802 8775 28617 19631 -11577 -17637 25007 -13102 8515 -1481 -2529 -1975 -395 1055 -1245 -2765 11574 -6632 8139 800 6601 4163 5622 -690 1713 8718 -3292 1819 982 1387 -2063 -3198 -2370 -985 -475 887 -3055 1470 -4134 544 100 1221 896 579 -542 1942 -2839 1380 -3821 694 1327 -2384 321 -1243 -2828 -472 -1636 615 1225 482 179 1050 610 3466 455 140 3111 1427 54 155 -186 -645 -939 -1744 -817 -769 -2573 -781 -118 383 1115 848 -85 -309 120 334 391 17 233 -35 -319 41 341 509 920 -588 33 -494 597 408 -323 -779 -246 -481 -63 -195 69 83 3 456 268 -311 264 -258 410 900000 -200 774 1151 -442 3437 656 -207 252 -932 -449 -1768 633 -381 -149 -612 932 -126 893 -76 1247 -1447 52 -2289 -89 -1190 -54 718 822 741 2286 1865 -1519 -2425 2373 -1851 1137 -254 -507 -438 -92 254 -314 -717 2670 -1819 1974 211 1720 1185 1711 -239 618 3095 -1342 725 395 549 -839 -1351 -1065 -478 -248 471 -1649 739 -2194 295 60 789 605 393 -359 1181 -1658 724 -2062 380 811 -1695 246 -1042 -2539 -439 -1621 626 1272 504 183 1009 553 2916 392 128 3064 1581 67 201 -244 -814 -1110 -1967 -916 -902 -3216 -1004 -158 542 1678 1352 -141 -510 190 503 568 24 345 -55 -515 66 546 794 1391 -870 47 -686 835 607 -519 -1332 -436 -880 -120 -385 142 173 6 967 559 -631 514 -495 SS 20211217T150010.9Z 8021.625126 323 1 2.05 2 74.35 147.97 112.66 344.62 0.00 1 0.00 1 0 17 6.699e-02 6.705e-03 3.730e-02 3.471e-03 4.357789e-01 1.792616e-03 5.252690e-03 -6.000000e+00 3.949671e-02 222.14 -2.00 3.58 -2.00 319.03 0.00e+00 2.055092e-03 4.270533e-04 4.051166e-04 -6.000000e+00 1.714209e-03 272.84 -2.00 20.00 -2.00 318.50 0.00e+00 3.642 0.001 302.00 328.00 3 1.4424e+00 4.8824e-03 4.1560e-02 -6.0000e+00 9.7096e-02 2.6513e-02 5.6214e-03 2.2480e-02 -6.0000e+00 1.0580e-01 -8.5481e-03 4.2370e-03 1.1541e-02 -6.0000e+00 6.2971e-02 -6.4322e-03 2.2382e-03 3.9178e-03 -6.0000e+00 2.6403e-02 2.2476e-03 -5.5124e-04 1.0918e-04 4.8026e-05 -6.0000e+00 2.0804e-03 1.0205e-02 1.4144e-05 12 9 1 12 1 1 99.90 22.74 0.10 0.01021 0.00606 13 79 1 5 0 134.040 26.51 19.97 22.74 7.25 33.4 939.40 -30061 43173 -11878 8220 -26354 8179 -21282 14993 -19288 452 -17338 -5458 -23367 1238 -11576 -3403 -11976 -360 -2015 2925 1833 2059 -2246 2068 -103 771 -3210 843 -1215 -812 264 1193 3924 -3141 -1259 -1923 -349 502 -500 -2033 -1138 -1475 779 -823 -413 -307 161 -833 88 140 2010 904 2407 1196 1735 -321 2300 -620 -324 -744 1029 1032 2356 1235 730 -493 363 -494 828 1680 -12 176 342 682 324 -238 106 -883 -600 -471 -1420 -725 -1579 -1816 -912 -223 -258 284 -200 359 -61 99 -279 234 443 355 364 1150 234 -621 -360 -1034 -609 391 -310 -1734 -944 -544 2 700 217 298 106 104 336 378 842 437 557 -340 -692 78 272 900 207 116 -78 1271 682 -261 308 -628 -377 -220 -186 -465 -303 191 249 34 469 -634 -55 -943 825 -380 219 -893 202 -703 400 -755 16 -744 -228 -1304 66 -811 -253 -1049 -31 -184 267 174 198 -231 216 -12 90 -394 98 -141 -96 34 169 597 -535 -209 -321 -61 100 -118 -559 -343 -474 255 -280 -141 -106 56 -293 31 51 769 375 1051 556 838 -162 1159 -320 -165 -380 531 565 1377 775 472 -316 225 -308 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