File name: Pandora169s1_Egbert_20211221_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T115125.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211221_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211221T155722.9Z 8025.664848 383 1 34.41 2 70.11 160.50 97.98 315.60 0.00 1 0.00 1 0 17 3.705e-02 8.394e-03 1.708e-02 2.919e-03 3.815166e-01 1.507774e-03 4.618940e-03 -6.000000e+00 2.186649e-02 222.30 -2.00 3.58 -2.00 318.13 0.00e+00 1.664419e-03 2.741887e-04 2.790074e-04 -6.000000e+00 9.471689e-04 272.58 -2.00 20.00 -2.00 317.60 0.00e+00 2.908 0.000 302.00 328.00 3 4.6497e+00 3.9949e-03 3.4082e-02 -6.0000e+00 5.3780e-02 1.1054e-01 4.5270e-03 1.9466e-02 -6.0000e+00 5.8584e-02 -2.8778e-02 3.0023e-03 9.8723e-03 -6.0000e+00 3.4861e-02 2.0842e-03 1.5548e-03 3.2122e-03 -6.0000e+00 1.4618e-02 1.8303e-04 -3.7515e-04 9.1631e-05 3.8332e-05 -6.0000e+00 1.1503e-03 7.4588e-03 4.9163e-05 12 9 1 12 33 1 87.27 22.85 0.07 0.00746 0.00464 8 3 1 5 0 3803.420 26.62 19.99 22.85 7.11 33.2 941.92 -1743 6421 -11601 3790 -5610 568 17936 10701 -6091 -7699 -17417 -5315 -19409 -3809 -1979 -707 -2698 2414 1837 1046 5187 4415 -213 4818 -2902 -22 -3517 -3496 -2455 606 2265 2261 7630 -5616 -6557 380 -2966 1341 99 -1358 -1082 -1315 -865 -1679 528 1765 -2171 1380 -1966 -995 1744 1487 1294 2318 2022 1193 703 684 410 -423 405 1453 482 1885 1299 -586 -345 -904 356 1577 875 1411 1216 771 681 -1313 -306 -1857 -22 -1391 -1920 -872 -2769 -2288 -792 -507 116 410 -242 -21 222 311 660 324 84 772 790 483 -261 -651 -683 -1481 -694 829 -63 -1450 -936 -544 528 856 106 145 -39 221 380 613 658 335 321 109 45 95 233 -197 873 818 32 529 666 -399 -272 -1041 -145 -131 -13 -305 249 438 297 34 -255 -322 -526 -86 329 -733 204 -308 28 793 554 -404 -551 -1410 -409 -1919 -382 -227 -90 -380 345 277 165 808 699 -36 814 -554 -4 -704 -683 -461 112 439 482 1686 -1451 -1684 91 -777 383 33 -524 -456 -586 -397 -788 245 815 -1034 637 -938 -480 864 784 722 1343 1216 737 443 431 256 -265 257 964 344 1403 989 -441 -251 -655 267 1262 750 1246 1079 669 563 -1030 -224 -1341 -16 -1125 -1702 -827 -2807 -2407 -860 -573 135 486 -289 -24 249 330 668 326 87 857 945 618 -349 -876 -892 -1849 -830 985 -77 -1880 -1249 -749 751 1271 164 229 -62 334 552 860 915 477 472 165 70 146 350 -290 1242 1132 44 721 943 -596 -422 -1669 -236 -219 -22 -541 448 796 542 62 -450 -554 -895 SS 20211221T164715.4Z 8025.699484 415 1 9.26 2 68.02 172.54 103.52 325.15 0.00 1 0.00 1 0 17 1.786e-02 7.053e-03 9.011e-03 2.113e-03 3.554720e-01 1.090763e-03 4.348607e-03 -6.000000e+00 1.053838e-02 222.30 -2.00 3.58 -2.00 317.66 0.00e+00 7.361200e-04 1.735373e-04 1.930202e-04 -6.000000e+00 4.565156e-04 272.58 -2.00 20.00 -2.00 317.13 0.00e+00 2.649 0.000 302.00 328.00 3 3.1410e+00 2.8628e-03 3.1301e-02 -6.0000e+00 2.5919e-02 6.4637e-02 3.2288e-03 1.8126e-02 -6.0000e+00 2.8236e-02 -1.7798e-02 2.0305e-03 9.1063e-03 -6.0000e+00 1.6802e-02 -2.1127e-03 1.0269e-03 2.6980e-03 -6.0000e+00 7.0436e-03 1.1196e-03 -3.0389e-04 6.6565e-05 3.4573e-05 -6.0000e+00 5.5451e-04 8.5026e-03 3.5968e-05 12 9 1 12 1 1 99.10 22.62 0.15 0.00850 0.00622 14 18 1 5 0 605.900 26.32 20.00 22.62 8.36 33.3 949.89 -3672 3930 -4491 -1697 -5546 -989 2691 -1687 -6624 -4460 -8966 -5091 -6608 -1920 489 245 -465 320 405 -694 -1529 -342 1412 1435 915 -757 -302 -1823 878 94 2786 2290 2933 -1423 -3695 -2272 -1411 -338 1364 -487 -1739 -989 -11 -601 -100 860 -1393 -314 205 -354 1011 1092 659 1452 1128 821 1162 -393 86 -424 699 1302 2218 1633 320 -797 -633 -87 1054 965 892 753 345 322 497 -385 -226 -864 24 -367 -1233 -1263 -2516 -1921 -989 -843 -230 103 270 277 378 388 -191 199 720 618 348 768 -524 -468 -411 -848 -449 580 -756 -1580 -803 -803 -152 634 32 326 -60 310 78 726 823 730 686 -227 -167 -161 222 382 885 460 2 1177 820 -3 64 -584 -238 18 -37 -516 -141 453 -202 -428 171 -352 -296 -265 280 -363 -129 -427 -70 191 -138 -603 -424 -920 -532 -792 -257 71 40 -83 60 80 -144 -328 -73 303 311 211 -185 -74 -437 206 22 651 593 824 -417 -1086 -680 -429 -117 533 -217 -842 -507 -6 -323 -54 460 -757 -167 108 -193 553 642 402 931 732 550 790 -271 58 -287 479 947 1684 1293 262 -634 -493 -67 841 804 789 700 323 291 430 -315 -175 -647 19 -309 -1114 -1232 -2613 -2047 -1081 -955 -273 122 321 327 429 416 -198 201 761 684 420 973 -699 -625 -534 -1049 -535 690 -940 -2051 -1062 -1092 -213 924 48 507 -92 459 110 1011 1132 1014 984 -338 -255 -243 331 548 1232 629 2 1586 1151 -5 97 -908 -381 29 -62 -894 -246 800 -360 -750 292 -593 -487 SS 20211221T165704.4Z 8025.706301 418 1 1.62 2 67.83 174.96 104.48 327.12 0.00 1 0.00 1 0 17 1.818e-02 7.445e-03 9.642e-03 2.406e-03 3.559643e-01 1.241855e-03 4.364940e-03 -6.000000e+00 1.072426e-02 222.31 -2.00 3.58 -2.00 317.61 0.00e+00 7.787322e-04 1.937493e-04 1.550774e-04 -6.000000e+00 4.646755e-04 272.58 -2.00 20.00 -2.00 317.06 0.00e+00 2.628 0.000 302.00 328.00 3 1.5964e+00 3.2558e-03 3.1154e-02 -6.0000e+00 2.6376e-02 4.9754e-02 3.6695e-03 1.8159e-02 -6.0000e+00 2.8737e-02 -2.2010e-02 2.2891e-03 9.1203e-03 -6.0000e+00 1.7100e-02 6.3589e-04 1.1506e-03 2.6994e-03 -6.0000e+00 7.1659e-03 5.3961e-03 -5.4468e-04 7.5559e-05 3.5035e-05 -6.0000e+00 5.6454e-04 9.9892e-03 7.9992e-06 12 9 1 12 1 1 10.04 22.61 0.24 0.00999 0.00590 10 81 1 5 0 130.600 26.32 20.00 22.61 9.03 33.3 953.21 2666 -4922 1615 -5604 -5352 -10189 365 -2536 -2369 -5978 -5388 -4389 -3115 -895 1348 -389 -1136 268 1792 1243 1695 -535 1861 1658 -350 -5 -2689 -1896 -1534 -649 165 1625 2081 -1553 -5079 -2784 -2115 -976 -595 -490 -1259 408 -442 118 -455 698 -713 444 -52 330 757 1802 1140 1162 712 1092 1181 360 -176 712 687 1895 1574 1260 562 -924 160 169 1309 1524 -474 527 295 307 456 -645 -685 -870 -204 -490 -1358 -1524 -2558 -1879 -520 -854 -46 58 141 525 312 580 -9 518 782 133 533 713 -219 -950 -531 -1056 49 370 -500 -1833 -1109 -975 -617 424 287 282 -42 203 109 677 735 425 615 137 -295 -20 486 322 804 647 132 1527 1188 213 51 -271 -177 -90 -101 -334 -137 428 -367 -234 -147 -689 -300 191 -426 136 -493 -435 -833 28 -221 -229 -596 -552 -471 -373 -123 211 -70 -208 51 355 257 358 -116 404 380 -87 -1 -715 -483 -374 -157 42 451 590 -476 -1581 -839 -678 -357 -244 -222 -639 206 -233 63 -246 374 -385 235 -28 178 431 1041 710 767 470 739 813 250 -121 482 477 1390 1206 994 455 -730 124 129 1047 1294 -431 479 270 282 405 -527 -535 -656 -160 -412 -1250 -1500 -2651 -1979 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