File name: Pandora169s1_Egbert_20220123_L2Fit_fout2c16d20210920p1-8.txt File generation date: 20241103T122335.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20220123_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20220123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0332 305.1741 305.3149 305.4558 305.5966 305.7375 305.8783 306.0191 306.1599 306.3007 306.4414 306.5822 306.7229 306.8637 307.0044 307.1451 307.2858 307.4265 307.5672 307.7079 307.8485 307.9892 308.1298 308.2705 308.4111 308.5517 308.6923 308.8329 308.9734 309.1140 309.2546 309.3951 309.5356 309.6762 309.8167 309.9572 310.0976 310.2381 310.3786 310.5190 310.6595 310.7999 310.9403 311.0807 311.2211 311.3615 311.5019 311.6423 311.7826 311.9229 312.0633 312.2036 312.3439 312.4842 312.6245 312.7648 312.9050 313.0453 313.1855 313.3258 313.4660 313.6062 313.7464 313.8866 314.0267 314.1669 314.3071 314.4472 314.5873 314.7274 314.8675 315.0076 315.1477 315.2878 315.4279 315.5679 315.7080 315.8480 315.9880 316.1280 316.2680 316.4080 316.5480 316.6879 316.8279 316.9678 317.1077 317.2477 317.3876 317.5275 317.6673 317.8072 317.9471 318.0869 318.2268 318.3666 318.5064 318.6462 318.7860 318.9258 319.0655 319.2053 319.3451 319.4848 319.6245 319.7642 319.9039 320.0436 320.1833 320.3230 320.4626 320.6023 320.7419 320.8815 321.0211 321.1607 321.3003 321.4399 321.5795 321.7190 321.8586 321.9981 322.1376 322.2771 322.4166 322.5561 322.6956 322.8350 322.9745 323.1139 323.2534 323.3928 323.5322 323.6716 323.8110 323.9503 324.0897 324.2290 324.3684 324.5077 324.6470 324.7863 324.9256 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220123T134714.8Z 8058.574477 299 1 12.08 2 81.53 127.80 70.05 248.54 0.00 1 0.00 1 0 25 4.896e-01 2.008e-02 2.741e-01 1.186e-02 9.839825e-01 7.570437e-03 1.082325e-02 -6.000000e+00 3.139684e-01 223.66 -2.00 3.58 -2.00 321.89 0.00e+00 1.826315e-02 3.942919e-03 4.371412e-03 -6.000000e+00 2.036663e-02 271.00 -2.00 20.00 -2.00 321.49 0.00e+00 6.396 0.005 302.00 328.00 3 2.0964e+00 2.6228e-02 8.9732e-02 -6.0000e+00 7.8604e-01 4.7712e-01 4.3230e-02 7.7245e-02 -6.0000e+00 8.6709e-01 -5.2970e-01 5.1446e-02 3.2776e-02 -6.0000e+00 4.8884e-01 2.1108e-01 2.3442e-02 1.8641e-02 -6.0000e+00 2.2134e-01 4.5123e-05 -2.3961e-03 3.5219e-04 2.0841e-04 -6.0000e+00 1.7727e-02 5.3532e-04 -3.5459e-04 12 9 9 12 1 1 32.27 22.62 0.09 0.00054 -0.01747 6 6 1 5 0 1699.900 26.32 20.00 22.62 -4.76 32.0 898.60 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -239379 900000 900000 900000 -162692 900000 -202612 900000 -27994 900000 900000 900000 -187149 900000 -45128 900000 900000 900000 -26111 900000 900000 -91880 -46752 900000 -27184 900000 900000 150041 -53023 127152 63376 35307 -35599 900000 -13923 45213 13571 29542 107562 45094 62057 15989 44647 -12605 23189 27282 30563 -6557 19884 2 8001 15695 27145 188 47613 -8266 22476 -1276 29288 8244 4811 -1429 8811 -3405 17879 -8409 -32 3529 -8442 5919 2466 -2405 -772 -3151 4765 -2602 -1688 -319 2057 -633 2545 -912 -814 377 -751 320 -1331 -673 1131 -590 -2896 -2562 -3530 -2365 -1054 -710 -1708 1173 -2157 1186 -1769 314 -1296 1715 1663 618 446 -543 467 1625 -647 1872 161 570 -886 2722 1061 671 67 736 -356 -193 270 -819 -597 131 -343 420 297 579 -1397 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -3062 900000 900000 900000 -3084 900000 -6692 900000 -322 900000 900000 900000 -5986 900000 -518 900000 900000 900000 -366 900000 900000 -3604 -1273 900000 -659 900000 900000 1723 -2603 1506 1364 1008 -1913 900000 -696 1489 635 1331 2828 2227 2927 1205 2786 -1327 1813 2037 2168 -634 1585 0 897 1887 3253 30 5157 -1560 3548 -280 5324 1879 1116 -330 1694 -666 2771 -1733 -7 902 -2859 2028 966 -1054 -352 -1537 2256 -1345 -863 -157 942 -284 1106 -434 -440 237 -560 271 -1252 -647 1031 -499 -2271 -1923 -2739 -1901 -883 -639 -1715 1299 -2738 1586 -2507 439 -1799 2283 2223 859 641 -801 670 2216 -861 2369 201 693 -1084 3401 1501 1076 119 1403 -725 -414 607 -1918 -1419 312 -812 956 643 1177 -2785 SS 20220123T141434.6Z 8058.593456 314 1 49.79 2 77.80 133.14 74.65 253.60 0.00 1 0.00 1 0 25 6.564e-01 2.346e-02 2.978e-01 8.145e-03 7.361191e-01 4.509556e-03 8.716554e-03 -6.000000e+00 3.921435e-01 223.66 -2.00 3.58 -2.00 320.95 0.00e+00 8.579460e-03 1.830654e-03 1.717972e-03 -6.000000e+00 1.725892e-02 271.00 -2.00 20.00 -2.00 320.51 0.00e+00 4.595 0.002 302.00 328.00 3 4.3745e+00 1.3711e-02 5.9120e-02 -6.0000e+00 9.6762e-01 4.1733e-01 1.7855e-02 3.9572e-02 -6.0000e+00 1.0548e+00 -4.0115e-01 1.7813e-02 2.3414e-02 -6.0000e+00 6.2465e-01 1.7193e-01 8.8387e-03 1.0408e-02 -6.0000e+00 2.6183e-01 2.9680e-05 -3.6372e-03 2.3768e-04 1.4509e-04 -6.0000e+00 2.0811e-02 2.6216e-03 -4.7476e-04 12 8 8 10 0 0 99.97 22.61 0.16 0.00262 -0.02471 19 4 1 5 0 2619.900 26.32 20.00 22.61 -5.06 32.1 896.59 -234269 900000 51919 900000 56791 -63143 900000 392920 36989 -31899 -83452 -93020 -163612 144722 900000 143807 -17955 -5140 28049 49673 29275 26944 94237 36364 -88261 -67596 33459 -12840 188170 -34430 348439 14260 236488 -53963 -3871 66309 -23640 31535 39093 -4693 13067 18031 26766 8100 -3955 16249 6805 54517 17358 12474 29794 25849 18059 12444 30575 3969 11819 15951 15191 -13668 -253 2869 -3477 10034 13075 -1161 5708 -1045 -4823 908 4149 6327 -5273 7310 2080 -1199 -7057 -449 -5825 2685 -5406 4472 -3958 -3772 -1410 -751 3388 1556 -2192 -450 -1191 -1606 3617 -1740 -4438 1208 -41 497 -1178 -263 655 -1415 -1735 -4319 -1579 -3900 -601 -750 734 879 -534 -355 1828 -929 -882 -620 2166 113 1455 -13 615 1413 838 1081 2058 -500 1906 713 2239 -1056 -90 -300 373 -936 -70 -44 547 116 116 -792 -3 -822 -488 -10326 900000 412 900000 451 -779 900000 3119 294 -359 -1499 -2010 -7557 1149 900000 1141 -523 -148 658 1017 715 668 1369 868 -6034 -3989 873 -484 1494 -1690 2766 635 1959 -5167 -242 2308 -1812 1705 2291 -456 1209 1713 2472 906 -501 1766 826 4549 2098 1677 3751 3703 3016 2342 5154 874 2469 3185 2986 -3430 -58 686 -985 2798 3792 -388 1793 -359 -1850 368 1780 2771 -2550 3002 826 -447 -2607 -158 -2356 1165 -2924 2502 -2616 -2647 -1023 -569 2581 1233 -1793 -352 -891 -1140 2376 -1230 -3516 1037 -41 551 -1428 -323 767 -1556 -1765 -4376 -1614 -4261 -669 -889 929 1222 -820 -576 2965 -1518 -1391 -945 3208 174 2309 -22 1005 2226 1278 1596 2916 -701 2567 996 3362 -1799 -165 -586 758 -2010 -157 -103 1284 276 273 -1829 -7 -1718 -985 SS 20220123T143511.8Z 8058.607776 323 1 19.05 2 75.19 137.37 78.19 257.26 0.00 1 0.00 1 0 17 2.751e-01 6.810e-03 3.284e-02 1.182e-03 6.689767e-01 6.299280e-04 7.772706e-03 -6.000000e+00 1.633220e-01 223.66 -2.00 3.58 -2.00 320.24 0.00e+00 3.772029e-03 2.195741e-04 6.749272e-04 -6.000000e+00 6.990412e-03 271.00 -2.00 20.00 -2.00 319.80 0.00e+00 3.837 0.001 302.00 328.00 3 1.1380e+00 1.8213e-03 5.0987e-02 -6.0000e+00 4.0311e-01 7.2971e-02 2.2761e-03 3.5164e-02 -6.0000e+00 4.3868e-01 -4.7815e-02 2.2484e-03 1.9208e-02 -6.0000e+00 2.6054e-01 5.7563e-03 1.1504e-03 7.6786e-03 -6.0000e+00 1.0894e-01 1.8461e-03 -7.8422e-04 3.4029e-05 9.0556e-05 -6.0000e+00 8.5408e-03 -1.8981e-03 -2.6042e-05 12 9 1 12 1 1 99.97 22.63 0.16 -0.00190 -0.00779 151 83 1 5 0 124.150 26.41 20.01 22.63 -4.83 32.2 898.80 -104171 -92444 -88223 -94015 -89953 -110310 -74251 -97495 -80747 -81906 -76202 -75762 -53412 -39363 -19047 -13336 -14417 -17314 -6668 -12301 -4798 -12208 249 -10848 -10476 -12364 -8028 -13953 -9987 -6846 -1757 -1658 2175 -1386 -6386 -4023 -5805 -2822 -1689 -1111 -1006 -223 -354 -522 -292 1570 -233 1263 137 1731 2314 2954 2480 2485 1644 1779 1405 526 -564 -214 821 2282 2586 3087 1706 426 768 166 1020 1743 798 857 208 162 -132 -936 -1251 -1421 -1284 -239 -1271 -837 -1788 -1958 -1203 -615 169 518 519 526 283 228 -344 -131 7 186 482 878 335 -518 -295 -830 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