File name: Pandora169s1_Egbert_20220531_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T164228.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v4d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20220531_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20220531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220531T102630.9Z 8186.435079 61 1 49.52 2 83.35 65.70 88.50 55.81 0.00 1 0.00 1 0 33 9.749e-01 7.254e-02 2.798e-01 1.804e-02 8.233582e-01 1.097275e-02 1.247695e-02 -6.000000e+00 6.228278e-01 231.87 -2.00 3.58 -2.00 321.61 0.00e+00 4.819933e-02 4.516580e-03 7.861352e-03 -6.000000e+00 2.834980e-02 281.87 -2.00 20.00 -2.00 321.07 0.00e+00 7.852 0.009 302.00 328.00 3 2.1710e+00 3.5837e-02 8.8465e-02 -6.0000e+00 1.5676e+00 1.9096e+00 4.2219e-02 4.7448e-02 -6.0000e+00 1.6922e+00 -2.2350e+00 2.9469e-02 4.4333e-02 -6.0000e+00 9.9332e-01 8.6877e-01 1.5568e-02 4.2042e-02 -6.0000e+00 4.2031e-01 8.7002e-06 7.8604e-03 5.3886e-04 7.8532e-04 -6.0000e+00 3.1999e-02 -1.8631e-02 1.5488e-03 12 8 8 10 0 0 68.09 22.68 0.28 -0.01863 0.04044 15 3 1 5 0 3300.850 26.32 20.00 22.68 26.50 37.4 1018.42 289174 352806 361405 900000 145235 900000 143254 900000 341992 900000 22954 -35467 96055 900000 182676 143743 153719 188096 296072 176815 900000 263865 95106 74654 10336 60651 17464 184456 37882 900000 -117146 900000 794 40536 900000 94830 900000 31235 43478 52414 125864 166054 6502 59890 141601 183835 900000 96611 51230 57249 109076 84610 160609 279489 64233 35981 78526 38263 18649 72650 21641 23644 43448 38073 60439 60656 17101 11786 34480 28654 78881 16202 45854 25513 900 -10164 9776 -3447 12081 -7083 26733 -4305 20 -4701 3035 10733 1559 -2956 4788 -513 7620 26788 -907 -26247 9039 692 -4819 -7962 -711 4037 -2252 -2387 -8800 -4565 -5205 -4825 -4303 7621 -1125 -1543 -6807 -3677 -4728 -800 -924 3392 -1993 425 -388 2094 2694 -1924 790 5917 -1916 2533 1595 7556 1067 3658 2134 3898 -153 1212 63 696 -1405 106 -648 -1395 -2309 -1708 9454 6778 6345 900000 11117 900000 6562 900000 6004 900000 1587 -4787 5530 900000 8094 10193 10702 9909 5747 9279 900000 4650 6258 4803 980 3288 1302 3238 2661 900000 -48496 900000 139 4791 900000 5871 900000 3370 4320 4879 6213 5841 957 5710 6843 6342 900000 7722 6282 6944 8852 8844 8808 5217 7753 5253 7412 4857 2742 6834 3444 4149 7181 7150 9524 9419 3894 2913 7484 7019 12692 4461 9093 5512 218 -2508 2013 -877 3142 -2580 8173 -1913 9 -2316 1452 4985 810 -1612 2387 -256 3324 9400 -415 -16608 4828 472 -4034 -7685 -675 3596 -1960 -1886 -6976 -3546 -4278 -4184 -3997 6993 -1259 -1945 -9813 -5361 -6961 -1110 -1253 4441 -2848 627 -600 3184 3965 -2838 1103 7658 -2587 3235 2120 10539 1791 6719 4314 8268 -354 2941 161 1823 -3793 283 -1695 -3496 -5479 -3855 SS 20220531T103803.3Z 8186.443094 64 1 49.08 2 81.45 67.61 86.82 57.69 0.00 1 0.00 1 0 17 4.668e-01 2.490e-02 1.507e-01 6.022e-03 7.701291e-01 3.533721e-03 9.214571e-03 -6.000000e+00 2.894226e-01 231.87 -2.00 3.58 -2.00 321.60 0.00e+00 1.185964e-02 1.812160e-03 3.603116e-03 -6.000000e+00 1.304950e-02 281.87 -2.00 20.00 -2.00 321.09 0.00e+00 6.336 0.005 302.00 328.00 3 2.4163e+00 1.2497e-02 7.5654e-02 -6.0000e+00 7.2483e-01 5.3561e-01 1.6644e-02 4.4454e-02 -6.0000e+00 7.8249e-01 -7.8437e-01 1.5106e-02 2.8241e-02 -6.0000e+00 4.6298e-01 3.2708e-01 7.0827e-03 1.4331e-02 -6.0000e+00 1.9507e-01 4.4884e-05 -1.6842e-03 1.8157e-04 2.4564e-04 -6.0000e+00 1.4865e-02 9.2546e-03 5.7836e-05 12 8 8 10 0 0 30.66 22.68 0.32 0.00925 -0.00340 44 9 1 5 0 1115.320 26.32 20.00 22.68 26.64 37.4 1019.04 -125120 900000 -90244 900000 -139722 900000 -139854 -114543 -146393 -105728 -160057 -162479 -87571 900000 -9967 20190 -17933 25301 29293 -16466 48024 125675 -38125 -5216 -44831 4534 -45064 -2065 23073 119860 -126891 82411 -25881 -7855 119202 -7160 42044 8191 32644 20996 64947 33754 9402 31439 62539 23743 94007 21078 51041 11657 59076 10303 43654 38273 18529 16360 31538 14906 14647 2453 19570 10263 27779 12211 20153 15980 6637 607 8633 9250 12752 2036 10598 3041 266 -3026 -3232 -942 -1815 -3073 2455 -613 -3933 -3448 -1299 1816 -41 -1384 -295 1358 -150 3245 -3908 -5319 -890 -1392 -2547 -3021 -1200 112 -2551 -1192 -2412 -1030 -4952 -1024 -2693 -121 -300 150 -537 -444 -1116 322 -734 1978 -156 658 453 1380 1412 428 1496 1943 905 1029 1134 2351 118 129 623 403 165 -97 457 -293 435 -157 -554 -540 -321 -1585 -2753 900000 -1624 900000 -3228 900000 -3337 -2196 -3704 -1944 -5165 -6554 -2329 900000 -195 340 -491 485 561 -502 805 948 -1300 -139 -1677 110 -1653 -52 487 1206 -14271 1727 -1538 -392 1849 -352 1497 448 1628 1324 2858 2141 743 2168 3234 1754 4045 1746 3556 1239 4615 1283 4460 4373 2519 2309 4028 2070 1996 383 2769 1797 4627 2599 4080 3370 1573 156 2293 2717 3840 687 3142 896 73 -791 -886 -261 -596 -1215 1066 -293 -2101 -1953 -766 1095 -26 -904 -187 806 -85 1709 -2246 -3403 -631 -1112 -2392 -3193 -1306 117 -2529 -1062 -2078 -902 -4789 -1012 -2909 -140 -374 210 -788 -678 -1708 492 -1094 2853 -238 999 719 2191 2184 671 2241 2799 1274 1413 1589 3582 201 246 1236 858 375 -228 1125 -753 1129 -410 -1417 -1309 -728 -3608 SS 20220531T105252.9Z 8186.453390 69 1 49.35 2 78.97 70.03 84.61 60.05 0.00 1 0.00 1 0 25 3.021e-01 7.547e-03 1.188e-01 2.023e-03 6.527903e-01 1.137966e-03 7.688970e-03 -6.000000e+00 1.858541e-01 231.87 -2.00 3.58 -2.00 320.84 0.00e+00 5.339441e-03 4.913653e-04 2.317909e-03 -6.000000e+00 8.057739e-03 281.87 -2.00 20.00 -2.00 320.27 0.00e+00 5.040 0.002 302.00 328.00 3 2.0028e+00 3.6493e-03 6.1206e-02 -6.0000e+00 4.6604e-01 2.6502e-02 4.8093e-03 3.7403e-02 -6.0000e+00 5.0272e-01 -4.5052e-02 4.6878e-03 2.1754e-02 -6.0000e+00 2.9833e-01 5.6373e-03 2.2756e-03 8.7033e-03 -6.0000e+00 1.2522e-01 2.7161e-04 -6.9968e-04 6.1410e-05 1.2296e-04 -6.0000e+00 9.4600e-03 8.6742e-03 6.6078e-05 11 8 0 10 0 0 -3.53 22.67 0.22 0.00867 0.00342 133 28 1 5 0 370.950 26.32 19.99 22.67 26.83 37.4 1020.02 -105675 -35781 -94013 -86746 -123653 80506 -115454 -103456 -71296 -112536 -80875 -81440 -77218 -3080 -38295 -8816 -39265 -1549 -13420 -5858 -13421 -739 -34304 -9233 -34958 -6640 -35586 -14861 -23026 2949 -53328 6401 -21807 -5552 -3158 -3752 -4015 -486 371 11 -678 1227 -2126 477 2810 1652 5292 3105 2638 1213 5165 2369 5444 3162 1614 1570 1726 -382 -654 -494 3015 2761 4205 3241 1367 2083 959 737 2349 2157 1389 -304 1510 108 -854 -1566 -919 -1717 357 -1815 -539 -1735 -2287 -1724 -450 68 494 114 503 118 785 494 -320 -270 764 353 556 93 -350 -403 -964 -1082 -174 -336 -1986 -1237 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