File name: Pandora169s1_Egbert_20220616_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T164243.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v4d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20220616_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20220616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220616T103238.8Z 8202.439338 189 1 49.57 2 81.84 65.21 83.50 221.89 0.00 1 0.00 1 0 17 5.249e-01 2.664e-02 2.186e-01 5.979e-03 7.755929e-01 3.586822e-03 9.868438e-03 -6.000000e+00 3.327979e-01 232.86 -2.00 3.58 -2.00 321.57 0.00e+00 1.718917e-02 1.859911e-03 5.157909e-03 -6.000000e+00 1.556829e-02 283.55 -2.00 20.00 -2.00 321.05 0.00e+00 6.601 0.006 302.00 328.00 3 2.2131e+00 1.2757e-02 7.8481e-02 -6.0000e+00 8.3695e-01 5.9824e-01 1.6946e-02 4.5239e-02 -6.0000e+00 9.0506e-01 -8.1106e-01 1.5314e-02 3.2488e-02 -6.0000e+00 5.2827e-01 3.4128e-01 7.1857e-03 1.9088e-02 -6.0000e+00 2.2225e-01 4.0873e-05 -1.4828e-03 1.8056e-04 3.3375e-04 -6.0000e+00 1.7024e-02 7.3821e-03 8.8467e-05 12 9 8 11 8 0 17.96 22.72 0.25 0.00738 -0.00376 33 7 1 5 0 1501.920 26.32 20.01 22.72 27.00 37.5 1003.44 900000 -147234 900000 -95189 900000 900000 900000 -119668 900000 -170820 67381 -168224 900000 -4233 900000 -44910 -38061 -49261 154681 -32994 900000 -242 22156 -91192 41317 -33147 2625 120720 24385 182935 -132873 245755 6447 4991 171037 29420 60317 68172 -3706 45738 32620 44457 -9192 30000 48248 59458 42160 58801 24749 38986 30368 29758 26398 67181 10743 37030 16011 31185 -5487 24603 2410 21857 9932 20521 8930 22273 5425 10534 5505 18459 8567 6115 6967 10457 -3417 2996 -2109 1592 2476 -12 151 1461 -3822 -984 -2787 529 -50 -2654 147 -1945 -713 2054 -584 -6253 -839 -2904 -1423 -3861 -603 -822 -1223 -2459 75 -2905 -2764 -2175 -2049 -1953 865 -1561 -443 -1430 29 -455 1226 474 410 -200 1524 1103 2975 -578 1736 2013 896 -477 2458 2583 1030 284 910 -280 -9 -223 452 -289 573 -269 -556 -523 -686 -1354 900000 -4507 900000 -1715 900000 900000 900000 -2299 900000 -5245 392 -6566 900000 -64 900000 -1393 -1233 -1891 973 -1151 900000 -6 445 -4926 691 -1063 61 966 510 1065 -15547 1430 282 222 1679 1047 1782 2137 -247 2185 1872 2420 -832 1984 2803 3241 2780 3526 2121 3194 2942 3154 3082 5752 1550 4280 2211 3686 -885 3099 398 3393 1929 3944 1962 4346 1258 2489 1510 4959 2652 1949 2119 2863 -969 747 -548 435 779 -4 65 692 -2039 -542 -1648 319 -31 -1722 92 -1184 -407 1103 -326 -3996 -585 -2382 -1316 -4023 -638 -855 -1190 -2231 64 -2609 -2609 -2152 -2158 -2229 1066 -2164 -655 -2204 44 -678 1754 680 604 -309 2410 1763 4586 -888 2545 2864 1250 -661 3385 3847 1725 526 1793 -587 -19 -515 1084 -716 1427 -675 -1373 -1242 -1552 -2969 SS 20220616T105001.7Z 8202.451408 194 1 49.38 2 78.98 68.04 85.53 225.05 0.00 1 0.00 1 0 17 2.434e-01 7.106e-03 1.006e-01 1.984e-03 6.391294e-01 1.115406e-03 7.481163e-03 -6.000000e+00 1.503024e-01 232.86 -2.00 3.58 -2.00 320.72 0.00e+00 4.437572e-03 4.677935e-04 2.028472e-03 -6.000000e+00 6.535588e-03 283.55 -2.00 20.00 -2.00 320.12 0.00e+00 5.045 0.002 302.00 328.00 3 1.9871e+00 3.5422e-03 6.0699e-02 -6.0000e+00 3.7762e-01 3.8061e-02 4.6220e-03 3.6342e-02 -6.0000e+00 4.0687e-01 -1.8758e-02 4.4246e-03 2.0396e-02 -6.0000e+00 2.4149e-01 -5.4247e-03 2.1595e-03 7.7538e-03 -6.0000e+00 1.0136e-01 2.7399e-04 -5.6293e-04 6.0255e-05 1.0824e-04 -6.0000e+00 7.6223e-03 7.3979e-03 9.9279e-05 11 9 0 11 8 0 59.93 22.74 0.17 0.00740 0.00317 122 26 1 5 0 404.720 26.32 19.99 22.74 28.14 37.5 1010.23 -39026 -104619 -1900 -56777 -74516 -12237 -42096 -120078 -78398 -127315 -55678 -83825 1661 -15068 22884 -36226 -24339 -36571 16183 -29643 22678 -22280 5788 -21666 -3640 -23883 -12949 -16150 16415 -510 -32658 1452 -5645 -15646 13932 -12893 2673 -1018 2313 -3273 3351 -38 -1765 -1891 5548 -574 4886 2328 1576 3053 4707 1654 3628 3487 -244 1936 175 -249 -2634 95 714 2775 2236 2882 1029 2518 -381 537 1192 2428 554 367 170 832 -2228 -710 -1607 -407 -1259 -508 -1216 -1464 -2603 -318 -1034 650 55 613 648 747 134 1032 -215 180 681 459 434 159 -314 -239 -1247 -1180 -93 115 -1771 -933 -1084 -217 482 466 383 -122 113 -255 279 829 666 219 403 -299 180 212 720 321 374 -946 410 791 3 -360 -338 -583 -336 45 -120 -247 280 296 -38 194 5 -321 -170 -919 -7 -339 -517 -52 -244 -1591 -822 -2179 -566 -1273 15 -191 266 -766 -518 -975 296 -840 422 -625 131 -701 -105 -819 -430 -556 431 -18 -1686 67 -291 -916 647 -780 160 -76 191 -330 350 -4 -218 -241 674 -76 638 327 225 471 798 321 756 782 -60 481 45 -64 -682 24 186 795 723 1001 371 885 -140 210 496 1115 278 187 84 382 -1013 -293 -657 -176 -600 -282 -744 -1002 -1947 -248 -829 543 48 538 558 610 108 784 -165 148 607 453 490 190 -392 -288 -1467 -1275 -96 123 -2055 -1089 -1351 -290 679 697 615 -201 183 -397 429 1252 1035 346 664 -504 296 336 1142 491 551 -1370 593 1233 4 -649 -634 -1160 -682 96 -264 -564 650 690 -88 422 10 -663 SS 20220616T110542.6Z 8202.462299 203 1 49.42 2 76.36 70.55 87.46 227.83 0.00 1 0.00 1 0 17 7.990e-02 6.113e-03 2.497e-02 1.144e-03 5.357501e-01 6.294583e-04 6.268949e-03 -6.000000e+00 4.934684e-02 232.86 -2.00 3.58 -2.00 319.86 0.00e+00 2.304086e-03 1.989598e-04 7.211256e-04 -6.000000e+00 2.145772e-03 283.55 -2.00 20.00 -2.00 319.20 0.00e+00 4.139 0.001 302.00 328.00 3 2.0383e+00 1.8316e-03 4.9786e-02 -6.0000e+00 1.2398e-01 2.5058e-02 2.1971e-03 2.9270e-02 -6.0000e+00 1.3358e-01 -1.1852e-02 1.8454e-03 1.4868e-02 -6.0000e+00 7.9286e-02 -7.3687e-03 9.4589e-04 4.9294e-03 -6.0000e+00 3.3277e-02 6.7356e-04 -4.7489e-04 3.5419e-05 5.9303e-05 -6.0000e+00 2.5026e-03 7.1621e-03 9.0389e-05 11 1 0 11 8 0 98.34 22.75 0.15 0.00716 0.00359 157 34 1 5 0 314.730 26.32 20.00 22.75 28.79 37.5 1013.40 -20691 -36390 -20176 -26398 -7087 -9279 -19890 -31628 -31843 -33721 -24544 -23384 -12822 -6965 778 -2758 -15777 -2106 1353 1971 -1747 3049 -1551 -3238 -5248 -233 -9171 -1656 -1336 1907 -11517 4945 -5393 -4123 -3713 -1063 -3200 807 -606 -730 -1511 -931 -2667 323 -143 443 869 932 -195 1270 986 1434 1887 1537 -462 1198 -242 -332 -944 432 1094 1883 2047 1337 -13 547 -150 492 1951 1110 776 448 591 331 -633 -808 -1238 -989 -606 -1419 -1085 -1554 -2057 -902 -647 220 954 498 736 645 913 86 147 190 378 199 755 216 -433 -338 -994 -1226 223 156 -1659 -1170 -843 -616 503 412 287 -35 205 23 266 634 505 392 289 -309 -260 209 268 340 445 -422 445 1128 132 -56 -462 -418 -234 58 -327 -232 258 316 -196 301 -65 -414 -252 -531 -256 -342 -79 -110 -268 -543 -604 -697 -505 -560 -318 -201 25 -105 -707 -90 59 90 -85 146 -83 -190 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