File name: Pandora169s1_Egbert_20230206_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T204823.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230206_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230206T164026.4Z 8437.694751 49 1 49.50 2 60.98 165.44 115.88 333.74 0.00 1 0.00 1 0 17 1.165e-02 6.687e-03 4.211e-03 1.119e-03 3.230944e-01 5.864009e-04 3.977145e-03 -6.000000e+00 6.973395e-03 224.23 -2.00 3.58 -2.00 317.49 0.00e+00 6.391920e-04 8.757661e-05 1.488371e-04 -6.000000e+00 2.972646e-04 271.01 -2.00 20.00 -2.00 316.99 0.00e+00 2.052 0.000 302.00 328.00 3 4.3082e+00 1.5369e-03 2.5943e-02 -6.0000e+00 1.7237e-02 4.7189e-02 1.7238e-03 1.6637e-02 -6.0000e+00 1.8724e-02 7.6756e-04 1.0740e-03 8.3512e-03 -6.0000e+00 1.1108e-02 -9.0748e-03 5.4099e-04 2.4663e-03 -6.0000e+00 4.6978e-03 6.3464e-04 -2.5869e-04 3.5498e-05 3.1513e-05 -6.0000e+00 3.6380e-04 -9.3012e-04 4.4598e-05 11 8 0 10 0 0 99.72 23.07 0.05 -0.00093 -0.00287 93 20 1 5 0 532.170 26.73 20.00 23.07 2.04 36.6 951.55 2549 -689 -2301 -2116 -1844 1215 560 -656 -1931 -4247 -4994 -1572 -486 1572 940 -830 -1479 652 731 1736 485 265 1308 1524 -1172 -545 -1653 1121 -461 1394 962 2218 -1058 -2593 -3012 -2444 -2000 -677 -658 -1238 -947 -197 -983 -383 -88 -770 -177 -406 -564 689 1080 713 1175 926 806 1329 638 205 17 565 1211 1740 1798 1274 -569 -177 -422 93 1626 641 386 318 379 372 -246 -521 -688 -698 -244 -1326 -1016 -1933 -2291 -1228 -514 -274 326 168 438 225 577 -101 176 458 764 384 620 420 -197 -365 -896 -972 128 227 -1606 -1054 -913 -671 510 446 402 276 126 103 44 513 208 305 374 -105 -190 245 368 550 714 -346 706 1205 223 74 -379 -354 -204 183 -198 -369 221 225 -155 176 -389 -621 212 -63 -211 -182 -150 97 49 -63 -203 -472 -577 -191 -67 242 163 -158 -298 135 156 379 108 60 305 373 -306 -144 -432 275 -112 344 256 631 -325 -804 -919 -765 -690 -266 -295 -615 -498 -106 -544 -212 -49 -427 -97 -222 -310 386 635 443 760 622 553 925 448 143 12 396 877 1330 1447 1056 -469 -140 -325 73 1344 572 360 301 354 334 -209 -415 -524 -535 -198 -1181 -973 -1974 -2444 -1353 -588 -326 396 206 529 263 639 -107 179 474 833 449 776 551 -264 -479 -1127 -1172 151 278 -2066 -1395 -1246 -945 742 673 622 425 189 148 61 694 285 432 548 -158 -285 363 535 776 976 -464 930 1624 316 110 -576 -549 -323 297 -333 -634 384 393 -270 300 -649 -1019 SS 20230206T164544.8Z 8437.698435 52 1 49.42 2 60.75 166.88 116.29 335.02 0.00 1 0.00 1 0 17 1.669e-02 6.820e-03 1.038e-02 2.093e-03 3.209700e-01 1.093266e-03 3.929821e-03 -6.000000e+00 9.988769e-03 224.23 -2.00 3.58 -2.00 318.19 0.00e+00 4.641763e-04 1.955193e-04 2.069576e-04 -6.000000e+00 4.257542e-04 271.01 -2.00 20.00 -2.00 317.68 0.00e+00 2.038 0.000 302.00 328.00 3 5.0085e+00 2.9032e-03 2.5791e-02 -6.0000e+00 2.4691e-02 3.1957e-02 3.2778e-03 1.6571e-02 -6.0000e+00 2.6818e-02 3.3303e-02 2.1572e-03 8.3524e-03 -6.0000e+00 1.5909e-02 -2.4791e-02 1.1118e-03 2.4736e-03 -6.0000e+00 6.7303e-03 3.1951e-04 3.7247e-05 6.7755e-05 3.1455e-05 -6.0000e+00 5.2093e-04 -1.2931e-03 9.3483e-05 11 8 0 10 0 0 99.99 23.06 0.21 -0.00129 -0.00101 211 45 1 5 0 234.190 26.73 19.99 23.06 2.23 36.6 952.79 1805 -3423 -866 1988 1663 5816 6973 -3895 3764 -6207 -2216 -1507 2180 4236 2073 799 -2736 649 902 -1161 2483 1494 1654 1359 -1276 308 -2199 4555 -63 3270 2694 2007 -787 -3397 -2001 -1692 -2346 -1261 -1118 -2375 -1546 -954 -1615 -1189 -57 -1369 -551 -731 -599 216 1204 408 969 1244 12 1088 95 -388 206 610 723 1520 2089 1163 -1024 215 -721 -155 1747 1350 535 335 408 1057 48 -2 -439 -637 481 -1492 -1107 -1582 -1983 -952 -545 68 648 177 481 152 888 343 68 806 857 102 618 140 -284 -46 -1145 -1030 -101 152 -1781 -1268 -1037 -557 545 704 544 -35 -14 57 -137 501 88 332 213 -124 -129 190 449 339 830 -729 428 1141 275 -21 -437 -441 -138 218 -162 -223 261 525 -37 -40 -193 -657 115 -240 -59 126 101 344 441 -296 288 -534 -190 -139 221 479 267 112 -419 101 145 -196 412 254 292 254 -256 62 -444 833 -12 610 545 442 -187 -826 -471 -411 -639 -396 -406 -974 -674 -430 -748 -553 -26 -637 -252 -333 -274 102 596 216 539 719 7 661 59 -239 125 373 462 1034 1506 872 -765 151 -496 -109 1304 1101 462 296 354 870 37 -1 -297 -435 351 -1222 -991 -1526 -2019 -1011 -608 79 775 215 573 174 948 345 66 790 898 117 767 185 -385 -60 -1435 -1222 -117 184 -2293 -1692 -1436 -801 816 1102 877 -57 -22 84 -192 684 123 479 323 -193 -201 290 669 488 1147 -985 567 1551 397 -32 -691 -713 -229 374 -289 -409 485 983 -70 -72 -341 -1143 SS 20230206T181821.7Z 8437.762751 114 1 49.41 2 60.64 192.50 120.21 358.93 0.00 1 0.00 1 0 17 2.282e-02 7.783e-03 9.173e-03 2.184e-03 3.137154e-01 1.141919e-03 3.852621e-03 -6.000000e+00 1.365808e-02 224.23 -2.00 3.58 -2.00 317.78 0.00e+00 7.620304e-04 1.840730e-04 2.317254e-04 -6.000000e+00 5.821875e-04 271.01 -2.00 20.00 -2.00 317.29 0.00e+00 2.031 0.000 302.00 328.00 3 5.3862e+00 3.0075e-03 2.5470e-02 -6.0000e+00 3.3761e-02 5.9634e-02 3.3827e-03 1.6160e-02 -6.0000e+00 3.6672e-02 1.2761e-02 2.1516e-03 8.1381e-03 -6.0000e+00 2.1755e-02 -1.4923e-02 1.0945e-03 2.4413e-03 -6.0000e+00 9.2017e-03 2.2137e-04 -5.1681e-05 7.0047e-05 3.0649e-05 -6.0000e+00 7.1242e-04 -9.0687e-04 7.0751e-05 11 9 0 11 8 0 99.99 23.00 0.04 -0.00091 -0.00130 68 15 1 5 0 726.570 26.62 20.00 23.00 4.98 36.8 967.88 7965 -3935 3044 -4741 2796 -2192 8062 -5432 4592 -13283 -3847 -5532 692 499 3212 -4659 -373 -1097 4856 -1260 3924 -837 2659 -216 -1010 -552 -870 4918 932 3325 3298 1505 -1326 -4039 -2411 -2316 -2125 -1869 -894 -1509 -595 41 -1101 -863 303 -829 -211 7 -1315 1011 499 397 581 1445 -11 1187 136 683 -890 809 686 1988 1906 1868 -732 617 -1370 342 1016 1220 526 868 378 956 -408 -246 -1450 -696 -854 -1606 -1102 -1768 -2306 -866 -608 74 584 204 656 212 625 202 -241 -415 546 133 1134 395 -144 -307 -925 -1578 -224 -210 -1489 -1106 -494 -351 883 703 775 295 118 -242 246 157 55 -52 303 -336 361 440 539 346 731 -1641 537 887 446 -200 -242 -422 -265 16 127 -225 450 513 -200 155 -84 -1041 572 -332 240 -377 197 -163 591 -492 409 -1431 -393 -621 84 69 485 -815 -66 -205 892 -252 757 -171 546 -48 -236 -130 -202 1038 199 717 767 384 -365 -1134 -653 -648 -660 -672 -368 -693 -289 20 -568 -448 156 -429 -107 4 -674 525 275 232 355 911 -7 783 91 451 -590 535 474 1450 1474 1486 -582 463 -1013 255 810 1050 478 799 344 829 -334 -186 -1053 -505 -665 -1381 -1027 -1767 -2424 -943 -693 87 709 251 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