File name: Pandora169s1_Egbert_20230421_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T232157.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230421_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230421T121500.3Z 8511.510420 97 1 49.92 2 71.56 91.26 79.49 75.37 0.00 1 0.00 1 0 17 1.501e-01 1.080e-02 5.099e-02 3.248e-03 4.355447e-01 1.734242e-03 5.222332e-03 -6.000000e+00 9.127563e-02 228.61 -2.00 3.58 -2.00 319.12 0.00e+00 1.878654e-03 4.214818e-04 8.686001e-04 -6.000000e+00 3.930444e-03 277.40 -2.00 20.00 -2.00 318.52 0.00e+00 3.121 0.001 302.00 328.00 3 5.1112e+00 4.7801e-03 3.8232e-02 -6.0000e+00 2.2742e-01 4.2930e-02 5.5103e-03 2.3204e-02 -6.0000e+00 2.4605e-01 -2.2715e-02 4.1673e-03 1.1868e-02 -6.0000e+00 1.4602e-01 -1.3662e-04 2.1883e-03 3.7724e-03 -6.0000e+00 6.1502e-02 8.9038e-05 -6.7330e-04 1.0275e-04 4.5937e-05 -6.0000e+00 4.6944e-03 9.1788e-04 -6.6143e-05 12 9 8 11 32 0 98.06 22.98 0.17 0.00092 -0.00414 13 3 1 5 0 3837.470 26.62 20.00 22.98 14.74 37.9 1013.75 90405 -20801 53511 -1894 52132 68206 73055 -5943 5391 -18627 62 -53319 5928 6376 15555 -18359 2187 -1029 703 -8878 17444 -787 8266 -15620 -6545 -6523 -179 30662 1882 12530 2106 9794 -8164 -7264 -3646 -492 -2476 14 -5758 -2603 666 -2374 -382 -905 1422 -436 2177 -1348 -1008 2007 297 1223 176 4908 -70 2612 1001 785 -2346 2724 -583 3250 1741 3040 -1278 1458 -1051 421 725 1691 908 1163 -746 1327 -1272 -1518 -773 -1077 374 -677 -1799 -1759 -2978 -1524 -812 668 877 176 1 458 1132 1706 -567 -992 -376 -545 502 144 -579 -461 -1238 -1823 222 635 -1163 -389 -634 -129 1005 176 296 302 454 275 398 657 -195 642 672 571 303 177 387 748 671 -3461 -371 1319 755 -509 -700 -335 -295 -3 146 -244 407 286 -140 294 -41 -621 1022 -666 903 -49 814 944 1053 -188 167 -749 2 -3491 269 340 881 -1568 167 -86 61 -872 1370 -74 756 -1890 -767 -781 -20 2516 202 1299 268 1292 -1359 -1207 -579 -79 -457 3 -1501 -741 199 -762 -124 -299 464 -146 714 -461 -352 719 116 509 79 2205 -34 1266 496 386 -1175 1327 -307 1790 1043 1879 -811 876 -636 261 487 1223 695 902 -577 963 -878 -979 -477 -682 255 -518 -1521 -1597 -2870 -1523 -847 719 971 198 1 488 1136 1620 -536 -970 -394 -623 618 189 -776 -604 -1549 -2177 258 759 -1469 -507 -860 -183 1483 274 477 486 716 417 580 941 -285 968 1050 909 482 278 592 1110 966 -4993 -523 1906 1159 -829 -1185 -580 -525 -5 277 -476 801 568 -277 565 -78 -1143 SS 20230421T122015.0Z 8511.514063 100 1 48.87 2 70.62 92.19 78.59 76.19 0.00 1 0.00 1 0 17 5.834e-02 7.602e-03 2.236e-02 2.245e-03 4.216030e-01 1.196850e-03 5.049972e-03 -6.000000e+00 3.546912e-02 228.61 -2.00 3.58 -2.00 318.92 0.00e+00 1.338198e-03 2.735584e-04 4.606526e-04 -6.000000e+00 1.527414e-03 277.40 -2.00 20.00 -2.00 318.32 0.00e+00 2.979 0.000 302.00 328.00 3 4.5526e+00 3.2790e-03 3.6653e-02 -6.0000e+00 8.8372e-02 3.2643e-02 3.7534e-03 2.2344e-02 -6.0000e+00 9.5616e-02 -1.6258e-02 2.7326e-03 1.1200e-02 -6.0000e+00 5.6743e-02 -3.1677e-03 1.4316e-03 3.3922e-03 -6.0000e+00 2.3898e-02 1.8189e-04 -6.8391e-04 7.1093e-05 4.1586e-05 -6.0000e+00 1.8243e-03 1.2941e-03 -6.3608e-05 11 8 0 10 0 0 98.59 22.98 0.11 0.00129 -0.00385 31 7 1 5 0 1576.000 26.62 20.00 22.98 14.81 37.9 1014.01 37858 -19063 27411 -5226 12797 4397 8272 -18268 -2943 -17147 -7053 -21293 3820 -1355 3288 -8951 -5029 -7021 -4122 -1695 8293 40 -903 -3909 -2428 -1719 -3896 9362 -2299 6947 3346 4225 -4196 -4448 766 -2607 -3205 884 -2212 -734 -739 -943 -1186 -547 1584 172 862 -1211 -846 1424 961 1297 -162 2253 -92 2104 450 37 -1281 1102 600 1742 1461 2274 -797 1621 -904 549 1518 1413 442 843 -774 893 -820 -424 -1131 -1341 -376 -731 -1329 -1845 -2464 -1517 -948 155 829 549 88 569 421 907 1 -99 862 -24 876 171 -427 -265 -929 -1103 -165 -31 -1150 -764 -663 -441 710 -113 578 141 143 153 195 580 125 219 381 -10 310 284 719 383 482 -2053 745 1128 410 -285 -707 -454 42 -10 -27 -258 249 421 -50 -12 -174 -463 814 -715 695 -167 336 126 250 -768 -117 -808 -321 -1226 206 -90 240 -804 -469 -707 -425 -177 805 4 -102 -482 -311 -224 -510 1057 -288 850 470 650 -744 -794 129 -471 -654 204 -611 -224 -243 -325 -420 -195 558 62 308 -444 -316 548 398 573 -77 1096 -47 1083 236 20 -672 575 330 1020 918 1477 -525 1013 -568 353 1049 1059 350 676 -618 672 -585 -281 -725 -880 -266 -574 -1145 -1709 -2409 -1542 -1005 170 931 624 99 615 431 881 0 -98 904 -28 1079 224 -572 -347 -1163 -1316 -193 -38 -1459 -1002 -902 -624 1049 -175 923 227 224 230 284 827 181 329 591 -16 490 441 1091 567 693 -2921 1037 1623 624 -459 -1181 -777 74 -18 -51 -495 483 821 -98 -23 -321 -840 SS 20230421T123101.3Z 8511.521543 103 1 19.09 2 68.69 94.10 76.74 77.88 0.00 1 0.00 1 0 17 2.892e-02 7.195e-03 1.629e-02 2.588e-03 3.879361e-01 1.376208e-03 4.672325e-03 -6.000000e+00 1.758896e-02 228.61 -2.00 3.58 -2.00 318.36 0.00e+00 1.563337e-03 2.653849e-04 2.810247e-04 -6.000000e+00 7.572360e-04 277.40 -2.00 20.00 -2.00 317.74 0.00e+00 2.726 0.000 302.00 328.00 3 4.2263e+00 3.7076e-03 3.3576e-02 -6.0000e+00 4.3824e-02 2.6945e-02 4.1901e-03 2.0471e-02 -6.0000e+00 4.7412e-02 -2.0054e-02 2.8177e-03 1.0184e-02 -6.0000e+00 2.8137e-02 9.0947e-04 1.4600e-03 3.1624e-03 -6.0000e+00 1.1853e-02 3.3480e-04 -5.4176e-04 8.1840e-05 3.7828e-05 -6.0000e+00 9.0438e-04 3.3275e-04 -3.9926e-05 12 9 1 12 1 1 98.41 23.00 0.23 0.00033 -0.00374 13 8 1 5 0 1350.920 26.62 19.99 23.00 15.08 37.9 1016.10 176 -16851 -3005 -5994 -2081 -6078 -1683 -10624 -2634 -13504 -1579 -11655 -95 -1889 3175 -6606 -3746 487 4894 1263 4528 -1015 2468 -3193 1496 -3195 -1046 3006 3155 1085 3237 3199 -458 -5748 -1070 -4372 -1030 -619 452 -1839 -543 -1167 -201 -645 882 48 733 -815 -670 550 1669 627 295 1137 -349 2009 -302 -1004 -159 1192 1206 2641 1319 1271 -393 216 -404 -332 1645 1242 10 889 777 650 -853 283 -1207 -904 -189 -1139 -1292 -1496 -2748 -902 -716 -91 586 208 351 564 335 347 108 513 483 338 441 466 -363 -646 -639 -984 -407 467 -1361 -1337 -872 -584 231 248 231 149 86 122 192 810 208 360 481 114 13 157 749 515 792 -1217 758 1051 441 -88 -395 -358 -284 62 -1 51 255 74 -318 -204 -75 -521 8 -943 -149 -289 -92 -283 -82 -619 -154 -909 -100 -896 -8 -181 331 -826 -488 65 652 180 634 -152 374 -538 253 -574 -182 488 509 187 603 653 -102 -1348 -237 -1036 -264 -184 153 -705 -220 -494 -86 -281 382 21 319 -360 -300 254 812 326 162 646 -206 1187 -183 -607 -95 713 753 1740 931 927 -287 152 -280 -237 1240 1010 9 768 662 532 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