File name: Pandora169s1_Egbert_20230523_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241104T001547.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230523_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230523T111252.7Z 8543.467277 88 1 50.44 2 76.33 74.45 100.08 36.13 0.00 1 0.00 1 0 17 3.566e-01 1.167e-02 1.906e-01 4.835e-03 6.341583e-01 2.738502e-03 7.397329e-03 -6.000000e+00 2.204952e-01 231.35 -2.00 3.58 -2.00 320.47 0.00e+00 4.705997e-03 1.050805e-03 1.057369e-03 -6.000000e+00 1.034939e-02 281.03 -2.00 20.00 -2.00 319.89 0.00e+00 4.132 0.001 302.00 328.00 3 4.4876e+00 8.3206e-03 5.3240e-02 -6.0000e+00 5.5192e-01 1.5003e-01 1.0614e-02 3.4865e-02 -6.0000e+00 5.9634e-01 -7.0571e-02 1.0091e-02 1.9105e-02 -6.0000e+00 3.5262e-01 1.3421e-02 5.0174e-03 7.6521e-03 -6.0000e+00 1.4960e-01 4.7789e-05 -1.5802e-03 1.4750e-04 9.1948e-05 -6.0000e+00 1.1473e-02 3.6788e-03 -2.2626e-04 12 8 8 10 0 0 99.96 23.02 0.81 0.00368 -0.00820 14 3 1 5 0 3601.790 26.62 19.99 23.02 16.64 26.9 940.39 900000 -122900 900000 -107370 -30415 900000 -115239 -60002 -5173 -46914 900000 -126672 -16200 25457 89566 -65586 -13242 -50584 -64 27671 146498 51923 47187 -47013 -22817 -14230 15094 900000 -21962 212237 7498 88203 -33815 -20330 9990 -7010 -1470 -5228 370 -12316 424 6787 -1848 -1870 6536 8353 12639 8998 -1024 10033 8628 4323 3641 14091 -2001 5114 5009 -3539 -5854 1427 -2564 1664 1293 5291 -585 3068 -2725 623 457 1804 1631 2521 222 -615 -2122 2393 -1574 -2137 971 -1670 -923 -2336 -2909 -2434 -2183 322 -242 -835 1397 351 -755 2812 467 -928 3097 -154 617 -65 -60 -124 -1504 -1106 -441 579 -1371 -408 -345 205 307 -359 -376 303 586 52 492 396 602 589 483 425 51 529 272 -82 -398 -971 374 1898 -256 -623 -647 -395 -462 -185 308 -237 -148 663 -424 585 -298 -73 900000 -1719 900000 -1293 -169 900000 -1643 -566 -32 -460 900000 -3511 -202 269 626 -2294 -319 -1884 -2 556 973 874 880 -2251 -925 -549 445 900000 -960 1151 333 2142 -2783 -1507 558 -482 -109 -477 38 -1620 54 869 -266 -276 915 1180 1766 1356 -179 1719 1653 945 866 3246 -557 1377 1361 -1029 -1717 398 -792 547 472 1996 -236 1183 -1119 264 215 921 882 1369 119 -313 -1009 1016 -679 -980 490 -986 -609 -1706 -2273 -1999 -1883 285 -221 -773 1249 303 -623 2156 364 -777 2780 -159 702 -80 -76 -153 -1765 -1209 -466 624 -1571 -485 -430 270 434 -548 -605 492 937 80 736 584 905 917 778 691 82 824 413 -122 -572 -1369 525 2795 -414 -1086 -1186 -751 -913 -379 654 -517 -328 1463 -927 1232 -607 -144 SS 20230523T112355.7Z 8543.474950 91 1 48.99 2 74.41 76.25 98.94 38.22 0.00 1 0.00 1 0 17 1.466e-01 7.755e-03 4.712e-02 2.239e-03 5.637723e-01 1.222768e-03 6.626384e-03 -6.000000e+00 9.001390e-02 231.35 -2.00 3.58 -2.00 319.80 0.00e+00 2.370084e-03 3.800157e-04 8.818638e-04 -6.000000e+00 3.895514e-03 281.03 -2.00 20.00 -2.00 319.18 0.00e+00 3.655 0.001 302.00 328.00 3 3.7205e+00 3.5194e-03 4.7053e-02 -6.0000e+00 2.2549e-01 8.2575e-02 4.2171e-03 3.0558e-02 -6.0000e+00 2.4334e-01 -3.5494e-02 3.5788e-03 1.5642e-02 -6.0000e+00 1.4439e-01 1.4802e-03 1.8431e-03 5.0820e-03 -6.0000e+00 6.0662e-02 1.8012e-04 -8.1164e-04 6.7830e-05 6.3408e-05 -6.0000e+00 4.5881e-03 1.9602e-03 -8.6405e-05 11 8 0 10 0 0 98.78 23.00 0.15 0.00196 -0.00414 32 7 1 5 0 1530.700 26.62 20.00 23.00 17.38 26.9 944.93 -3131 -57013 -8947 -38946 -50589 -2977 -96467 -60522 -29080 -37129 -16549 -46652 -26259 -10016 4311 -23606 -24929 440 -9045 -4450 12558 -5371 -10797 -11569 -15665 513 -4617 22492 -1682 12539 618 10030 -9089 -10578 230 -4726 -2838 -2074 -1328 -2345 -1051 360 -997 -216 3239 1856 4065 777 495 1930 2479 693 2913 2938 -581 1233 675 -385 -1051 1595 550 2442 3038 2573 309 1067 -830 809 1398 712 -926 393 786 569 -1128 -485 -1001 -1864 -375 -1114 -1300 -1664 -2201 -1346 -866 543 808 -4 801 717 188 1046 -585 4 488 119 634 256 -644 -190 -1177 -1316 -29 366 -1598 -687 -582 -408 153 332 219 332 236 -160 343 663 500 430 274 187 -85 485 499 236 318 -1364 680 1191 -45 -270 -358 -562 -118 149 -186 -269 340 238 -21 234 -224 -505 -31 -976 -104 -564 -786 -32 -2512 -1288 -514 -749 -303 -1281 -733 -294 132 -1039 -1222 19 -441 -217 539 -278 -621 -718 -1069 31 -293 1109 -106 763 48 814 -953 -1142 22 -506 -338 -291 -218 -441 -213 76 -220 -48 712 420 919 186 124 513 715 221 976 1043 -221 476 264 -151 -409 616 227 1080 1456 1309 161 542 -429 434 816 455 -631 269 524 360 -674 -269 -543 -1061 -233 -784 -1012 -1403 -1968 -1254 -843 545 832 -4 818 706 177 936 -525 3 495 132 768 330 -857 -247 -1459 -1543 -33 428 -1971 -873 -769 -565 224 514 354 542 378 -250 515 983 754 669 440 304 -137 765 770 355 465 -1970 972 1775 -72 -459 -635 -1030 -222 291 -376 -555 708 498 -43 471 -437 -966 SS 20230523T113423.0Z 8543.482210 94 1 49.14 2 72.59 77.95 97.81 40.17 0.00 1 0.00 1 0 17 7.180e-02 6.711e-03 2.156e-02 1.430e-03 5.104108e-01 7.747767e-04 6.028960e-03 -6.000000e+00 4.411249e-02 231.35 -2.00 3.58 -2.00 319.34 0.00e+00 1.919206e-03 2.072791e-04 5.611902e-04 -6.000000e+00 1.908162e-03 281.04 -2.00 20.00 -2.00 318.70 0.00e+00 3.294 0.001 302.00 328.00 3 3.3051e+00 2.1741e-03 4.2414e-02 -6.0000e+00 1.1051e-01 5.7177e-02 2.5376e-03 2.7458e-02 -6.0000e+00 1.1924e-01 -1.4114e-02 1.9995e-03 1.3809e-02 -6.0000e+00 7.0756e-02 -7.0232e-03 1.0441e-03 4.3941e-03 -6.0000e+00 2.9737e-02 4.0994e-04 -5.0139e-04 4.3883e-05 5.2513e-05 -6.0000e+00 2.2472e-03 1.1222e-03 -1.5743e-05 11 9 0 11 8 0 99.52 23.00 0.08 0.00112 -0.00265 65 14 1 5 0 755.960 26.62 20.00 23.00 18.22 26.9 950.00 -10346 -6312 -13080 -2175 -34153 12257 -48706 -18677 -8566 -22723 -31499 -10011 -11750 1761 662 1498 -13928 3531 -2865 4644 -5232 5178 -3635 469 -9402 -556 -7151 10525 -5024 5692 -730 3798 -5294 -4536 -2418 -2344 -3472 -466 -817 -1766 -434 -612 -1036 -768 153 -830 212 227 -690 788 1900 600 1923 1377 739 1210 292 -581 -609 123 1911 1714 2760 1505 -67 -166 105 533 1844 801 1035 412 241 132 -396 -472 -710 -1379 23 -1247 -935 -1917 -2151 -1181 -664 -20 679 207 838 415 335 294 77 314 648 215 488 326 -492 -278 -983 -961 277 109 -1414 -1107 -1053 -521 309 260 87 32 164 291 168 688 361 646 188 -230 -150 470 375 504 699 -794 502 1341 201 -61 -523 -518 -164 173 -222 -289 151 289 -193 214 -278 -331 -179 -115 -256 -38 -744 186 -1344 -444 -203 -642 -1028 -309 -440 70 31 78 -906 211 -192 303 -380 352 -282 38 -870 -49 -662 818 -456 509 -78 440 -719 -620 -322 -326 -551 -85 -175 -429 -113 -167 -293 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