File name: Pandora169s1_Egbert_20230525_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241105T133534.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230525_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230525T102030.8Z 8545.430912 66 1 47.54 2 84.91 65.54 113.73 4.30 0.00 1 0.00 1 0 17 4.315e-01 7.664e-02 1.900e-01 3.261e-02 1.125294e+00 1.992562e-02 1.280917e-02 -6.000000e+00 2.672505e-01 231.48 -2.00 3.58 -2.00 320.98 0.00e+00 -9.984988e-03 4.349811e-03 2.391327e-03 -6.000000e+00 1.197254e-02 281.24 -2.00 20.00 -2.00 320.14 0.00e+00 9.696 0.018 302.00 328.00 3 5.1118e-01 5.6729e-02 1.1345e-01 -6.0000e+00 6.6928e-01 2.9250e+00 6.5496e-02 6.5416e-02 -6.0000e+00 7.2334e-01 -2.4935e+00 3.7581e-02 2.8236e-02 -6.0000e+00 4.2923e-01 7.3090e-01 1.9607e-02 1.1780e-02 -6.0000e+00 1.8130e-01 4.6675e-06 1.9088e-03 8.3403e-04 1.7708e-04 -6.0000e+00 1.3806e-02 1.0367e-02 -4.9812e-04 12 9 8 11 32 0 3.39 23.01 1.10 0.01037 0.02471 12 3 1 5 0 3958.510 26.62 19.99 23.01 7.87 26.0 902.74 162142 52264 900000 42592 -34377 71535 -22981 95641 34959 16508 45963 -49432 42988 115404 90844 604 25224 36528 114581 10937 900000 24123 65288 -24607 -8236 1672 76078 900000 25374 900000 27505 139102 -69860 -11453 900000 16372 30489 -13627 -2394 900000 40657 -8107 18613 -12981 900000 58366 100516 73327 -20604 37405 45497 -3920 68015 205000 11427 39987 45260 7630 -37954 34796 -41824 -44512 -445 44383 7015 33041 -4877 -10863 -2596 40017 44985 50868 15680 11042 1165 53119 -14793 -51203 -3859 -3711 13645 16421 39 7197 -11677 34205 14004 -2878 16709 8931 -14417 59581 11012 -18609 53542 -2157 3470 -2400 1 3387 202 -12721 -11592 -1183 -10618 5762 5728 16899 293 -3299 -7200 8935 2237 6616 564 1076 -910 -536 -1164 5622 309 -4132 -5719 725 -10414 6006 3523 10435 691 -6422 2319 -545 -5504 918 3508 1004 -593 368 -4609 713 1062 4894 9791 8174 900000 5073 -7388 5495 -4425 6116 3975 2233 4966 -14546 6036 9056 9669 154 5076 6358 8878 2056 900000 3568 6754 -6066 -1704 290 5757 900000 2823 900000 3749 7017 -25188 -2220 900000 2295 4121 -3184 -566 900000 6951 -2112 3537 -3062 900000 6366 7310 7119 -5101 5823 7116 -1038 9682 8181 2909 7750 7927 1735 -11988 5309 -13427 -15949 -116 8040 1813 6764 -1488 -3816 -929 10243 11075 11312 4384 2826 287 7480 -4030 -21939 -1251 -1399 4980 6409 19 3370 -6701 13071 6438 -1503 6893 3702 -7053 14636 4558 -11573 19994 -1573 2741 -2178 1 2805 155 -9885 -8515 -808 -8262 4059 4371 13041 304 -4025 -10030 11254 3028 8471 751 1434 -1276 -776 -1715 7554 413 -5463 -7426 863 -13425 6647 4273 13669 1154 -13022 4798 -1258 -14336 2418 9486 2844 -1715 1045 -13104 1805 2489 10658 SS 20230525T103223.8Z 8545.439164 69 1 49.76 2 82.96 67.52 113.55 7.18 0.00 1 0.00 1 0 17 5.759e-01 2.698e-02 2.696e-01 7.358e-03 1.112780e+00 4.648198e-03 1.240849e-02 -6.000000e+00 3.570480e-01 231.48 -2.00 3.58 -2.00 322.31 0.00e+00 7.422274e-03 2.790867e-03 3.109899e-03 -6.000000e+00 1.736582e-02 281.24 -2.00 20.00 -2.00 321.89 0.00e+00 7.493 0.008 302.00 328.00 3 1.1447e+00 1.8686e-02 9.8125e-02 -6.0000e+00 8.9930e-01 1.3502e+00 2.5835e-02 6.6906e-02 -6.0000e+00 9.7462e-01 -1.7746e+00 2.3019e-02 3.6971e-02 -6.0000e+00 5.7530e-01 7.1065e-01 1.0434e-02 1.3953e-02 -6.0000e+00 2.4374e-01 3.3244e-05 -2.2991e-03 1.9941e-04 2.5897e-04 -6.0000e+00 1.8537e-02 4.3945e-03 -1.7077e-04 12 9 8 11 8 0 -8.35 22.97 0.31 0.00439 -0.01288 54 12 1 5 0 921.250 26.62 19.99 22.97 7.90 26.1 903.50 900000 -99841 900000 -133472 79908 17097 -92989 -178788 900000 -172676 900000 -164394 900000 -30600 900000 -70205 -33389 -511 900000 13432 192929 130344 65699 -89939 -19772 -476 80086 900000 42593 900000 70509 139473 -10619 -726 900000 76173 42430 62133 40363 40046 65997 105227 76462 119424 101602 53970 123687 84129 53819 82983 58784 95869 61313 155601 14420 84191 56113 38012 -1003 119218 -3083 40167 20949 39707 12559 59319 19081 29546 14066 37521 29910 21470 12484 25802 5163 20167 5177 -5033 1107 4533 5823 5832 -1722 5335 -2941 6538 3161 -4220 262 -1005 110 6842 -2027 -8666 1965 -1906 -2219 -4788 -4139 -1443 -1681 -6260 -1765 -5169 -4838 -2204 -1270 -1788 -1460 -2029 -1274 -1958 -390 -1318 -39 287 920 232 1869 1934 3050 2386 4358 1584 2624 -4942 2861 2136 1524 -912 844 -49 -347 -118 585 -292 486 506 -252 -173 -808 -2085 900000 -2683 900000 -4035 572 122 -1555 -6576 900000 -6059 900000 -6996 900000 -618 900000 -2756 -1017 -12 900000 266 1381 933 712 -4129 -478 -9 695 900000 550 900000 1027 1235 -410 -25 900000 1243 1027 1434 1300 1430 1980 2269 2159 2250 2249 1872 2356 2459 2239 2932 2866 3685 3452 3980 1337 4280 3591 2726 -96 3879 -311 3097 2170 3857 1625 5238 2521 3879 2360 5611 4993 3834 2277 3799 819 2616 780 -929 230 1091 1612 1816 -621 1912 -1189 2525 1288 -1837 107 -396 41 2373 -804 -4136 1008 -1203 -1640 -4063 -3684 -1232 -1328 -4646 -1180 -3602 -3522 -1656 -1022 -1609 -1503 -2404 -1673 -2756 -555 -1881 -54 400 1315 346 2827 2889 4323 3236 5618 2038 3268 -6502 3661 3083 2550 -1769 1776 -111 -849 -307 1579 -814 1356 1403 -683 -442 -1929 -4764 SS 20230525T104323.1Z 8545.446795 72 1 49.23 2 81.13 69.33 113.30 9.82 0.00 1 0.00 1 0 17 9.114e-01 1.199e-02 2.421e-01 2.881e-03 9.753678e-01 1.708858e-03 1.110390e-02 -6.000000e+00 5.597908e-01 231.48 -2.00 3.58 -2.00 321.82 0.00e+00 7.142579e-03 9.786481e-04 4.326806e-03 -6.000000e+00 2.448541e-02 281.24 -2.00 20.00 -2.00 321.36 0.00e+00 6.135 0.004 302.00 328.00 3 1.1594e+00 6.4719e-03 8.3306e-02 -6.0000e+00 1.4027e+00 2.6463e-01 1.0360e-02 6.0894e-02 -6.0000e+00 1.5136e+00 -3.2350e-01 1.1461e-02 3.7282e-02 -6.0000e+00 8.9819e-01 1.2410e-01 5.1161e-03 1.4676e-02 -6.0000e+00 3.7744e-01 1.5509e-04 -1.0542e-03 7.7324e-05 2.4773e-04 -6.0000e+00 2.8884e-02 3.7525e-03 -1.2699e-04 12 8 8 10 0 0 -15.78 22.95 0.26 0.00375 -0.00417 131 28 1 5 0 375.720 26.51 20.00 22.95 8.20 26.1 905.20 -173814 -308746 -277162 -285640 -323972 -204160 -381055 -289105 -258634 -291354 -238333 -262490 -14115 -134027 -131595 -116245 -183070 -68106 1524 -91251 -73644 -1035 -84070 -111719 -135852 -67846 -99126 900000 -47394 106112 -10130 44392 -46237 -31099 7267 -16345 -11465 -16028 -3084 -6490 11967 6234 9607 9186 14583 468 19174 17153 11981 13861 15383 13937 13253 16614 6080 8182 11461 723 2376 8083 3514 5031 9707 9682 8763 9183 6092 2596 6231 6816 4279 2074 3567 1106 -496 598 -3418 -2973 2506 -230 1502 -316 -2150 -1121 -929 212 811 -1118 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