File name: Pandora169s1_Egbert_20230616_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241107T083325.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230616_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230616T114737.2Z 8567.491403 139 1 49.29 2 69.14 77.24 54.09 91.17 0.00 1 0.00 1 0 25 4.613e-02 7.383e-03 1.511e-02 1.733e-03 4.331270e-01 9.380220e-04 5.171747e-03 -6.000000e+00 2.851244e-02 232.86 -2.00 3.58 -2.00 318.78 0.00e+00 1.018320e-03 2.081741e-04 5.142432e-04 -6.000000e+00 1.238834e-03 283.55 -2.00 20.00 -2.00 318.06 0.00e+00 2.781 0.000 302.00 328.00 3 4.2704e+00 2.5860e-03 3.6017e-02 -6.0000e+00 7.1637e-02 3.5348e-02 2.9534e-03 2.3410e-02 -6.0000e+00 7.7163e-02 -2.0657e-02 2.0730e-03 1.1477e-02 -6.0000e+00 4.5799e-02 -1.2645e-03 1.0759e-03 3.2330e-03 -6.0000e+00 1.9245e-02 2.8203e-04 -7.1562e-04 5.4313e-05 3.9329e-05 -6.0000e+00 1.4445e-03 -3.2618e-03 -6.5831e-05 11 8 0 10 0 0 98.99 22.95 0.26 -0.00326 -0.00864 36 8 1 5 0 1368.950 26.51 20.00 22.95 19.86 28.6 962.79 2639 -14730 -6711 -10777 -17918 -11786 -18114 -24054 -1483 -16255 -14382 -15782 -954 -314 -2174 -5861 -6222 -3505 1275 702 5765 1091 2321 -4304 -4607 -5012 -595 6156 -118 2039 2990 2715 -492 -6177 111 -3755 -1032 -2308 -222 -2736 390 -926 -235 -1114 949 -892 484 -668 254 463 2082 1010 1664 1874 325 1586 625 -109 -8 732 1411 1891 2058 1759 -388 465 -339 614 1294 838 493 562 333 1163 -778 -23 -1328 -716 -436 -881 -1596 -1753 -2636 -1035 -1167 -136 493 406 80 750 538 658 -169 291 476 223 619 105 -893 -288 -1164 -1215 -348 376 -1555 -819 -976 -539 336 502 358 171 220 152 269 686 572 303 336 103 4 179 528 415 900 -1141 693 1226 417 -78 -264 -437 -128 81 -97 -188 194 198 -173 -40 -58 -817 74 -535 -227 -358 -607 -383 -690 -1095 -59 -788 -724 -910 -56 -21 -170 -532 -613 -359 131 75 600 122 269 -571 -648 -726 -81 759 -15 277 451 459 -87 -1169 19 -712 -217 -585 -62 -895 134 -340 -88 -428 360 -346 185 -261 101 184 883 469 824 931 171 845 340 -59 -4 393 797 1162 1313 1183 -264 300 -216 403 934 645 407 473 274 894 -583 -15 -866 -475 -320 -709 -1398 -1622 -2634 -1082 -1254 -153 553 462 90 822 570 648 -162 288 498 254 757 136 -1202 -373 -1462 -1470 -408 457 -1975 -1089 -1324 -774 497 773 562 271 345 232 387 991 816 455 515 164 6 275 807 607 1295 -1609 951 1760 634 -125 -433 -746 -219 146 -180 -353 371 382 -329 -76 -105 -1479 SS 20230616T134252.7Z 8567.571443 222 1 39.23 2 48.63 96.91 34.36 115.30 0.00 1 0.00 1 0 17 1.134e-02 7.526e-03 3.596e-03 1.564e-03 2.419604e-01 8.510299e-04 2.947985e-03 -6.000000e+00 7.014315e-03 232.86 -2.00 3.58 -2.00 316.52 0.00e+00 3.516826e-04 9.988114e-05 1.172716e-04 -6.000000e+00 3.046006e-04 283.56 -2.00 20.00 -2.00 315.80 0.00e+00 1.510 0.000 302.00 328.00 3 5.2444e+00 2.2369e-03 1.9744e-02 -6.0000e+00 1.7624e-02 3.9405e-02 2.4829e-03 1.2894e-02 -6.0000e+00 1.8978e-02 -3.1542e-03 1.4411e-03 6.2516e-03 -6.0000e+00 1.1264e-02 -6.3070e-03 6.6947e-04 1.7141e-03 -6.0000e+00 4.7378e-03 4.6990e-04 1.0587e-04 5.0038e-05 2.3164e-05 -6.0000e+00 3.5490e-04 -5.9819e-03 6.5293e-05 12 9 1 12 9 1 99.99 23.07 0.03 -0.00598 -0.00519 51 14 1 5 0 751.050 26.73 19.99 23.07 23.18 28.8 981.29 2548 -1144 -1324 -2527 -1427 31 1360 -1079 35 -3578 -2367 -2137 452 356 1300 -1786 -46 -236 2014 674 1037 -151 1455 10 968 -684 -898 737 612 1845 1866 1846 333 -4779 -2158 -3047 -1215 -438 -136 -1779 -670 -506 -389 -891 369 -689 -254 -888 -492 561 1478 490 1093 1193 527 1585 658 12 177 742 1303 1945 1680 1385 -814 -172 -753 433 1262 1128 251 514 439 495 -234 -83 -1251 -310 -342 -917 -1804 -1858 -2714 -985 -1086 -352 124 67 194 378 337 94 -4 828 591 518 417 264 -492 -460 -1058 -801 86 459 -1363 -777 -867 -786 313 440 541 208 298 167 435 568 276 375 220 -166 -1 273 396 461 810 -531 635 1185 407 235 -143 -417 -15 145 -111 -396 418 87 -268 -111 -276 -884 407 -198 -226 -408 -214 5 213 -190 7 -703 -467 -445 102 90 356 -532 -14 -74 641 222 344 -51 499 4 360 -260 -335 259 208 625 665 697 132 -1958 -845 -1233 -532 -217 -76 -1106 -436 -338 -264 -607 249 -464 -168 -580 -319 367 1000 349 805 905 409 1240 520 9 139 586 1061 1659 1501 1262 -735 -147 -623 360 1107 1060 248 515 435 474 -213 -70 -1013 -248 -288 -837 -1779 -1935 -2959 -1105 -1273 -428 154 85 241 454 383 101 -4 855 641 598 514 341 -648 -593 -1310 -952 101 555 -1741 -1021 -1175 -1096 449 650 814 311 431 231 573 732 361 506 309 -241 -1 393 558 632 1072 -688 805 1525 547 327 -204 -607 -23 220 -175 -638 680 142 -440 -179 -436 -1381 SS 20230616T135224.5Z 8567.578061 225 1 49.33 2 46.94 98.78 32.85 118.01 0.00 1 0.00 1 0 17 1.038e-02 7.297e-03 4.847e-04 2.674e-04 2.336476e-01 1.464113e-04 2.857894e-03 -6.000000e+00 6.423499e-03 232.86 -2.00 3.58 -2.00 315.83 0.00e+00 4.726406e-04 1.468574e-05 5.695669e-05 -6.000000e+00 2.789454e-04 283.56 -2.00 20.00 -2.00 315.15 0.00e+00 1.462 0.000 302.00 328.00 3 2.2747e+00 3.8170e-04 1.9080e-02 -6.0000e+00 1.6139e-02 1.6516e-02 4.2232e-04 1.2436e-02 -6.0000e+00 1.7379e-02 -9.2711e-03 2.4184e-04 6.0268e-03 -6.0000e+00 1.0315e-02 -1.4574e-03 1.0853e-04 1.6665e-03 -6.0000e+00 4.3387e-03 9.8432e-03 1.9427e-05 8.4898e-06 2.3562e-05 -6.0000e+00 3.2501e-04 -5.8107e-03 7.1203e-05 11 9 0 11 8 0 99.90 23.07 0.16 -0.00581 -0.00566 557 119 1 5 0 88.550 26.62 19.99 23.07 23.51 28.8 983.09 -182 -618 -2009 -3688 -2897 -1200 -131 585 -876 -2948 -2910 -1027 -694 170 384 -407 221 993 982 1401 564 986 1690 1308 1286 608 -782 -437 380 1344 1837 2091 863 -2740 -2612 -1790 -1559 -303 -135 -915 -960 -564 -596 -635 -43 -512 -563 -394 -487 652 1043 755 1115 790 629 1238 585 198 340 659 1345 1632 1615 904 -654 -427 -368 314 1593 525 73 170 238 463 -154 -194 -521 -481 -13 -1061 -1466 -1981 -2411 -1199 -934 -526 25 -12 155 202 434 -58 154 899 562 298 550 246 -503 -487 -747 -883 183 321 -1325 -1129 -801 -737 223 441 407 89 260 187 389 717 527 416 386 -199 -233 264 418 579 939 176 803 1356 495 253 -208 -361 -107 256 -261 -367 69 70 -318 -137 -429 -861 -40 -144 -466 -859 -620 -251 -29 143 -218 -765 -763 -280 -211 54 136 -155 87 400 384 559 229 401 703 572 585 282 -356 -187 164 577 782 948 413 -1343 -1237 -866 -796 -170 -84 -614 -689 -418 -450 -481 -32 -381 -409 -279 -341 462 775 570 880 650 508 1011 483 162 289 541 1150 1430 1507 869 -616 -388 -317 272 1422 501 75 171 245 451 -144 -172 -448 -410 -11 -996 -1468 -2076 -2590 -1349 -1080 -643 31 -14 190 242 495 -63 163 952 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