File name: Pandora169s1_Egbert_20230729_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241107T185359.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230729_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230729 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230729T185536.2Z 8610.788613 382 1 1.30 2 31.74 223.55 125.45 96.37 0.00 1 0.00 1 0 17 9.590e-03 7.605e-03 2.872e-03 2.163e-03 1.625161e-01 1.198467e-03 2.024481e-03 -6.000000e+00 5.927984e-03 232.53 -2.00 3.58 -2.00 314.46 0.00e+00 3.147391e-04 9.245282e-05 2.246736e-05 -6.000000e+00 2.608378e-04 286.50 -2.00 20.00 -2.00 313.86 0.00e+00 1.175 0.000 302.00 328.00 3 2.9388e+00 3.0812e-03 1.4442e-02 -6.0000e+00 1.4867e-02 2.6294e-02 3.3847e-03 8.6878e-03 -6.0000e+00 1.6002e-02 -4.5981e-03 1.9391e-03 4.2135e-03 -6.0000e+00 9.5174e-03 -3.6327e-03 8.3646e-04 1.1626e-03 -6.0000e+00 4.0206e-03 7.6678e-03 -6.0315e-04 6.8362e-05 1.8530e-05 -6.0000e+00 3.0016e-04 -1.3009e-02 -8.1874e-05 12 9 1 12 1 1 71.18 23.00 0.23 -0.01301 -0.01754 5 57 1 5 0 186.530 26.62 19.99 23.00 24.48 31.5 964.36 598 -890 -689 -3996 -2023 -379 1484 2027 122 -1876 -2282 -334 405 312 759 -431 197 824 405 863 720 802 1542 1265 222 337 -532 -424 540 1323 2120 1950 465 -2635 -2239 -1329 -1208 -46 212 -1219 -996 -447 -464 -902 -294 -745 -526 -1076 -84 379 810 1067 1012 840 428 808 763 477 41 730 999 1388 1497 454 -618 -270 -383 291 1422 399 -64 201 188 367 -145 248 -468 -30 316 -717 -1114 -2243 -2307 -1003 -966 -750 -303 214 182 184 347 43 -54 1061 609 160 825 152 -298 -416 -449 -898 -200 223 -1520 -953 -827 -851 326 579 511 108 295 29 476 801 635 356 232 -412 -141 286 299 722 998 348 960 1462 511 -39 -271 -276 -208 136 -130 -437 -78 275 -337 -275 -271 -996 238 -372 -280 -1537 -743 -135 552 776 51 -808 -981 -146 181 155 388 -234 109 463 222 481 404 450 877 750 138 210 -323 -240 301 722 1188 1150 273 -1567 -1341 -765 -772 -32 158 -987 -823 -379 -399 -780 -251 -628 -445 -883 -67 302 670 925 880 756 379 722 684 426 37 652 930 1321 1502 451 -616 -256 -354 267 1336 401 -66 213 197 381 -145 231 -421 -26 279 -678 -1120 -2374 -2493 -1131 -1126 -897 -365 261 226 217 402 47 -56 1093 642 179 968 186 -375 -507 -529 -1038 -228 257 -1845 -1210 -1062 -1102 437 784 706 147 390 36 589 948 762 438 296 -540 -188 373 390 924 1249 416 1146 1765 632 -49 -353 -355 -274 181 -181 -621 -114 392 -482 -396 -379 -1369 SS 20230729T190302.5Z 8610.793779 388 1 6.83 2 32.68 226.34 124.20 97.51 0.00 1 0.00 1 0 17 9.717e-03 7.773e-03 1.787e-03 1.306e-03 1.642167e-01 7.214398e-04 2.040155e-03 -6.000000e+00 6.009126e-03 232.53 -2.00 3.58 -2.00 314.62 0.00e+00 4.190293e-04 5.756423e-05 1.926847e-05 -6.000000e+00 2.643666e-04 286.50 -2.00 20.00 -2.00 314.01 0.00e+00 1.187 0.000 302.00 328.00 3 3.7798e+00 1.8579e-03 1.4596e-02 -6.0000e+00 1.5070e-02 3.6256e-02 2.0418e-03 8.7902e-03 -6.0000e+00 1.6218e-02 -5.9688e-03 1.1687e-03 4.2520e-03 -6.0000e+00 9.6459e-03 -2.0090e-03 5.0665e-04 1.1845e-03 -6.0000e+00 4.0768e-03 3.2439e-03 3.4908e-05 4.1263e-05 1.8648e-05 -6.0000e+00 3.0401e-04 -1.2627e-02 7.8392e-05 12 9 1 12 1 1 99.94 22.98 0.18 -0.01263 -0.01236 22 37 1 5 0 289.570 26.62 20.00 22.98 25.36 31.3 968.20 443 -148 -1187 -2735 -2528 -494 -9 1473 -67 -1974 -2064 -203 -142 311 40 -291 -137 1110 1026 1340 85 792 1717 1387 845 915 -841 -192 335 1751 2032 2215 884 -2534 -2521 -1317 -1958 -421 -118 -1051 -1130 -591 -696 -723 -397 -575 -969 -611 -659 556 1224 711 902 616 835 1448 509 203 415 837 1332 1592 1469 1009 -563 -642 -468 25 1313 699 -84 232 167 644 136 -279 -410 -530 69 -1098 -1490 -1971 -2479 -1220 -892 -567 42 -181 145 14 526 -76 161 1061 643 160 704 258 -456 -388 -515 -827 266 123 -1196 -1171 -771 -715 386 541 405 383 332 94 268 530 460 430 370 -202 -153 238 184 286 1130 18 793 1583 655 233 -186 -268 -135 282 -109 -642 -72 171 -314 -95 -363 -956 166 -58 -458 -982 -878 -165 -3 534 -26 -802 -833 -83 -60 146 19 -150 -72 591 559 743 48 443 973 780 494 538 -486 -108 177 902 1080 1236 517 -1504 -1436 -757 -1198 -283 -88 -846 -932 -501 -599 -622 -339 -482 -789 -498 -524 441 1005 592 783 554 734 1282 457 181 366 744 1230 1505 1470 1031 -559 -609 -431 23 1230 698 -87 246 175 664 135 -260 -367 -462 61 -1038 -1499 -2072 -2673 -1374 -1034 -674 52 -227 179 17 604 -83 168 1087 675 177 824 314 -571 -470 -604 -949 299 146 -1485 -1480 -982 -947 514 749 557 532 449 121 330 625 550 542 483 -270 -208 318 238 364 1398 22 938 1891 802 300 -240 -353 -182 381 -150 -931 -104 248 -457 -135 -516 -1335 SS 20230729T190627.4Z 8610.796150 391 1 3.90 2 33.13 227.58 123.62 98.04 0.00 1 0.00 1 0 17 9.812e-03 7.710e-03 5.786e-04 4.196e-04 1.634197e-01 2.317463e-04 2.025394e-03 -6.000000e+00 6.069034e-03 232.53 -2.00 3.58 -2.00 314.66 0.00e+00 3.306671e-04 1.860389e-05 2.327562e-05 -6.000000e+00 2.669828e-04 286.50 -2.00 20.00 -2.00 314.04 0.00e+00 1.193 0.000 302.00 328.00 3 9.6098e-01 5.9722e-04 1.4605e-02 -6.0000e+00 1.5221e-02 1.0149e-02 6.5695e-04 8.7276e-03 -6.0000e+00 1.6379e-02 -3.5854e-03 3.7611e-04 4.2238e-03 -6.0000e+00 9.7414e-03 -2.7871e-03 1.6259e-04 1.1677e-03 -6.0000e+00 4.1180e-03 5.4634e-02 8.4151e-05 1.3324e-05 1.8358e-05 -6.0000e+00 3.0694e-04 -1.3393e-02 9.9725e-05 12 9 1 12 1 1 99.98 22.98 0.22 -0.01339 -0.01276 213 618 1 5 0 16.920 26.62 20.01 22.98 25.76 31.3 971.53 576 -639 -1442 -3440 -1957 -1029 743 1142 -3 -2212 -2233 -521 -245 201 541 -502 218 980 1090 1183 581 855 1678 1290 1336 860 -501 -378 521 1365 1844 2081 1119 -2635 -2562 -1673 -1679 -349 -192 -970 -1056 -763 -680 -736 -115 -590 -735 -470 -574 617 1065 651 1041 848 521 1299 565 208 286 605 1139 1580 1496 891 -672 -534 -418 212 1514 608 -72 156 228 524 -145 -163 -511 -302 60 -959 -1459 -2070 -2534 -1229 -904 -551 -46 5 112 150 388 -63 152 1041 572 245 650 288 -409 -457 -727 -916 202 341 -1199 -1088 -756 -765 235 494 475 141 338 209 446 683 509 405 412 -224 -293 173 372 561 970 329 806 1426 532 296 -143 -450 -50 173 -195 -414 -37 62 -366 -102 -439 -872 213 -248 -550 -1227 -675 -345 261 410 -1 -892 -895 -213 -102 92 271 -252 111 508 578 640 318 467 928 745 798 491 -297 -209 270 734 962 1139 639 -1536 -1433 -948 -997 -239 -138 -783 -868 -646 -584 -632 -98 -494 -597 -386 -460 492 883 543 903 762 457 1147 505 185 252 538 1052 1482 1485 905 -664 -507 -371 196 1417 605 -74 164 236 540 -139 -147 -445 -256 54 -911 -1466 -2166 -2816 -1369 -1032 -667 -55 6 137 180 444 -69 160 1074 601 270 782 359 -505 -568 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