File name: Pandora169s1_Egbert_20230818_L2Fit_fwvt1c12d20201119p1-8.txt File generation date: 20230824T092105.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v12d20201119.txt Level 1 file used: Pandora169s1_Egbert_20230818_L1_smca1c12d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB data based on session 9 First and last pixel inside fitting window: 1648 1797 Nominal wavelengths inside fitting window [nm]: 492.1123 492.2333 492.3542 492.4751 492.5960 492.7169 492.8378 492.9587 493.0795 493.2003 493.3212 493.4420 493.5627 493.6835 493.8042 493.9250 494.0457 494.1664 494.2871 494.4077 494.5284 494.6490 494.7696 494.8902 495.0108 495.1313 495.2519 495.3724 495.4929 495.6134 495.7339 495.8543 495.9748 496.0952 496.2156 496.3360 496.4564 496.5767 496.6971 496.8174 496.9377 497.0580 497.1783 497.2985 497.4188 497.5390 497.6592 497.7794 497.8996 498.0197 498.1399 498.2600 498.3801 498.5002 498.6202 498.7403 498.8603 498.9804 499.1004 499.2203 499.3403 499.4603 499.5802 499.7001 499.8200 499.9399 500.0598 500.1796 500.2995 500.4193 500.5391 500.6589 500.7786 500.8984 501.0181 501.1378 501.2575 501.3772 501.4969 501.6165 501.7361 501.8558 501.9753 502.0949 502.2145 502.3340 502.4536 502.5731 502.6926 502.8120 502.9315 503.0509 503.1704 503.2898 503.4092 503.5285 503.6479 503.7672 503.8866 504.0059 504.1252 504.2444 504.3637 504.4829 504.6021 504.7213 504.8405 504.9597 505.0789 505.1980 505.3171 505.4362 505.5553 505.6744 505.7934 505.9124 506.0315 506.1505 506.2694 506.3884 506.5073 506.6263 506.7452 506.8641 506.9830 507.1018 507.2207 507.3395 507.4583 507.5771 507.6959 507.8146 507.9334 508.0521 508.1708 508.2895 508.4082 508.5268 508.6454 508.7641 508.8827 509.0012 509.1198 509.2384 509.3569 509.4754 509.5939 509.7124 509.8309 509.9493 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230818T104050.7Z 8630.445031 45 1 49.37 2 88.27 73.32 107.66 60.43 0.00 1 0.00 1 0 22 5.772e-03 5.686e-03 2.134e-04 2.129e-04 2.147722e+04 1.656240e+01 1.232782e+03 -6.000000e+00 3.370550e+02 286.61 -2.00 20.00 -2.00 505.38 0.00e+00 1.953321e-03 6.109279e-06 1.711814e-04 -6.000000e+00 1.661697e-04 286.61 -2.00 20.00 -2.00 500.79 0.00e+00 1.490603e+00 4.291046e-03 1.508961e-01 -6.000000e+00 1.180009e-01 231.64 -2.00 3.58 -2.00 502.33 0.00e+00 16.694 0.091 489.00 513.00 1 2.6711e+00 3.2779e-04 2.9557e-02 -6.0000e+00 9.0483e-03 -3.4167e-02 8.3581e-05 3.7164e-03 -6.0000e+00 2.3664e-03 1.1273e-02 -1.2697e-02 2.0241e-05 1.1678e-04 -6.0000e+00 6.5650e-04 1.9339e-02 -9.6635e-04 12 8 8 10 0 0 99.81 23.03 2.42 0.01934 -0.06873 269 57 1 4 0 183.510 26.62 20.00 23.03 18.83 31.8 935.01 900000 -1085 -758 -110 338 628 900 1202 1299 1135 859 475 194 -164 -420 -568 -615 -430 -31 396 379 214 248 370 466 658 652 494 307 -117 -739 -1067 -926 -605 26 428 155 -168 -244 -256 -485 -339 -165 13 186 414 469 405 190 -35 -391 -842 -1196 -1291 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299 204 180 134 -277 -501 -612 -645 -481 -167 -199 -92 208 296 307 351 423 453 396 212 -134 -572 SQ 20230818T104656.9Z 8630.449270 50 1 21.21 2 87.22 74.37 106.75 61.63 0.00 1 0.00 1 0 22 4.554e-03 4.508e-03 1.345e-04 1.343e-04 1.733520e+04 1.016180e+01 1.058552e+03 -6.000000e+00 2.659617e+02 286.61 -2.00 20.00 -2.00 505.33 0.00e+00 1.560886e-03 3.847353e-06 1.275669e-04 -6.000000e+00 1.312870e-04 286.61 -2.00 20.00 -2.00 500.63 0.00e+00 1.328820e+00 2.720094e-03 1.164620e-01 -6.000000e+00 9.333484e-02 231.64 -2.00 3.58 -2.00 502.19 0.00e+00 14.009 0.054 489.00 513.00 1 1.3048e+00 2.0799e-04 2.3248e-02 -6.0000e+00 7.1521e-03 -1.8720e-02 5.3319e-05 2.9350e-03 -6.0000e+00 1.8779e-03 6.5660e-02 -7.5663e-03 1.3216e-05 1.0103e-04 -6.0000e+00 5.1790e-04 5.0302e-03 -1.1265e-03 12 9 1 12 1 1 5.10 23.03 1.61 0.00503 -0.04745 456 126 1 4 0 45.800 26.62 19.99 23.03 19.02 31.7 935.40 900000 -856 -498 -69 323 442 648 931 1036 870 692 372 159 -126 -365 -467 -467 -333 34 385 321 119 163 293 363 537 533 375 234 -61 -619 -830 -654 -415 91 403 129 -166 -180 -241 -395 -312 -134 -26 121 302 346 277 124 -41 -364 -710 -981 -1100 -1023 -617 -161 17 67 105 193 302 541 608 586 595 436 193 80 -50 -258 -411 -381 -311 -112 61 -79 -460 -658 -631 -600 -613 -580 -607 -485 -337 -226 -286 -255 -170 -32 112 396 626 729 559 420 274 84 -108 -477 -928 -1017 -798 -397 -176 -302 -445 -463 -436 -193 -22 7 131 327 471 619 849 951 723 482 307 160 120 276 412 274 239 153 85 181 191 -130 -335 -399 -467 -342 -99 -167 -186 70 214 228 313 320 344 310 208 -84 -400 900000 -796 -466 -65 312 432 638 917 1032 871 691 368 158 -124 -357 -455 -455 -329 34 382 324 121 164 296 368 546 544 382 237 -62 -616 -825 -647 -409 92 411 132 -170 -183 -243 -403 -319 -135 -26 124 309 356 284 126 -42 -366 -709 -977 -1082 -1007 -607 -162 17 68 107 197 309 553 624 601 608 442 197 80 -50 -254 -409 -379 -306 -111 61 -79 -457 -654 -619 -583 -595 -565 -595 -480 -332 -224 -286 -255 -169 -31 111 394 625 726 547 406 260 79 -101 -439 -855 -935 -746 -381 -174 -302 -444 -461 -432 -191 -22 7 133 328 474 625 866 966 741 494 315 161 120 278 415 274 240 154 86 182 191 -129 -336 -397 -466 -340 -101 -170 -190 72 221 238 330 335 359 328 218 -87 -410 SQ 20230818T105003.8Z 8630.451433 53 1 11.54 2 86.68 74.91 106.28 62.24 0.00 1 0.00 1 0 22 4.205e-03 4.164e-03 1.275e-04 1.274e-04 1.574501e+04 9.539918e+00 9.723295e+02 -6.000000e+00 2.456113e+02 286.61 -2.00 20.00 -2.00 505.32 0.00e+00 1.451917e-03 3.643206e-06 1.176209e-04 -6.000000e+00 1.212452e-04 286.61 -2.00 20.00 -2.00 500.60 0.00e+00 1.267113e+00 2.583337e-03 1.057565e-01 -6.000000e+00 8.619819e-02 231.64 -2.00 3.58 -2.00 502.17 0.00e+00 12.788 0.041 489.00 513.00 1 7.7483e-01 1.9756e-04 2.0868e-02 -6.0000e+00 6.6051e-03 -1.6192e-02 5.0701e-05 2.6633e-03 -6.0000e+00 1.7345e-03 1.3327e-01 -7.2619e-03 1.2705e-05 9.5906e-05 -6.0000e+00 4.7822e-04 -5.3601e-03 -1.0754e-03 11 8 0 10 0 0 0.27 23.03 1.46 -0.00536 -0.05573 539 115 1 4 0 21.200 26.62 20.00 23.03 19.09 31.7 936.01 900000 -762 -451 -19 321 450 648 885 975 820 641 342 162 -87 -302 -395 -407 -304 39 336 277 77 165 269 340 505 493 343 263 -60 -569 -768 -622 -428 67 344 89 -179 -173 -235 -365 -256 -117 -42 82 250 252 232 103 -51 -319 -671 -933 -1021 -949 -587 -173 -45 -30 21 153 264 496 555 549 561 397 223 95 -21 -227 -344 -337 -302 -112 61 -102 -435 -604 -512 -538 -548 -550 -559 -456 -285 -214 -295 -230 -137 -40 146 341 627 682 528 393 256 55 -115 -444 -863 -952 -743 -368 -186 -304 -429 -442 -354 -205 -3 -20 111 284 440 548 783 859 671 384 243 116 122 295 405 244 188 141 92 171 193 -119 -299 -356 -405 -274 -83 -153 -171 109 183 237 264 305 311 315 205 -41 -320 900000 -721 -421 -18 310 439 637 885 970 820 638 344 161 -85 -294 -390 -396 -299 39 337 279 78 169 275 349 520 500 348 269 -61 -572 -758 -612 -427 67 348 92 -185 -178 -240 -369 -259 -119 -43 84 257 261 240 106 -52 -322 -674 -919 -1008 -938 -580 -172 -46 -31 22 157 271 508 571 565 575 404 224 96 -20 -224 -337 -335 -298 -111 61 -102 -432 -592 -503 -524 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