File name: Pandora169s1_Egbert_20231018_L2Fit_fout2c17d20230819p1-8.txt File generation date: 20241107T225954.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v17d20230819.txt Level 1 file used: Pandora169s1_Egbert_20231018_L1_smca1c17d20230819p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20231018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1181 305.2589 305.3997 305.5404 305.6812 305.8220 305.9627 306.1035 306.2442 306.3849 306.5256 306.6663 306.8070 306.9477 307.0883 307.2290 307.3696 307.5102 307.6509 307.7915 307.9321 308.0727 308.2132 308.3538 308.4944 308.6349 308.7754 308.9160 309.0565 309.1970 309.3375 309.4780 309.6184 309.7589 309.8993 310.0398 310.1802 310.3206 310.4610 310.6014 310.7418 310.8822 311.0226 311.1629 311.3032 311.4436 311.5839 311.7242 311.8645 312.0048 312.1451 312.2853 312.4256 312.5658 312.7061 312.8463 312.9865 313.1267 313.2669 313.4071 313.5473 313.6874 313.8276 313.9677 314.1078 314.2479 314.3880 314.5281 314.6682 314.8083 314.9483 315.0884 315.2284 315.3685 315.5085 315.6485 315.7885 315.9285 316.0684 316.2084 316.3483 316.4883 316.6282 316.7681 316.9080 317.0479 317.1878 317.3277 317.4676 317.6074 317.7472 317.8871 318.0269 318.1667 318.3065 318.4463 318.5861 318.7258 318.8656 319.0053 319.1450 319.2848 319.4245 319.5642 319.7039 319.8435 319.9832 320.1228 320.2625 320.4021 320.5417 320.6813 320.8209 320.9605 321.1001 321.2397 321.3792 321.5187 321.6583 321.7978 321.9373 322.0768 322.2163 322.3558 322.4952 322.6347 322.7741 322.9135 323.0530 323.1924 323.3318 323.4711 323.6105 323.7499 323.8892 324.0286 324.1679 324.3072 324.4465 324.5858 324.7251 324.8643 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231018T153247.9Z 8691.647776 184 1 19.91 2 57.76 153.05 94.81 122.98 0.00 1 0.00 1 0 25 1.112e-02 7.226e-03 1.084e-03 5.038e-04 2.426951e-01 2.670918e-04 3.017648e-03 -6.000000e+00 6.701239e-03 225.03 -2.00 3.58 -2.00 316.32 0.00e+00 5.671006e-04 3.053476e-05 9.505456e-05 -6.000000e+00 2.946079e-04 280.01 -2.00 20.00 -2.00 315.69 0.00e+00 1.868 0.000 302.00 328.00 3 1.8449e+00 6.8890e-04 2.2023e-02 -6.0000e+00 1.6545e-02 3.1271e-02 7.6791e-04 1.2557e-02 -6.0000e+00 1.7909e-02 -7.1594e-03 4.4742e-04 6.2258e-03 -6.0000e+00 1.0674e-02 -3.6787e-03 2.1048e-04 1.8062e-03 -6.0000e+00 4.5659e-03 1.0236e-02 2.0983e-04 1.6042e-05 2.4589e-05 -6.0000e+00 3.4691e-04 -5.6247e-03 1.1765e-04 12 9 1 12 1 1 99.99 23.02 0.17 -0.00562 -0.00405 328 175 1 5 0 60.500 26.62 20.00 23.02 17.23 32.7 950.48 840 -1378 -1838 -4558 -3148 -2215 404 177 -148 -3358 -3148 -1824 -92 -40 871 -539 260 839 1203 1110 392 435 1706 1046 1133 583 -804 -966 -324 763 1834 1853 1274 -2650 -3131 -1799 -1649 -351 192 -692 -1087 -522 -614 -663 -15 -282 -671 -373 -722 509 1215 781 1057 993 500 1305 660 212 150 581 1143 1830 1805 1316 -516 -553 -403 67 1468 935 92 414 153 518 -46 -338 -678 -788 -232 -943 -1509 -1819 -2441 -1350 -787 -595 77 132 321 178 328 -59 -146 704 564 290 704 382 -271 -472 -696 -1116 -31 374 -1060 -1288 -736 -898 142 520 564 195 370 214 293 485 539 338 440 -174 -139 207 471 536 987 162 488 1183 576 197 -112 -525 -207 143 -239 -323 -1 223 -220 -51 -306 -888 147 -261 -346 -819 -514 -377 67 33 -29 -712 -673 -407 -23 -11 253 -171 85 283 418 396 142 159 631 386 436 229 -313 -377 -120 280 703 720 523 -1128 -1292 -746 -757 -176 108 -441 -713 -355 -427 -464 -11 -194 -453 -245 -471 334 834 572 776 761 395 1042 534 171 120 465 951 1552 1637 1187 -462 -481 -346 57 1282 870 93 410 150 503 -43 -289 -560 -639 -199 -869 -1488 -1879 -2699 -1502 -895 -718 93 163 390 214 378 -65 -150 746 612 333 858 488 -359 -610 -874 -1316 -37 444 -1364 -1691 -972 -1243 198 764 830 286 534 298 390 619 695 458 613 -248 -200 293 666 725 1310 215 625 1537 770 271 -161 -776 -303 218 -373 -508 -2 364 -359 -81 -488 -1379 SS 20231018T153651.4Z 8691.650595 187 1 51.28 2 57.44 154.18 94.23 123.65 0.00 1 0.00 1 0 17 1.155e-02 7.415e-03 2.407e-04 1.252e-04 2.397114e-01 6.664743e-05 3.003553e-03 -6.000000e+00 6.955547e-03 225.03 -2.00 3.58 -2.00 316.02 0.00e+00 5.472737e-04 7.095571e-06 7.500324e-05 -6.000000e+00 3.059547e-04 280.01 -2.00 20.00 -2.00 315.42 0.00e+00 1.851 0.000 302.00 328.00 3 9.7495e-02 1.7140e-04 2.1821e-02 -6.0000e+00 1.7173e-02 1.5303e-02 1.9077e-04 1.2438e-02 -6.0000e+00 1.8592e-02 -9.3314e-03 1.1030e-04 6.1618e-03 -6.0000e+00 1.1081e-02 -1.6999e-03 5.0969e-05 1.7761e-03 -6.0000e+00 4.7374e-03 6.0476e-02 -4.3151e-04 3.9701e-06 2.5207e-05 -6.0000e+00 3.6036e-04 -4.4519e-03 -1.4321e-07 11 8 0 10 0 0 91.69 23.02 0.23 -0.00445 -0.00769 2816 601 1 5 0 17.520 26.62 20.00 23.02 17.62 32.8 953.47 280 -892 -2106 -4808 -3874 -2075 -472 465 -789 -3179 -3679 -1494 -463 144 727 -205 266 1183 1169 1469 575 760 1755 1386 1276 659 -899 -1090 -171 975 1856 2043 1338 -2505 -3148 -1936 -1664 -218 313 -555 -894 -477 -497 -694 -5 -362 -628 -445 -554 530 1211 818 1107 980 561 1298 630 113 160 518 1193 1739 1718 1188 -542 -656 -424 15 1576 844 74 263 195 518 -134 -367 -635 -755 -114 -921 -1479 -1864 -2507 -1444 -925 -589 -8 13 217 141 380 -15 -61 748 551 241 564 423 -297 -461 -702 -1026 -2 386 -1179 -1231 -776 -833 171 497 509 203 354 230 329 610 518 359 429 -161 -196 268 504 572 999 307 557 1350 556 222 -146 -474 -224 133 -244 -389 -60 163 -283 -113 -302 -890 59 -201 -475 -1034 -761 -395 -95 102 -189 -746 -877 -368 -126 44 231 -71 95 435 444 571 228 302 709 590 531 281 -379 -464 -69 389 776 857 594 -1150 -1404 -870 -827 -118 187 -357 -622 -344 -348 -489 -4 -264 -450 -311 -382 369 882 603 858 792 446 1041 513 91 128 418 998 1482 1567 1125 -509 -573 -367 13 1381 787 74 261 200 505 -126 -330 -528 -616 -99 -853 -1463 -1931 -2668 -1609 -1054 -710 -9 16 263 170 439 -17 -63 798 600 278 689 539 -379 -595 -851 -1213 -3 460 -1468 -1619 -1027 -1115 238 706 749 298 511 320 441 780 670 470 599 -229 -283 380 692 778 1335 394 719 1700 748 306 -203 -680 -330 197 -370 -614 -95 260 -450 -181 -468 -1345 SS 20231018T154214.4Z 8691.654333 190 1 51.36 2 57.03 155.68 93.47 124.53 0.00 1 0.00 1 0 17 1.148e-02 7.468e-03 2.335e-04 1.233e-04 2.370843e-01 6.555278e-05 2.967842e-03 -6.000000e+00 6.914973e-03 225.03 -2.00 3.58 -2.00 315.98 0.00e+00 5.349402e-04 6.918888e-06 7.232613e-05 -6.000000e+00 3.041950e-04 280.01 -2.00 20.00 -2.00 315.38 0.00e+00 1.831 0.000 302.00 328.00 3 9.1137e-02 1.6848e-04 2.1576e-02 -6.0000e+00 1.7073e-02 1.5313e-02 1.8748e-04 1.2289e-02 -6.0000e+00 1.8485e-02 -9.2580e-03 1.0838e-04 6.0869e-03 -6.0000e+00 1.1017e-02 -1.5908e-03 4.9967e-05 1.7519e-03 -6.0000e+00 4.7095e-03 6.2314e-02 -5.6308e-04 3.9075e-06 2.4747e-05 -6.0000e+00 3.5832e-04 -4.2636e-03 -2.4244e-05 11 8 0 10 0 0 49.79 23.02 0.22 -0.00426 -0.00849 2897 619 1 5 0 17.030 26.62 20.00 23.02 18.38 32.9 957.10 311 -777 -2221 -4694 -3760 -2104 -442 430 -731 -3183 -3646 -1483 -472 82 776 -214 250 1097 1158 1456 600 810 1733 1427 1370 600 -897 -1046 -149 958 1875 1978 1352 -2540 -3150 -1913 -1624 -189 324 -562 -908 -491 -520 -681 -16 -394 -628 -418 -558 555 1239 863 1098 965 574 1273 649 127 193 524 1211 1718 1727 1200 -560 -645 -438 -1 1543 861 105 262 219 511 -144 -389 -656 -747 -118 -913 -1441 -1874 -2507 -1413 -933 -579 -5 21 230 160 389 -11 -47 741 569 247 542 427 -310 -422 -691 -1024 8 405 -1196 -1243 -773 -834 174 517 505 193 339 238 344 619 510 362 447 -137 -188 262 494 590 1014 309 544 1323 560 195 -137 -471 -224 147 -251 -397 -44 143 -270 -106 -300 -901 67 -179 -513 -1030 -753 -409 -90 96 -179 -762 -885 -372 -131 26 251 -75 91 410 446 574 241 326 710 615 578 259 -383 -451 -61 387 792 838 605 -1176 -1416 -866 -813 -103 194 -364 -636 -357 -366 -483 -11 -290 -453 -293 -387 388 905 639 853 782 457 1024 529 103 155 424 1016 1469 1577 1138 -526 -564 -378 -1 1351 802 106 260 224 497 -137 -350 -545 -640 -102 -844 -1422 -1938 -2772 -1570 -1060 -697 -6 25 279 192 448 -12 -48 788 617 284 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