File name: Pandora169s1_Egbert_20231107_L2Fit_fout2c17d20230819p1-8.txt File generation date: 20241107T231643.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v17d20230819.txt Level 1 file used: Pandora169s1_Egbert_20231107_L1_smca1c17d20230819p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20231107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1181 305.2589 305.3997 305.5404 305.6812 305.8220 305.9627 306.1035 306.2442 306.3849 306.5256 306.6663 306.8070 306.9477 307.0883 307.2290 307.3696 307.5102 307.6509 307.7915 307.9321 308.0727 308.2132 308.3538 308.4944 308.6349 308.7754 308.9160 309.0565 309.1970 309.3375 309.4780 309.6184 309.7589 309.8993 310.0398 310.1802 310.3206 310.4610 310.6014 310.7418 310.8822 311.0226 311.1629 311.3032 311.4436 311.5839 311.7242 311.8645 312.0048 312.1451 312.2853 312.4256 312.5658 312.7061 312.8463 312.9865 313.1267 313.2669 313.4071 313.5473 313.6874 313.8276 313.9677 314.1078 314.2479 314.3880 314.5281 314.6682 314.8083 314.9483 315.0884 315.2284 315.3685 315.5085 315.6485 315.7885 315.9285 316.0684 316.2084 316.3483 316.4883 316.6282 316.7681 316.9080 317.0479 317.1878 317.3277 317.4676 317.6074 317.7472 317.8871 318.0269 318.1667 318.3065 318.4463 318.5861 318.7258 318.8656 319.0053 319.1450 319.2848 319.4245 319.5642 319.7039 319.8435 319.9832 320.1228 320.2625 320.4021 320.5417 320.6813 320.8209 320.9605 321.1001 321.2397 321.3792 321.5187 321.6583 321.7978 321.9373 322.0768 322.2163 322.3558 322.4952 322.6347 322.7741 322.9135 323.0530 323.1924 323.3318 323.4711 323.6105 323.7499 323.8892 324.0286 324.1679 324.3072 324.4465 324.5858 324.7251 324.8643 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231107T171925.7Z 8711.721826 417 1 25.66 2 60.70 184.57 64.03 258.75 0.00 1 0.00 1 0 17 1.230e-02 7.024e-03 4.452e-03 1.548e-03 2.826295e-01 8.129953e-04 3.505972e-03 -6.000000e+00 7.357954e-03 223.16 -2.00 3.58 -2.00 316.99 0.00e+00 1.313867e-03 1.094380e-04 8.728428e-05 -6.000000e+00 3.223835e-04 277.42 -2.00 20.00 -2.00 316.40 0.00e+00 2.034 0.000 302.00 328.00 3 4.0581e+00 2.1102e-03 2.4467e-02 -6.0000e+00 1.8107e-02 3.3457e-02 2.3624e-03 1.4572e-02 -6.0000e+00 1.9634e-02 -4.6430e-03 1.4173e-03 7.2858e-03 -6.0000e+00 1.1700e-02 -4.8254e-03 6.9521e-04 2.3247e-03 -6.0000e+00 5.0120e-03 8.8860e-04 1.0757e-04 4.9291e-05 2.9040e-05 -6.0000e+00 3.8345e-04 -5.9545e-03 8.4703e-05 12 9 1 12 1 1 99.99 22.98 0.10 -0.00595 -0.00515 36 15 1 5 0 693.330 26.62 20.00 22.98 10.02 32.5 925.65 2988 -775 -1054 -3804 -4211 426 -130 -1344 -433 -3504 -5604 -2595 -855 1524 -820 -913 -1118 565 1676 1587 529 388 940 1598 -306 248 -1106 -318 -807 2195 860 2153 147 -2550 -3166 -1615 -1641 -1425 174 -799 -1035 -63 -434 -797 378 -460 -443 -668 -316 35 1553 385 1448 951 332 1035 687 630 -103 643 799 1697 1746 1461 -694 -163 -271 -215 1514 1461 400 459 133 399 65 -409 -683 -629 7 -987 -1524 -1756 -2529 -1326 -697 -603 324 43 413 138 496 -74 -38 309 612 191 460 434 -122 -271 -877 -1197 -16 477 -1212 -1202 -690 -727 131 475 433 43 240 305 230 711 251 360 306 -154 -221 205 453 470 945 -205 413 1494 535 299 -134 -338 -219 69 -268 -324 87 285 -270 -76 -235 -809 347 -99 -135 -470 -489 47 -15 -176 -60 -519 -863 -414 -151 299 -183 -219 -282 146 444 432 147 109 269 475 -96 79 -349 -96 -238 639 269 712 52 -922 -1123 -576 -637 -627 86 -438 -602 -38 -265 -491 231 -283 -269 -403 -189 21 978 256 997 679 243 765 513 468 -76 477 612 1361 1472 1268 -603 -136 -217 -174 1279 1322 382 446 129 373 58 -342 -542 -495 6 -884 -1472 -1799 -2712 -1465 -799 -719 395 54 505 164 562 -80 -40 321 662 221 567 561 -161 -354 -1104 -1447 -18 577 -1543 -1581 -933 -1012 189 705 658 66 356 433 313 943 336 496 438 -227 -328 301 652 659 1284 -273 540 1971 738 429 -198 -509 -335 109 -435 -538 146 484 -459 -128 -385 -1306 SS 20231107T173621.8Z 8711.733586 426 1 13.26 2 61.06 189.20 67.00 261.81 0.00 1 0.00 1 0 17 1.356e-02 7.195e-03 4.426e-03 1.702e-03 2.853318e-01 8.955341e-04 3.543987e-03 -6.000000e+00 8.109850e-03 223.16 -2.00 3.58 -2.00 316.76 0.00e+00 1.164033e-03 1.137050e-04 7.380783e-05 -6.000000e+00 3.553359e-04 277.42 -2.00 20.00 -2.00 316.17 0.00e+00 2.057 0.000 302.00 328.00 3 3.6250e+00 2.3160e-03 2.4719e-02 -6.0000e+00 1.9957e-02 3.2786e-02 2.5893e-03 1.4683e-02 -6.0000e+00 2.1641e-02 -8.3382e-03 1.5367e-03 7.3342e-03 -6.0000e+00 1.2896e-02 -2.7307e-03 7.4461e-04 2.2841e-03 -6.0000e+00 5.5241e-03 1.3376e-03 3.8497e-05 5.3916e-05 2.9297e-05 -6.0000e+00 4.2265e-04 -5.9110e-03 7.9868e-05 12 9 1 12 1 1 99.84 22.97 0.16 -0.00591 -0.00562 17 14 1 5 0 736.240 26.51 19.99 22.97 10.89 32.5 930.66 -801 -1097 -2710 -3764 -6840 -1102 -944 -7 -2321 -3993 -6395 -1934 -471 113 741 -742 -890 1175 925 2439 589 904 1222 865 708 670 -784 -380 -412 2020 1628 2887 637 -2767 -3125 -1678 -1121 54 -54 -580 -1152 -645 -291 -823 -117 -719 52 -357 -782 419 914 685 1496 1059 830 1580 553 8 405 -59 1320 1715 1674 1256 -500 -525 -134 -430 1591 699 60 51 406 244 211 -530 -554 -920 -36 -781 -981 -2022 -2410 -1618 -620 -344 68 -268 373 229 718 166 41 659 784 396 531 197 -378 -376 -750 -1110 -214 383 -1048 -1310 -783 -919 64 701 525 193 319 275 273 576 310 382 244 19 -173 295 317 564 835 -2 554 1326 533 73 -151 -402 -248 176 -120 -367 18 180 -210 114 -461 -827 -108 -156 -391 -519 -911 -139 -125 -1 -370 -661 -1105 -343 -92 25 181 -195 -247 330 270 722 179 276 379 280 240 229 -269 -125 -132 641 550 1033 242 -1075 -1192 -644 -465 25 -28 -332 -704 -403 -185 -527 -75 -461 33 -223 -489 265 599 472 1063 776 622 1199 423 6 307 -46 1037 1410 1434 1106 -443 -447 -110 -356 1366 644 58 50 396 232 191 -451 -452 -745 -30 -711 -953 -2089 -2604 -1799 -713 -408 83 -330 455 272 813 180 43 690 852 458 654 254 -498 -488 -943 -1340 -254 463 -1325 -1719 -1053 -1268 91 1027 787 290 468 388 370 761 412 522 346 27 -255 427 453 783 1128 -3 721 1747 731 104 -221 -601 -374 272 -191 -602 30 301 -350 187 -742 -1316 SS 20231107T174619.9Z 8711.740508 429 1 10.20 2 61.39 191.90 68.75 263.57 0.00 1 0.00 1 0 17 1.283e-02 7.396e-03 7.881e-03 2.839e-03 2.873962e-01 1.494525e-03 3.569117e-03 -6.000000e+00 7.671781e-03 223.16 -2.00 3.58 -2.00 316.89 0.00e+00 8.402642e-04 1.955762e-04 1.419755e-04 -6.000000e+00 3.362284e-04 277.42 -2.00 20.00 -2.00 316.29 0.00e+00 2.079 0.000 302.00 328.00 3 4.2458e+00 3.8725e-03 2.4943e-02 -6.0000e+00 1.8879e-02 2.5011e-02 4.3323e-03 1.4751e-02 -6.0000e+00 2.0473e-02 -1.2234e-03 2.5862e-03 7.3869e-03 -6.0000e+00 1.2201e-02 -6.0038e-03 1.2623e-03 2.2067e-03 -6.0000e+00 5.2247e-03 7.0445e-04 -4.7125e-05 9.0111e-05 2.8725e-05 -6.0000e+00 3.9997e-04 -5.1114e-03 3.2909e-05 12 9 1 12 1 1 99.77 22.96 0.07 -0.00511 -0.00547 6 7 1 5 0 1455.270 26.51 20.00 22.96 11.30 32.4 931.80 476 -1150 -1016 -814 -5154 -449 297 2846 -3269 -1775 -6082 -2067 -1870 -1221 -2400 -1933 -209 27 903 1515 -352 500 1619 1031 908 -954 -1594 25 102 2847 1658 2052 -112 -3805 -1236 -2363 -1729 204 -40 -920 -889 -729 228 -464 495 -571 -958 -571 -287 483 2055 999 1010 1246 945 860 1484 218 115 93 1257 1396 2167 1177 -769 -283 -128 49 1384 899 531 633 -147 360 -175 -643 -480 -1226 43 -536 -1124 -1974 -2724 -1259 -635 -427 -388 108 345 -40 426 274 -404 696 8 355 352 294 -284 -400 -1005 -576 -371 428 -1312 -1207 -618 -558 207 418 275 508 368 -22 536 503 81 391 218 241 8 26 522 830 1268 -325 503 1205 478 365 -113 -546 -149 396 -93 -618 -5 426 -527 30 -397 -895 58 -152 -134 -101 -624 -52 36 375 -489 -271 -985 -344 -349 -256 -565 -486 -54 7 250 428 -102 145 480 320 293 -318 -527 8 31 861 537 707 -41 -1440 -449 -881 -697 92 -20 -517 -529 -447 141 -291 308 -357 -595 -351 -176 300 1316 675 709 902 699 647 1118 165 87 71 974 1135 1838 1031 -674 -238 -104 40 1184 824 509 618 -143 339 -157 -545 -387 -986 36 -484 -1092 -2036 -2935 -1393 -729 -508 -473 132 421 -48 483 296 -422 725 9 411 434 380 -375 -521 -1264 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