File name: Pandora169s1_Egbert_20240208_L2Fit_fout2c17d20230819p1-8.txt File generation date: 20241106T162813.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v17d20230819.txt Level 1 file used: Pandora169s1_Egbert_20240208_L1_smca1c17d20230819p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20240208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1181 305.2589 305.3997 305.5404 305.6812 305.8220 305.9627 306.1035 306.2442 306.3849 306.5256 306.6663 306.8070 306.9477 307.0883 307.2290 307.3696 307.5102 307.6509 307.7915 307.9321 308.0727 308.2132 308.3538 308.4944 308.6349 308.7754 308.9160 309.0565 309.1970 309.3375 309.4780 309.6184 309.7589 309.8993 310.0398 310.1802 310.3206 310.4610 310.6014 310.7418 310.8822 311.0226 311.1629 311.3032 311.4436 311.5839 311.7242 311.8645 312.0048 312.1451 312.2853 312.4256 312.5658 312.7061 312.8463 312.9865 313.1267 313.2669 313.4071 313.5473 313.6874 313.8276 313.9677 314.1078 314.2479 314.3880 314.5281 314.6682 314.8083 314.9483 315.0884 315.2284 315.3685 315.5085 315.6485 315.7885 315.9285 316.0684 316.2084 316.3483 316.4883 316.6282 316.7681 316.9080 317.0479 317.1878 317.3277 317.4676 317.6074 317.7472 317.8871 318.0269 318.1667 318.3065 318.4463 318.5861 318.7258 318.8656 319.0053 319.1450 319.2848 319.4245 319.5642 319.7039 319.8435 319.9832 320.1228 320.2625 320.4021 320.5417 320.6813 320.8209 320.9605 321.1001 321.2397 321.3792 321.5187 321.6583 321.7978 321.9373 322.0768 322.2163 322.3558 322.4952 322.6347 322.7741 322.9135 323.0530 323.1924 323.3318 323.4711 323.6105 323.7499 323.8892 324.0286 324.1679 324.3072 324.4465 324.5858 324.7251 324.8643 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240208T130524.3Z 8804.545420 53 1 50.54 2 84.86 116.83 83.08 137.17 0.00 1 0.00 1 0 25 8.089e-01 6.105e-02 3.628e-01 2.380e-02 1.015663e+00 1.463875e-02 1.200210e-02 -6.000000e+00 4.942682e-01 224.30 -2.00 3.58 -2.00 322.13 0.00e+00 -1.338026e-02 4.983078e-03 1.121906e-02 -6.000000e+00 2.153960e-02 271.01 -2.00 20.00 -2.00 321.66 0.00e+00 9.646 0.017 302.00 328.00 3 6.8708e-01 4.5972e-02 1.2796e-01 -6.0000e+00 1.2256e+00 1.8824e+00 5.3990e-02 1.0987e-01 -6.0000e+00 1.3345e+00 -2.4288e+00 3.6916e-02 3.9655e-02 -6.0000e+00 7.8261e-01 9.4938e-01 2.0688e-02 1.1614e-02 -6.0000e+00 3.3239e-01 8.8791e-06 -1.2151e-03 6.9186e-04 1.3400e-04 -6.0000e+00 2.6784e-02 3.2711e-03 -3.2025e-04 12 8 8 10 0 0 10.91 23.11 0.97 0.00327 -0.00586 23 5 1 5 0 2197.180 26.73 19.99 23.11 6.18 33.5 968.51 900000 14132 274976 106540 900000 189163 900000 -12722 270211 -32051 78925 -49548 75748 374417 900000 7605 33597 31454 128998 31184 89377 63631 42799 -13371 -20988 829 47845 900000 900000 900000 75779 900000 -73433 -11576 237389 -27399 162182 318664 10260 21517 31331 240196 34221 54604 87193 152506 121475 111491 -4891 108194 31583 106943 71520 900000 -22782 115111 66447 179323 -44715 8214 -10575 96409 -12610 45221 -288 900000 -24035 5736 18304 88741 -114 23274 11906 4604 -26296 9466 -22642 -31684 14804 -4579 15236 464 523 3603 -6124 16292 16720 -609 7309 -3175 29907 38599 276 -18749 34072 -1998 5881 -10598 -621 -3631 -5655 -13380 -2623 -14438 5742 5514 2628 7903 9902 -8151 -1125 -2965 2449 2390 2513 2315 -229 1331 2567 8503 7289 -217 6249 2517 2810 -25288 2435 6548 1434 -1182 2316 -1274 -2446 -1688 1530 -797 1383 -472 -765 -486 1614 1566 900000 1994 6369 4309 900000 4381 900000 -1341 6259 -4059 3495 -7860 3997 8672 900000 904 3095 2849 4280 2431 3625 3147 2654 -1490 -2549 78 2549 900000 900000 900000 2913 900000 -13022 -1094 5498 -2720 3756 7381 1020 2129 2952 5563 2953 3600 3912 3532 3642 3744 -524 4229 2818 5031 5062 900000 -4308 6050 5466 4658 -9014 950 -1468 5239 -2129 4810 -48 900000 -5228 1023 3235 8909 -27 4485 2404 899 -6079 1434 -4581 -7577 2675 -1169 3755 148 181 1285 -2507 5648 5903 -252 2727 -1242 8213 9634 103 -9290 12119 -1162 3683 -8643 -488 -2893 -4262 -9833 -1648 -10294 3585 3659 1933 6146 8658 -9656 -1401 -4024 3249 3157 3264 3005 -314 1873 3699 11587 9693 -295 7781 3168 3448 -39583 3059 8832 2345 -2261 4759 -2933 -6118 -4495 4188 -2301 3966 -1374 -2168 -1297 3925 3596 SS 20240208T143243.1Z 8804.606054 89 1 49.78 2 72.10 133.99 74.42 154.45 0.00 1 0.00 1 0 17 7.459e-02 8.045e-03 3.495e-02 2.715e-03 4.559308e-01 1.431435e-03 5.472934e-03 -6.000000e+00 4.477143e-02 224.30 -2.00 3.58 -2.00 319.05 0.00e+00 1.436277e-03 3.391923e-04 4.413208e-04 -6.000000e+00 1.904636e-03 271.01 -2.00 20.00 -2.00 318.58 0.00e+00 3.211 0.001 302.00 328.00 3 4.4130e+00 3.8916e-03 3.9003e-02 -6.0000e+00 1.1070e-01 6.2331e-02 4.4783e-03 2.3697e-02 -6.0000e+00 1.2011e-01 -1.5715e-02 3.4967e-03 1.2229e-02 -6.0000e+00 7.1238e-02 -4.5781e-03 1.8641e-03 4.0260e-03 -6.0000e+00 3.0249e-02 1.6143e-04 -6.1297e-05 8.4618e-05 4.8191e-05 -6.0000e+00 2.3260e-03 -4.2068e-03 -3.5424e-05 11 9 0 11 8 0 97.46 23.12 0.02 -0.00421 -0.00467 16 3 1 5 0 3110.890 26.73 20.00 23.12 6.70 33.9 972.32 29573 -27253 26367 26124 -6648 6915 42840 -565 -11506 -8657 -22265 -15994 1658 19571 2330 -6116 -7066 -906 5879 1341 110 2926 2276 -8004 -10284 -6093 -1871 17336 -413 12276 -2994 11245 -10086 -4944 -3787 -6428 -179 -678 -2955 -1772 -2049 -462 -1347 -1733 1293 2031 -139 1798 -1417 1646 2029 732 1644 3074 -151 1087 1314 1199 -1989 -89 114 1253 2017 2316 -363 694 -1296 -202 1213 1736 728 824 524 -63 -489 -675 -1069 -1897 1 -1595 -1010 -1777 -2208 -2013 -757 -164 848 342 843 -44 822 988 130 -344 1349 48 673 189 -103 -253 -808 -1298 -386 -158 -553 -1096 -579 -285 280 307 232 542 326 143 142 739 -64 397 387 251 17 -113 444 530 240 -1738 117 1562 125 -66 -298 -643 -717 137 -125 -44 167 397 -302 265 -63 -225 531 -859 537 513 -164 154 765 -16 -391 -302 -926 -703 74 877 141 -448 -566 -73 471 116 10 260 213 -879 -1220 -716 -210 1594 -45 1251 -392 1444 -1700 -809 -604 -1084 -32 -142 -739 -496 -624 -146 -441 -578 424 667 -47 602 -500 594 784 307 728 1416 -74 541 659 598 -1007 -45 60 700 1206 1451 -233 428 -800 -127 815 1263 563 649 408 -47 -344 -442 -674 -1221 0 -1229 -851 -1621 -2129 -2027 -791 -177 941 385 935 -48 839 959 124 -337 1395 55 825 246 -138 -335 -1026 -1566 -452 -189 -692 -1428 -779 -399 411 475 373 875 518 220 209 1064 -94 597 604 400 27 -177 679 789 348 -2484 164 2237 190 -107 -500 -1112 -1273 250 -236 -86 327 783 -594 509 -118 -411 SS 20240208T143816.1Z 8804.609908 92 1 49.15 2 71.39 135.19 74.00 155.63 0.00 1 0.00 1 0 17 4.684e-02 7.080e-03 1.736e-02 1.813e-03 4.419298e-01 9.546172e-04 5.347355e-03 -6.000000e+00 2.809765e-02 224.30 -2.00 3.58 -2.00 318.80 0.00e+00 1.625979e-03 2.090313e-04 3.808189e-04 -6.000000e+00 1.195690e-03 271.01 -2.00 20.00 -2.00 318.33 0.00e+00 3.096 0.001 302.00 328.00 3 3.7979e+00 2.5756e-03 3.7688e-02 -6.0000e+00 6.9471e-02 6.0059e-02 2.9394e-03 2.2960e-02 -6.0000e+00 7.5392e-02 -2.2476e-02 2.1852e-03 1.1752e-02 -6.0000e+00 4.4716e-02 -2.0691e-03 1.1625e-03 3.8056e-03 -6.0000e+00 1.8977e-02 3.3930e-04 -7.0293e-04 5.6499e-05 4.5989e-05 -6.0000e+00 1.4609e-03 -2.0639e-03 -1.0351e-04 11 9 0 11 8 0 94.93 23.12 0.07 -0.00206 -0.00735 32 7 1 5 0 1535.600 26.73 20.00 23.12 6.97 33.7 973.56 8962 -25528 5396 -9434 -4713 4670 15417 -19478 1984 -22707 -2559 -21170 204 -4755 4718 -7877 916 -6580 3653 -3509 3396 -1861 4383 -4432 -2036 -5289 -1726 5543 -1986 6178 2194 4467 -3324 -2203 -1205 -4102 -1177 477 -181 -1311 -670 -954 -1068 -1041 109 -685 -488 611 -1110 898 1332 1710 916 2727 252 1591 413 373 -1502 330 293 2162 1622 1755 -444 336 -1370 482 1100 1884 393 816 485 654 -578 -753 -953 -1052 -332 -899 -932 -1456 -2486 -1252 -910 -91 478 415 711 194 698 313 -122 -103 776 351 366 468 -291 -516 -797 -887 -19 -68 -1333 -1417 -728 -472 458 251 398 -87 338 -20 227 209 690 411 480 9 -36 356 589 542 617 -1026 456 1265 124 -15 -265 -398 -474 140 -236 -415 68 291 26 303 -45 -716 236 -984 162 -308 -141 130 422 -798 73 -1094 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